The roots of organic development /
The development of organic intermediates requires high performance and original technologies. This book reviews recent work on some fifteen basic technologies in intermediates development including; hydrogenation, fluorination, chlorination, nitration, enzymatic catalysis, hydroxylation, alkylation,...
Clasificación: | Libro Electrónico |
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Otros Autores: | , |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Amsterdam ; New York :
Elsevier,
1996.
|
Colección: | Industrial chemistry library ;
v. 8. |
Temas: | |
Acceso en línea: | Texto completo Texto completo |
MARC
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082 | 0 | 4 | |a 661/.8 |2 22 |
245 | 0 | 4 | |a The roots of organic development / |c edited by Jean-Roger Desmurs, Serge Ratton. |
260 | |a Amsterdam ; |a New York : |b Elsevier, |c 1996. | ||
300 | |a 1 online resource (xvi, 562 pages) : |b illustrations | ||
336 | |a text |b txt |2 rdacontent | ||
337 | |a computer |b c |2 rdamedia | ||
338 | |a online resource |b cr |2 rdacarrier | ||
490 | 1 | |a Industrial chemistry library ; |v v. 8 | |
520 | |a The development of organic intermediates requires high performance and original technologies. This book reviews recent work on some fifteen basic technologies in intermediates development including; hydrogenation, fluorination, chlorination, nitration, enzymatic catalysis, hydroxylation, alkylation, carboxylation and the Friedel Crafts reaction. Problems and industrial constraints involved in industrial development are highlighted from a research viewpoint and new technologies with potential for use in industry, particularly catalyst-based technologies clean chemical processes, are described. A chapter dealing with reviews on sodium amidure and polymerisation inhibitors is included. | ||
504 | |a Includes bibliographical references and indexes. | ||
505 | 0 | |a Chapter 1. Friedel-Crafts acylation : interactions between Lewis acids / acyl chlorides and Lewis acids / aryl ketones -- Chapter 2. Bismuth (III) salts in the Friedel-Crafts acylation -- Chapter 3. Friedel-Crafts acylation of aromatics using zeolites -- Chapter 4. CoCl2 catalyzed trifluoroacetylation of aromatics using trifluoroacetic anhydride -- Chapter 5. Catalysis by rare earth phosphate II : Selective O-methylation of phenols by methanol in vapor phase -- Chapter 6. Catalysis by rare earth phosphate III : Characterisation of samarium phosphate and samarium phosphate-cesium hydrogenophosphate as key catalysts for O-alkylation of phenols -- Chapter 7. Selective functionalisation of fluoroaromatics via organosilicon intermediates -- Chapter 8. Arylation of amines and alcohols catalyzed by nickel, copper or palladium complexes -- Chapter 9. The isomerisation of 1,2,4-trichlorobenzene : a theoretical study -- Chapter 10. Carboxylation of hydroxy aromatic compounds -- Chapter 11. Access to polychlorophenols, chemistry of intermediates -- Chapter 12. Diastereoselective halogenations -- Chapter 13. Enzymatic hydrolysis of adiponitrile into 5-cyanovaleric acid, an intermediate for Nylon 6 -- Chapter 14. Reagents with trifluoromethyl substituents -- Chapter 15. Fluorination of aromatic compounds by halogen exchange with fluoride anions ("Halex" reaction) -- Chapter 16. 4-Fluorophenol : a key intermediate for agrochemicals and pharmaceuticals -- Chapter 17. Fluorodecarboxylation of arylchloroformate : a new access to fluoroaromatics -- Chapter 18. Mild trifluoromethylation of organic compounds -- Chapter 19. Formylation of aromatic compounds in superacidic medium -- Chapter 20. High selectivities in hydrogenation of halogenonitrobenzenes on Pd, Pt or Raney Nickel as catalysts -- Chapter 21. Influence of the cation in condensation of glyoxylic acid on phenols in aqueous hydroxide solution -- Chapter 22. Selective access to hydroquinone <<Fuchsone>> route -- Chapter 23. The mechanisms of nitration of phenol -- Chapter 24. Oxidation of alkylphenols to hydroxybenzaldehydes -- Chapter 25. Large pore Ti-Beta zeolite with very low aluminium content : an active and selective catalyst for oxidations using hydrogen peroxide -- Chapter 26. Peptide synthesis by SAPPHO technology -- Chapter 27. A new and practical removal of allyl and allyloxycarbonyl group promoted by water-soluble Pd(0) catalysts -- Chapter 28. Safety of chlorination reactions -- Chapter 29. Sodium amide in organic synthesis -- Chapter 30. Delivery systems for controlled release of active materials -- Chapter 31. Anisole : an excellent solvent -- Chapter 32. The use of phenolic compounds as free-radical polymerization inhibitors -- Chapter 33. Tracing back the origin of vanillin by SNIF-NMR -- Chapter 34. NMR under high gas pressure -- Chapter 35. Lactic derivatives : methods for determining the optical purity of various intermediates. | |
588 | 0 | |a Print version record. | |
650 | 0 | |a Chemistry, Organic |x Industrial applications. | |
650 | 6 | |a Chimie organique |0 (CaQQLa)201-0004956 |x Applications industrielles. |0 (CaQQLa)201-0374039 | |
650 | 7 | |a TECHNOLOGY & ENGINEERING |x Chemical & Biochemical. |2 bisacsh | |
650 | 7 | |a Chemistry, Organic |x Industrial applications. |2 fast |0 (OCoLC)fst00853510 | |
653 | 0 | |a Organic compounds | |
700 | 1 | |a Desmurs, Jean-Roger. | |
700 | 1 | |a Ratton, Serge. | |
776 | 0 | 8 | |i Print version: |t Roots of organic development. |d Amsterdam ; New York : Elsevier, 1996 |z 0444824340 |z 9780444824349 |w (DLC) 96005960 |w (OCoLC)34192011 |
776 | 0 | 8 | |i Online version: |t Roots of organic development. |d Amsterdam ; New York : Elsevier, 1996 |w (OCoLC)760072670 |
830 | 0 | |a Industrial chemistry library ; |v v. 8. | |
856 | 4 | 0 | |u https://sciencedirect.uam.elogim.com/science/book/9780444824349 |z Texto completo |
856 | 4 | 0 | |u https://sciencedirect.uam.elogim.com/science/bookseries/09269614/8 |z Texto completo |