Cargando…
Monosaccharide sugars : chemical synthesis by chain elongation, degradation, and epimerization /
In a single volume, Monosaccharide Sugars critically summarizes the applied and potentially useful strategies for the synthesis and degradation of monosaccharides by chain-elongation, degradation, and epimerization. These methodologies permit the synthesis of rare or unnatural monosaccharides that a...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
San Diego :
Academic Press,
1998.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Ascending Synthesis of Monosaccharides: Building up with Total Synthesis. Building up of Sugars with Ascending Synthesis. Chain Extension with Diazoalkanes. Chain Extension with Malonester Derivatives. Chain Extensions with Phosphoranes. Olefination Reactions for the Synthesis of Chain-Extended Monosaccharides. Miscellaneous Methods for Chain Extension of the Monosaccharide Chain. Descending Synthesis of Monosaccharides: The Disulfone-Degradation. Degradation of the Calcium Salts of Aldonic Acids with Hydrogen Peroxide. Descending of Acylated Aldononitriles. Degradation of Saccharides with Oxidative Methods. Degradation of the Peroxide Derivatives of Saccharides. Chain Shortening of Saccharides by Means of Photochemical Methods. Preparation of Sugars with Isomerization: Epimerization of Saccharides in Alkaline Medium. Epimerization of Sugars with Molybdate Ions. Epimerization of Saccharides with the Amine-Complexes of Transition and Alkali-Earth Metals. Subject Index.