Cargando…

Direct synthesis of coordination and organometallic compounds /

This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinet...

Descripción completa

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Garnovski�i, A. D., Kharissov, Boris I.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; New York : Elsevier, 1999.
Edición:1st ed.
Temas:
Acceso en línea:Texto completo

MARC

LEADER 00000cam a2200000 a 4500
001 SCIDIR_ocn162131164
003 OCoLC
005 20231117014854.0
006 m o d
007 cr cn|||||||||
008 070802s1999 ne a ob 001 0 eng d
040 |a OPELS  |b eng  |e pn  |c OPELS  |d OCLCQ  |d N$T  |d YDXCP  |d MERUC  |d E7B  |d IDEBK  |d OCLCQ  |d OCLCF  |d OCLCQ  |d OCLCA  |d STF  |d D6H  |d OCLCQ  |d LEAUB  |d OL$  |d OCLCQ  |d OCLCO  |d COM  |d OCLCO  |d OCLCQ  |d OCLCO 
019 |a 173807726  |a 174963939  |a 441795262  |a 647652747  |a 815528639  |a 823108050  |a 823828752  |a 823898481  |a 824089768  |a 824136397  |a 1035686323 
020 |a 9780444720009 
020 |a 0444720006 
020 |a 9780080530444  |q (electronic bk.) 
020 |a 0080530443  |q (electronic bk.) 
020 |a 1281034126 
020 |a 9781281034120 
035 |a (OCoLC)162131164  |z (OCoLC)173807726  |z (OCoLC)174963939  |z (OCoLC)441795262  |z (OCoLC)647652747  |z (OCoLC)815528639  |z (OCoLC)823108050  |z (OCoLC)823828752  |z (OCoLC)823898481  |z (OCoLC)824089768  |z (OCoLC)824136397  |z (OCoLC)1035686323 
050 4 |a QD474  |b .D57 1999eb 
072 7 |a QD  |2 lcco 
072 7 |a SCI  |x 013040  |2 bisacsh 
072 7 |a PNND  |2 bicssc 
082 0 4 |a 547/.050459  |2 22 
245 0 0 |a Direct synthesis of coordination and organometallic compounds /  |c edited by Alexander D. Garnovskii, Boris I. Kharissov ; contributors, A.D. Garnovskii [and others]. 
250 |a 1st ed. 
260 |a Amsterdam ;  |a New York :  |b Elsevier,  |c 1999. 
300 |a 1 online resource (ix, 244 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
520 |a This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and & bgr;-diketones). 
505 0 |a Preface Chapter 1 -- Cryosynthesis of Metal Complexes Chapter II -- Electrochemical Synthesis of Metal Complexes Chapter III -- Oxidative Dissolution of Metals and Metal Oxides in a Liquid Phase Chapter IV -- Mechanosynthesis of Coordination Compounds Chapter V -- Some Peculiarities of Crystal Structure of Complexes Obtained by the Direct Synthesis. 
504 |a Includes bibliographical references and indexes. 
588 0 |a Print version record. 
650 0 |a Coordination compounds  |x Synthesis. 
650 0 |a Organometallic compounds  |x Synthesis. 
650 6 |a Compos�es de coordination  |0 (CaQQLa)201-0011366  |x Synth�ese.  |0 (CaQQLa)201-0377483 
650 6 |a Compos�es organom�etalliques  |0 (CaQQLa)201-0037501  |x Synth�ese.  |0 (CaQQLa)201-0377483 
650 7 |a SCIENCE  |x Chemistry  |x Organic.  |2 bisacsh 
650 7 |a Coordination compounds  |x Synthesis  |2 fast  |0 (OCoLC)fst00878283 
650 7 |a Organometallic compounds  |x Synthesis  |2 fast  |0 (OCoLC)fst01047981 
700 1 |a Garnovski�i, A. D. 
700 1 |a Kharissov, Boris I. 
776 0 8 |i Print version:  |t Direct synthesis of coordination and organometallic compounds.  |b 1st ed.  |d Amsterdam ; New York : Elsevier, 1999  |z 0444720006  |z 9780444720009  |w (DLC) 99023836  |w (OCoLC)41355647 
856 4 0 |u https://sciencedirect.uam.elogim.com/science/book/9780444720009  |z Texto completo