Solar fuels /

SOLAR FUELS In this book, you will have the opportunity to have comprehensive knowledge about the use of energy from the sun, which is our source of life, by converting it into different chemical fuels as well as catching up with the latest technology. The most important obstacle to solar meeting al...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Sanki, Nurdan Demirci (Editor ), Sankir, Mehmet (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Hoboken, NJ : Beverly, MA : John Wiley & Sons, Inc. ; Scrivener Publishing LLC, 2023.
Colección:Advances in solar cell materials and storage
Temas:
Solar energy.
Acceso en línea:Texto completo (Requiere registro previo con correo institucional)
Tabla de Contenidos:
  • Cover
  • Title Page
  • Copyright Page
  • Contents
  • Preface
  • Part I: Solar Thermochemical and Concentrated Solar Approaches
  • Chapter 1 Materials Design Directions for Solar Thermochemical Water Splitting
  • 1.1 Introduction
  • 1.1.1 Hydrogen via Solar Thermolysis
  • 1.1.2 Hydrogen via Solar Thermochemical Cycles
  • 1.1.3 Thermodynamics
  • 1.1.4 Economics
  • 1.2 Theoretical Methods
  • 1.2.1 Oxygen Vacancy Formation Energy
  • 1.2.2 Standard Entropy of Oxygen Vacancy Formation
  • 1.2.3 Stability
  • 1.2.4 Structure
  • 1.2.5 Kinetics
  • 1.3 The State-of-the-Art Redox-Active Metal Oxide
  • 1.4 Next-Generation Perovskite Redox-Active Materials
  • 1.5 Materials Design Directions
  • 1.5.1 Enthalpy Engineering
  • 1.5.2 Entropy Engineering
  • 1.5.3 Stability Engineering
  • 1.6 Conclusions
  • Acknowledgments
  • Appendices
  • Appendix A. Equilibrium Composition for Solar Thermolysis
  • Appendix B. Equilibrium Composition of Ceria
  • References
  • Chapter 2 Solar Metal Fuels for Future Transportation
  • 2.1 Introduction
  • 2.1.1 Sustainable Strategies to Address Climate Change
  • 2.1.2 Circular Economy
  • 2.1.3 Sustainable Solar Recycling of Metal Fuels
  • 2.2 Direct Combustion of Solar Metal Fuels
  • 2.2.1 Stabilized Metal-Fuel Flame
  • 2.2.2 Combustion Engineering
  • 2.2.3 Designing Metal-Fueled Engines
  • 2.3 Regeneration of Metal Fuels Through the Solar Reduction of Oxides
  • 2.3.1 Thermodynamics and Kinetics of Oxides Reduction
  • 2.3.2 Effect of Some Parameters on the Reduction Yield
  • 2.3.2.1 Carbon-Reducing Agent
  • 2.3.2.2 Catalysts and Additives
  • 2.3.2.3 Mechanical Milling
  • 2.3.2.4 CO Partial Pressure
  • 2.3.2.5 Carrier Gas
  • 2.3.2.6 Fast Preheating
  • 2.3.2.7 Progressive Heating
  • 2.3.3 Reverse Reoxidation of the Produced Metal Powders
  • 2.3.4 Reduction of Oxides Using Concentrated Solar Power.
  • 2.3.5 Solar Carbothermal Reduction of Magnesia
  • 2.3.6 Solar Carbothermal Reduction of Alumina
  • 2.4 Conclusions
  • Acknowledgments
  • References
  • Chapter 3 Design Optimization of a Solar Fuel Production Plant by Water Splitting With a Copper-Chlorine Cycle
  • Nomenclature
  • 3.1 Introduction
  • 3.2 System Description
  • 3.3 Mathematical Modeling and Optimization
  • 3.3.1 Energy and Exergy Analyses
  • 3.3.2 Economic Analysis
  • 3.3.3 Multiobjective Optimization (MOO) Algorithm
  • 3.4 Results and Discussion
  • 3.5 Conclusions
  • References
  • Chapter 4 Diversifying Solar Fuels: A Comparative Study on Solar Thermochemical Hydrogen Production Versus Solar Thermochemical Energy Storage Using Co3O4
  • 4.1 Introduction
  • 4.2 Materials and Methods
  • 4.3 Thermodynamics of Direct Decomposition of Water
  • 4.4 A Critical Analysis of Two-Step Thermochemical Water Splitting Cycles Through the Red/Ox Properties of Co3O4
  • 4.4.1 Red/Ox Characteristics of Co3O4 Measured by Temperature-Programmed Analysis
  • 4.4.2 The Role of Pt as a Reduction Promoter of Co3O4
  • 4.4.3 A Critical Analysis of the Solar Thermochemical Cycles of Water Splitting
  • 4.5 Cyclic Thermal Energy Storage Using Co3O4
  • 4.5.1 Mass and Heat Transfer Effects During Red/Ox Processes
  • 4.5.2 Cyclic Thermal Energy Storage Performance of Co3O4
  • 4.6 Conclusions
  • Acknowledgements
  • References
  • Part II: Artificial Photosynthesis and Solar Biofuel Production
  • Chapter 5 Shedding Light on the Production of Biohydrogen from Algae
  • 5.1 Introduction
  • 5.2 Hydrogen or Biohydrogen as Source of Energy
  • 5.3 Hydrogen Production From Various Resources
  • 5.4 Mechanism of Biological Hydrogen Production from Algae
  • 5.5 Production of Hydrogen from Different Algal Species
  • 5.5.1 Generation of Hydrogen in Scenedesmus obliquus
  • 5.5.2 Production of Hydrogen in Chlorella vulgaris.
  • 5.5.3 Generation of Hydrogen in Model Alga Chlamydomonas reinhardtii
  • 5.6 Concluding Remarks
  • Acknowledgments
  • References
  • Chapter 6 Photoelectrocatalysis Enables Greener Routes to Valuable Chemicals and Solar Fuels
  • 6.1 Introduction
  • 6.2 C-H Functionalization in Complex Organic Synthesis
  • 6.3 Examples of Photoelectrochemical-Induced C-H Activation
  • 6.4 C-C Functionalization
  • 6.5 Electrochemically Mediated Photoredox Catalysis (e-PRC)
  • 6.6 Interfacial Photoelectrochemistry (iPEC)
  • 6.7 Reagent-Free Cross Dehydrogenative Coupling
  • 6.8 Conclusion
  • References
  • Part III: Photocatalytic CO2 Reduction to Fuels
  • Chapter 7 Graphene-Based Catalysts for Solar Fuels
  • 7.1 Introduction
  • 7.2 Preparation of Graphene and Its Composites
  • 7.2.1 Preparation of Graphene (Oxide)
  • 7.2.2 Preparation of Graphene-Based Photocatalysts
  • 7.2.2.1 Hydrothermal/Solvothermal Method
  • 7.2.2.2 Sol-Gel Method
  • 7.2.2.3 In Situ Growth Method
  • 7.3 Graphene-Based Catalyst Characterization Techniques
  • 7.3.1 SEM, TEM, and HRTEM
  • 7.3.2 X-Ray Techniques: XPS, XRD, XANES, XAFS, and EXAFS
  • 7.3.3 Atomic Force Microscopy (AFM)
  • 7.3.4 Fourier Transform Infrared Spectroscopy (FTIR)
  • 7.3.5 Other Technologies
  • 7.4 Graphene-Based Catalyst Performance
  • 7.4.1 Photocatalytic CO2 Reduction
  • 7.4.2 Hydrogen Production by Water Splitting
  • 7.5 Conclusion and Future Opportunities
  • Acknowledgments
  • References
  • Chapter 8 Advances in Design and Scale-Up of Solar Fuel Systems
  • 8.1 Introduction
  • 8.2 Strategies for Solar Photoreactor Design
  • 8.2.1 Photocatalytic Systems
  • 8.2.1.1 Slurry Photoreactor
  • 8.2.1.2 Fixed Bed Photoreactor
  • 8.2.1.3 Twin Photoreactor (Membrane Photoreactor)
  • 8.2.1.4 Microreactor
  • 8.2.2 Electrochemical System
  • 8.2.2.1 CO2 Electrochemical Reactors
  • 8.2.3 Photoelectrochemical (PEC) Systems.
  • 8.3 Design Considerations for Scale-Up
  • 8.4 Future Systems and Large Reactors
  • 8.5 Conclusions
  • References
  • Part IV: Solar-Driven Water Splitting
  • Chapter 9 Photocatalyst Perovskite Ferroelectric Nanostructures
  • 9.1 Introduction
  • 9.2 Ferroelectric Properties and Materials
  • 9.3 Fundamental of Photocatalysis and Photoelectrocatalysis
  • 9.3.1 Photocatalytic Production of Hydrogen Fuel
  • 9.3.2 Photoelectrocatalytic Hydrogen Production
  • 9.3.3 Photocatalytic Dye/Pollutant Degradation
  • 9.4 Principle of Piezo/Ferroelectric Photo(electro)catalysis
  • 9.5 Ferroelectric Nanostructures for Photo(electro)catalysis
  • 9.6 Synthesis and Design of Nanostructured Ferroelectric Photo(electro)catalysts
  • 9.6.1 Hydrothermal/Solvothermal Methods
  • 9.6.2 Sol-Gel Methods
  • 9.6.3 Wet Chemical and Solution Methods
  • 9.6.4 Vapor Phase Deposition Methods
  • 9.6.5 Electrospinning Methods
  • 9.7 Photo(electro)catalytic Activities of Ferroelectric Nanostructures
  • 9.7.1 Photo(electro)catalytic Activities of BiFeO3 Nanostructures and Thin Films
  • 9.7.2 Photo(electro)catalytic Activities of LaFeO3 Nanostructures
  • 9.7.3 Photo(electro)catalytic Activities of BaTiO3 Nanostructures
  • 9.7.4 Photo(electro)catalytic Activities of SrTiO3 Nanostructures
  • 9.7.5 Photo(electro)catalytic Activities of YFeO3 Nanostructures
  • 9.7.6 Photo(electro)catalytic Activities of KNbO3 Nanostructures
  • 9.7.7 Photo(electro)catalytic Activities of NaNbO3 Nanostructures
  • 9.7.8 Photo(electro)catalytic Activities of LiNbO3 Nanostructures
  • 9.7.9 Photo(electro)catalytic Activities of PbTiO3 Nanostructures
  • 9.7.10 Photo(electro)catalytic Activities of ZnSnO3 Nanostructures
  • 9.8 Conclusion and Perspective
  • References
  • Chapter 10 Solar-Driven H2 Production in PVE Systems
  • 10.1 Introduction
  • 10.2 Approaches for H2 Production via Solar-Driven Water Splitting.
  • 10.3 Principle of Designing of PVE Systems for Solar-Driven Water Splitting
  • 10.4 Development of PVE Systems for Solar-Driven Water Splitting
  • 10.4.1 PVE Systems Based on Si PV Cells
  • 10.4.2 PVE Systems Based on Group III-V Compound PV Cells
  • 10.4.3 PVE Systems Based on Chalcogenide PV Cells
  • 10.4.4 PVE Systems Based on Perovskite PV Cells
  • 10.4.5 PVE Systems Based on Organic Heterojunction PV Cells
  • 10.5 Conclusions and Future Perspective
  • References
  • Chapter 11 Impactful Role of Earth-Abundant Cocatalysts in Photocatalytic Water Splitting
  • 11.1 Introduction
  • 11.2 Categories of Cocatalysts Utilized in Photocatalytic Water Splitting
  • 11.2.1 Metal and Non-Metal Cocatalysts
  • 11.2.2 Metal Oxides and Hydroxides
  • 11.2.3 Metal Sulfides
  • 11.2.4 Metal Phosphides and Carbides
  • 11.2.5 Molecular Cocatalysts
  • 11.3 Factors Determining the Cocatalyst Activity
  • 11.3.1 Intrinsic Properties of Cocatalysts
  • 11.3.2 Interfacial Coupling of Cocatalysts With Host Semiconductors
  • 11.4 Advanced Characterization Techniques for Cocatalytic Process
  • 11.5 Conclusion
  • Acknowledgments
  • References
  • Index
  • EULA.

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