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Advances in physical organic chemistry. Volume 40 /
Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics.
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam ; Boston :
Elsevier Academic Press,
2005.
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| Edición: | 1st ed. |
| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 020 | |a 9780120335404 |q (electronic bk.) | ||
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| 050 | 4 | |a QD476 |b .A4eb vol. 40 | |
| 072 | 7 | |a SCI |x 013040 |2 bisacsh | |
| 082 | 0 | 4 | |a 547/.13 |2 22 |
| 245 | 0 | 0 | |a Advances in physical organic chemistry. |n Volume 40 / |c editor, J.P. Richard. |
| 250 | |a 1st ed. | ||
| 260 | |a Amsterdam ; |a Boston : |b Elsevier Academic Press, |c 2005. | ||
| 300 | |a 1 online resource | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 504 | |a Includes bibliographical references and index. | ||
| 520 | |a Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a rapidly developing one, with results and methodologies finding application from biology to solid state physics. | ||
| 505 | 0 | |a Cover; Advances in Physical Organic Chemistry; Contents; Editor's preface; Contributors to Volume 40; Carbenes generated within cyclodextrins and zeolites; Introduction; Guest@Host; Definition of guest@host; Supramolecular chemistry; Characterizing the IC; Guests; Neutral organic reaction intermediates; 1,3-Cyclobutadiene; Ortho-benzyne; Carbenes; Hosts; Cyclodextrins; Structure and stoichiometry; Zeolites; Faujasite structure and stoichiometry; Choice of hosts; a- and �-CyDs; NaY FAU; Objectives; Shape Selectivity; Steering Reaction Outcomes; Control Carbene Spin State | |
| 505 | 8 | |a Carbene bond angle distortionFacilitate intersystem-crossing; Control Intramolecular Reactions; Constraint; Topologic distortion; Inhibit intermolecular reactions; Limit guest mobility; Supramolecular carbene chemistry; Carbene Reactions; Phase Transfer Catalysis; CyD-mediated Reimer-Tiemann reaction; CyD derivatization using nitrogenous carbene precursors; Encapsulated methylene; Choice of Carbenes; Case Studies; 2-Adamantanylidene; 2-Methylcyclohexanylidene; Evidence for diazo compound intermediacy; No increased C-H insertion into methyl group; Alkene isomer ratio unchanged | |
| 505 | 8 | |a Cyclooctanylidene3-Nortricyclanylidene; Phenylcarbene; Chloro(phenyl)carbene; Photolysis in alcohol solution; Photolysis in the supramolecular phase; Conclusions; Acknowledgments; References; Mechanistic studies on enzyme-catalyzed phosphoryl transfer; Introduction; Mechanistic Possibilities for Phosphoryl Transfer; Nomenclature Issues; Uncatalyzed reactions of phosphomonoesters; Dianions of Phosphomonoesters; Monoanions of Phosphomonoesters; Uncatalyzed reactions of phosphodiesters; Uncatalyzed reactions of phosphotriesters; Implications for enzymatic catalysis | |
| 505 | 8 | |a Enzymes that catalyze transfer of the phosphoryl (PO3) groupPhosphatases: General; Alkaline Phosphatase; Acid Phosphatase; Purple Acid Phosphatases; Ser/Thr Protein Phosphatases; Protein-Tyrosine Phosphatases (PTPASES); Ras; Phosphoglucomutases; Phosphodiesterases; Staphylococcal Nuclease; Ribonuclease (RNASE); Phosphotriesterases; References; Finite molecular assemblies in the organic solid state: toward engineering properties of solids; Introduction; Finite molecular assemblies; Supramolecular synthons, finite assemblies, and functional solids; Finite assemblies in the solid state; Synthons | |
| 505 | 8 | |a Synthetic AssembliesTwo-component assemblies; 1D assemblies; 2D assemblies; 3D assemblies; Functional Assemblies; Two-component assemblies; 1D assemblies; 2D assemblies; 3D assemblies; Our approach: template-controlled solid-state reactivity; Linear Templates; Target-Oriented Syntheses; Summary and outlook; Acknowledgment; References; The physical organic chemistry of very high-spin polyradicals; Introduction; Exchange coupling and magnetism; Preparation and characterization of polyarylmethyl polyradicals; High-spin versus low-spin polyradicals; Diradicals; Triradicals; Tetraradicals | |
| 650 | 0 | |a Physical organic chemistry. | |
| 650 | 6 | |a Chimie organique physique. |0 (CaQQLa)201-0034746 | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Organic. |2 bisacsh | |
| 650 | 7 | |a Physical organic chemistry |2 fast |0 (OCoLC)fst01715687 | |
| 700 | 1 | |a Richard, J. P. |q (John P.) | |
| 856 | 4 | 0 | |u https://sciencedirect.uam.elogim.com/science/book/9780120335404 |z Texto completo |