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Thermodynamics and applications in hydrocarbons energy production /
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
?2016.
|
| Edición: | 1st edition. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- A. Dedication
- B. About the Author
- C. Preface
- D. Acknowledgments
- E. Notation
- Terms
- Superscripts
- Subscripts
- Symbols
- 1. Review of Basic Concepts in Bulk Phase Equilibrium Thermodynamics
- Conditions for Equilibrium
- Mathematical Properties of U and S
- Gibbs-Duhem Equation
- Other Fundamental Equations
- Internal Energy Minimum Principle
- Chemical Potential of a Component in a Mixture
- Partial Molar Quantities
- Fugacity
- Ideal and Nonideal Fluids
- Activity Coefficient
- Relation between ?_i and G^E
- Activity Coefficient Models
- Legendre Transformation
- Jacobian Transformation
- Maxwell's Relations
- Examples and Theory Extension
- Problems
- References
- 2. General Theory of Bulk Phase Equilibria
- Equilibrium Condition under the Influence of Gravity
- Equilibrium Condition for Curved Interfaces
- Equilibrium Condition for Charged Systems
- Examples and Theory Extension
- Problems
- References
- 3. Equation-of-State Representation of Fluid Phase Behavior and Properties
- EOS Representation of Volumetric and Phase Behavior
- Associating Species
- Cubic-Plus-Association Equation of State
- Two-Phase Isothermal Compressibility
- Two-Phase Isentropic Compressibility and Two-Phase Sonic Velocity
- Single-Phase Sonic Velocity and Temperature Change Due to Expansion
- Examples and Theory Extension
- Problems
- References
- 4. Stability and Criticality
- Stability Analysis and Stability Limit
- Criticality Analysis
- Alternative Approach for Critical-Point Calculation
- Examples and Theory Extension
- Problems
- References
- 5. Phase Equilibrium Computations
- Gibbs Free Energy Surface Analysis
- Tangent-Plane Distance (TPD) Analysis
- Stability Testing
- Two-Phase Split Computations
- Three-Phase Split Calculations
- Direct Minimization of Gibbs Free Energy in Multiphase Split Calculation
- Phase-Split Calculations in Reduced Space
- Critical-Point Calculation
- Examples and Theory Extension
- Problems
- References
- 6. Theory of Irreversibility and Diffusion in Multicomponent Mixtures
- Irreversibility in a Closed System
- Derivation of Diffusion Flux and Diffusion Coefficients in Multicomponent Mixtures
- Prediction of Past Climate Changes from Irreversible Thermodynamics
- Examples and Theory Extension
- Problems
- Appendix
- References
- 7. Interfacial Thermodynamics
- Plane Interface
- Curved Interface
- Thermodynamic Functions
- Effect of Curvature on Interfacial Tension
- Work of Cluster Formation: Single-Component Systems
- Cap-Shaped Clusters
- Derivation of the Young Equation
- Driving Force (??)
- Thermodynamic Functions and Gibbs Adsorption Equation without Chemical Equilibrium
- Helmholtz Free Energy of an Open System
- Relation between ?_i?, ?_i?, ?_i^s and ?_i?, ?_i?, ?_i^s
- Fundamental Equation of the Interface
- Examples and Theory Extension
- Problems
- References
- 8. Thermodynamics of Thin Liquid Films
- Pressure Anisotropy in the Film
- Thin Liquid Film Work and Energy
- Equilibrium Conditions
- Film Tension
- Thermodynamic Functions of the Thin Liquid Film
- Relations between Disjoining Pressure and Contact Angle
- Example and Theory Extension
- Problems
- References.