The roots of organic development /

The development of organic intermediates requires high performance and original technologies. This book reviews recent work on some fifteen basic technologies in intermediates development including; hydrogenation, fluorination, chlorination, nitration, enzymatic catalysis, hydroxylation, alkylation,...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Desmurs, Jean-Roger, Ratton, Serge
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; New York : Elsevier, 1996.
Colección:Industrial chemistry library ; v. 8.
Temas:
Chemistry, Organic > Industrial applications.
Chimie organique > Applications industrielles.
TECHNOLOGY & ENGINEERING > Chemical & Biochemical.
Organic compounds
Acceso en línea:Texto completo
Texto completo
Tabla de Contenidos:
  • Chapter 1. Friedel-Crafts acylation : interactions between Lewis acids / acyl chlorides and Lewis acids / aryl ketones
  • Chapter 2. Bismuth (III) salts in the Friedel-Crafts acylation
  • Chapter 3. Friedel-Crafts acylation of aromatics using zeolites
  • Chapter 4. CoCl2 catalyzed trifluoroacetylation of aromatics using trifluoroacetic anhydride
  • Chapter 5. Catalysis by rare earth phosphate II : Selective O-methylation of phenols by methanol in vapor phase
  • Chapter 6. Catalysis by rare earth phosphate III : Characterisation of samarium phosphate and samarium phosphate-cesium hydrogenophosphate as key catalysts for O-alkylation of phenols
  • Chapter 7. Selective functionalisation of fluoroaromatics via organosilicon intermediates
  • Chapter 8. Arylation of amines and alcohols catalyzed by nickel, copper or palladium complexes
  • Chapter 9. The isomerisation of 1,2,4-trichlorobenzene : a theoretical study
  • Chapter 10. Carboxylation of hydroxy aromatic compounds
  • Chapter 11. Access to polychlorophenols, chemistry of intermediates
  • Chapter 12. Diastereoselective halogenations
  • Chapter 13. Enzymatic hydrolysis of adiponitrile into 5-cyanovaleric acid, an intermediate for Nylon 6
  • Chapter 14. Reagents with trifluoromethyl substituents
  • Chapter 15. Fluorination of aromatic compounds by halogen exchange with fluoride anions ("Halex" reaction)
  • Chapter 16. 4-Fluorophenol : a key intermediate for agrochemicals and pharmaceuticals
  • Chapter 17. Fluorodecarboxylation of arylchloroformate : a new access to fluoroaromatics
  • Chapter 18. Mild trifluoromethylation of organic compounds
  • Chapter 19. Formylation of aromatic compounds in superacidic medium
  • Chapter 20. High selectivities in hydrogenation of halogenonitrobenzenes on Pd, Pt or Raney Nickel as catalysts
  • Chapter 21. Influence of the cation in condensation of glyoxylic acid on phenols in aqueous hydroxide solution
  • Chapter 22. Selective access to hydroquinone <<Fuchsone>> route
  • Chapter 23. The mechanisms of nitration of phenol
  • Chapter 24. Oxidation of alkylphenols to hydroxybenzaldehydes
  • Chapter 25. Large pore Ti-Beta zeolite with very low aluminium content : an active and selective catalyst for oxidations using hydrogen peroxide
  • Chapter 26. Peptide synthesis by SAPPHO technology
  • Chapter 27. A new and practical removal of allyl and allyloxycarbonyl group promoted by water-soluble Pd(0) catalysts
  • Chapter 28. Safety of chlorination reactions
  • Chapter 29. Sodium amide in organic synthesis
  • Chapter 30. Delivery systems for controlled release of active materials
  • Chapter 31. Anisole : an excellent solvent
  • Chapter 32. The use of phenolic compounds as free-radical polymerization inhibitors
  • Chapter 33. Tracing back the origin of vanillin by SNIF-NMR
  • Chapter 34. NMR under high gas pressure
  • Chapter 35. Lactic derivatives : methods for determining the optical purity of various intermediates.

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