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Nuclear chemical engineering

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autores principales: Benedict, Manson (Autor), Pigford, Thomas H. (Autor), Levi, Hans Wolfgang (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: New York, N.Y. : McGraw-Hill Education LLC., c1981.
Edición:2nd edition.
Colección:McGraw-Hill series in nuclear engineering.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • A. Mcgraw-hill series in nuclear engineering
  • B. Dedication
  • C. Preface
  • 1. Chemical engineering aspects of nuclear power
  • Introduction
  • Nuclear fission
  • Nuclear fuels
  • Nuclear reactor types
  • Fuel processing flow sheets
  • Fuel-cycle operations
  • Fuel reprocessing
  • Isotope separation
  • Nuclear fusion
  • References
  • Problems
  • 2. Nuclear reactions
  • Nuclides
  • Radioactivity
  • Decay chains
  • Neutron reactions
  • The fission process
  • Growth and decay of nuclides with simultaneous radioactive decay, neutron absorption, and continuous processing
  • Derivation of the bateman equation (2.17) by laplace transforms
  • Nomenclature
  • References
  • Problems
  • 3. Fuel cycles for nuclear reactors
  • Nuclear fuels
  • Effects of irradiation on nuclear fuels
  • Fuel and poison management
  • Fuel management in a large pressurized-water reactor
  • Fuel-cycle costs
  • Hand calculation of fuel-cycle performance
  • Fuel-cycle material flow sheets
  • Nomenclature
  • References
  • Problems
  • 4. Solvent extraction of metals
  • Applications
  • Extractable metal-organic complexes
  • Solvent extraction principles
  • Distribution coefficients
  • Solvent requirements
  • Theory of countercurrent equilibrium extraction
  • Solvent extraction equipment
  • Nomenclature
  • References
  • Problems
  • 5. Uranium
  • Uranium isotopes
  • Uranium radioactive decay series
  • Metallic uranium
  • Uranium compounds
  • Uranium solution chemistry
  • Sources of uranium
  • Uranium resource estimates
  • Concentration of uranium
  • Uranium refining
  • Production of uranium metal
  • References
  • Problems
  • 6. Thorium
  • Uses of thorium
  • Thorium isotopes
  • Thorium radioactivity
  • Metallic thorium
  • Thorium compounds
  • Thorium solution chemistry
  • Thorium resources
  • Concentration and extraction of thorium
  • Purification of thorium
  • Conversion of thorium nitrate to oxide, fluoride, chloride, or metal
  • References
  • Problems
  • 7. Zirconium and hafnium
  • Uses of zirconium and hafnium
  • Natural occurrence
  • Production and price
  • Zirconium and hafnium metal and alloys
  • Zirconium and hafnium compounds
  • Extraction of zirconium and hafnium from zircon
  • Separation of zirconium and hafnium
  • Production of metallic zirconium and hafnium
  • Alternatives for producing hafnium-free zirconium from zircon
  • References
  • Problems
  • 8. Properties of irradiated fuel and other reactor materials
  • Fission-product radioactivity
  • Radioactivity of the actinides
  • Effect of fuel-cycle alternatives on properties of irradiated fuel
  • Radioactivity from neutron activation
  • Neutron activity in recycled fuel
  • Nomenclature
  • References
  • Problems
  • 9. Plutonium and other actinide elements
  • General chemical properties of the actinides
  • Properties of protactinium
  • Properties of neptunium
  • Properties of plutonium
  • Properties of americium
  • Properties of curium
  • References
  • Problems
  • 10. Fuel reprocessing
  • Objectives of reprocessing
  • Composition of irradiated fuel
  • History of reprocessing
  • The purex process
  • Reprocessing thorium-based fuels
  • Reprocessing lmfbr fuels
  • Neptunium recovery in reprocessing
  • Prevention of criticality in reprocessing plants
  • References
  • Problems.
  • 11. Radioactive waste management
  • Introduction
  • High-level waste
  • Non-high-level waste
  • Special radioactive waste
  • Disposal of radioactive waste
  • Assessment of long-term safety
  • References
  • Problem
  • 12. Stable isotopes: uses, separation methods, and separation principles
  • Uses of stable isotopes
  • Isotope separation methods
  • Terminology
  • Stage properties
  • Types of cascade
  • The simple cascade
  • The recycle cascade
  • The ideal cascade
  • Close-separation cascade
  • Separative capacity, separative work, and separation potential
  • Differential equation for separation potential
  • Equilibrium time for isotope separation plants
  • Squared-off cascade
  • Generalized ideal cascade
  • Three-component isotope separation
  • Nomenclature
  • References
  • Problems
  • 13. Separation of isotopes of hydrogen and other light elements
  • Sources of deuterium
  • Deuterium production processes and plants
  • Separation factors in distillation
  • Distillation of hydrogen
  • Distillation of water
  • Electrolysis
  • Electrolysis and steam-hydrogen exchange
  • Separation factors in deuterium exchange processes
  • Number of theoretical stages in exchange columns
  • Monothermal exchange processes
  • Dual-temperature water-hydrogen sulfide exchange process
  • Dual-temperature ammonia-hydrogen exchange process
  • Methylamine-hydrogen exchange processes
  • Dual-temperature water-hydrogen exchange processes
  • Exchange processes for separation of lithium isotopes
  • Exchange processes for other elements
  • Nomenclature
  • References
  • Problems
  • 14. Uranium isotope separation
  • Introduction
  • Isotopic content of uranium
  • Uranium enrichment projects
  • Gaseous diffusion
  • The gas centrifuge
  • Aerodynamic processes
  • Mass diffusion
  • Thermal diffusion
  • Laser isotope separation
  • Nomenclature
  • References
  • Problems
  • A. Fundamental physical constants
  • B. Conversion factors
  • Basic equivalents
  • Mass and energy equivalents?
  • Pressure equivalents
  • C. Properties of the nuclides
  • Nuclear species
  • Mass
  • Abundance or half-life
  • Decay mode
  • Decay energy
  • Neutron reactions
  • Credits
  • References
  • D. Radioactivity concentration limits for selected radionuclides.