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The roots of organic development /

The development of organic intermediates requires high performance and original technologies. This book reviews recent work on some fifteen basic technologies in intermediates development including; hydrogenation, fluorination, chlorination, nitration, enzymatic catalysis, hydroxylation, alkylation,...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Desmurs, Jean-Roger, Ratton, Serge
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; New York : Elsevier, 1996.
Colección:Industrial chemistry library ; v. 8.
Temas:
Acceso en línea:Texto completo
Texto completo

MARC

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245 0 4 |a The roots of organic development /  |c edited by Jean-Roger Desmurs, Serge Ratton. 
260 |a Amsterdam ;  |a New York :  |b Elsevier,  |c 1996. 
300 |a 1 online resource (xvi, 562 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
490 1 |a Industrial chemistry library ;  |v v. 8 
520 |a The development of organic intermediates requires high performance and original technologies. This book reviews recent work on some fifteen basic technologies in intermediates development including; hydrogenation, fluorination, chlorination, nitration, enzymatic catalysis, hydroxylation, alkylation, carboxylation and the Friedel Crafts reaction. Problems and industrial constraints involved in industrial development are highlighted from a research viewpoint and new technologies with potential for use in industry, particularly catalyst-based technologies clean chemical processes, are described. A chapter dealing with reviews on sodium amidure and polymerisation inhibitors is included. 
504 |a Includes bibliographical references and indexes. 
505 0 |a Chapter 1. Friedel-Crafts acylation : interactions between Lewis acids / acyl chlorides and Lewis acids / aryl ketones -- Chapter 2. Bismuth (III) salts in the Friedel-Crafts acylation -- Chapter 3. Friedel-Crafts acylation of aromatics using zeolites -- Chapter 4. CoCl2 catalyzed trifluoroacetylation of aromatics using trifluoroacetic anhydride -- Chapter 5. Catalysis by rare earth phosphate II : Selective O-methylation of phenols by methanol in vapor phase -- Chapter 6. Catalysis by rare earth phosphate III : Characterisation of samarium phosphate and samarium phosphate-cesium hydrogenophosphate as key catalysts for O-alkylation of phenols -- Chapter 7. Selective functionalisation of fluoroaromatics via organosilicon intermediates -- Chapter 8. Arylation of amines and alcohols catalyzed by nickel, copper or palladium complexes -- Chapter 9. The isomerisation of 1,2,4-trichlorobenzene : a theoretical study -- Chapter 10. Carboxylation of hydroxy aromatic compounds -- Chapter 11. Access to polychlorophenols, chemistry of intermediates -- Chapter 12. Diastereoselective halogenations -- Chapter 13. Enzymatic hydrolysis of adiponitrile into 5-cyanovaleric acid, an intermediate for Nylon 6 -- Chapter 14. Reagents with trifluoromethyl substituents -- Chapter 15. Fluorination of aromatic compounds by halogen exchange with fluoride anions ("Halex" reaction) -- Chapter 16. 4-Fluorophenol : a key intermediate for agrochemicals and pharmaceuticals -- Chapter 17. Fluorodecarboxylation of arylchloroformate : a new access to fluoroaromatics -- Chapter 18. Mild trifluoromethylation of organic compounds -- Chapter 19. Formylation of aromatic compounds in superacidic medium -- Chapter 20. High selectivities in hydrogenation of halogenonitrobenzenes on Pd, Pt or Raney Nickel as catalysts -- Chapter 21. Influence of the cation in condensation of glyoxylic acid on phenols in aqueous hydroxide solution -- Chapter 22. Selective access to hydroquinone <<Fuchsone>> route -- Chapter 23. The mechanisms of nitration of phenol -- Chapter 24. Oxidation of alkylphenols to hydroxybenzaldehydes -- Chapter 25. Large pore Ti-Beta zeolite with very low aluminium content : an active and selective catalyst for oxidations using hydrogen peroxide -- Chapter 26. Peptide synthesis by SAPPHO technology -- Chapter 27. A new and practical removal of allyl and allyloxycarbonyl group promoted by water-soluble Pd(0) catalysts -- Chapter 28. Safety of chlorination reactions -- Chapter 29. Sodium amide in organic synthesis -- Chapter 30. Delivery systems for controlled release of active materials -- Chapter 31. Anisole : an excellent solvent -- Chapter 32. The use of phenolic compounds as free-radical polymerization inhibitors -- Chapter 33. Tracing back the origin of vanillin by SNIF-NMR -- Chapter 34. NMR under high gas pressure -- Chapter 35. Lactic derivatives : methods for determining the optical purity of various intermediates. 
588 0 |a Print version record. 
650 0 |a Chemistry, Organic  |x Industrial applications. 
650 6 |a Chimie organique  |0 (CaQQLa)201-0004956  |x Applications industrielles.  |0 (CaQQLa)201-0374039 
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650 7 |a Chemistry, Organic  |x Industrial applications.  |2 fast  |0 (OCoLC)fst00853510 
653 0 |a Organic compounds 
700 1 |a Desmurs, Jean-Roger. 
700 1 |a Ratton, Serge. 
776 0 8 |i Print version:  |t Roots of organic development.  |d Amsterdam ; New York : Elsevier, 1996  |z 0444824340  |z 9780444824349  |w (DLC) 96005960  |w (OCoLC)34192011 
776 0 8 |i Online version:  |t Roots of organic development.  |d Amsterdam ; New York : Elsevier, 1996  |w (OCoLC)760072670 
830 0 |a Industrial chemistry library ;  |v v. 8. 
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856 4 0 |u https://sciencedirect.uam.elogim.com/science/bookseries/09269614/8  |z Texto completo