The Properties of Gases and Liquids, Sixth Edition /
Fully updated for the latest advances, this must-have chemical engineering guide serves as a single source for up-to-date physical data, chemical data, and predictive and estimation methods. The Properties of Gases and Liquids, Sixth Edition provides the latest curated data on over 480 compounds and...
Clasificación: | Libro Electrónico |
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Autores principales: | , , , |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
New York, N.Y. :
McGraw Hill LLC,
[2023]
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Edición: | Sixth edition. |
Colección: | McGraw-Hill's AccessEngineeringLibrary.
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover
- Title Page
- Copyright Page
- Contents
- Foreword
- Preface
- 1 Introduction
- 1.1 Scope
- 1.2 Estimation of Physical Properties
- 1.3 Traditional Estimation Methods
- 1.4 Nontraditional Estimation Methods
- 1.5 Database Development and Method Evaluation
- 1.6 Organization of the Book
- 1.7 References
- 2 Uncertainty
- 2.1 Scope
- 2.2 Introduction: Why Are Uncertainties Important?
- 2.3 Historical Background
- 2.4 Key Documents: The GUM, NIST 1297, and VIM
- 2.5 Uncertainty Assessment for Thermophysical Properties: The GUM Approach
- 2.6 The Uncertainty Budget
- 2.7 Reference Materials and Standard Reference Materials
- 2.8 Challenges for the User of Experimental Data from the Literature
- 2.9 Examples of Common Problems in Articles Reporting Thermophysical Properties
- 2.10 Modern Uncertainty Assessment Procedures (Critical Evaluation)
- 2.11 Summary
- 2.12 Disclaimer
- 2.13 References
- 3 Pure-Component Constants
- 3.1 Scope
- 3.2 Vapor-Liquid Critical Properties
- 3.3 Acentric Factor
- 3.4 Melting and Boiling Points
- 3.5 Discussion of Estimation Methods for Pure Component Constants
- 3.6 Dipole Moments
- 3.7 Availability of Data and Computer Programs
- 3.8 Notation
- 3.9 References
- 4 Thermodynamic Properties of Ideal Gases
- 4.1 Scope and Definitions
- 4.2 Estimation Methods for the Ideal Gas Standard State
- 4.3 Method of Benson
- 4.4 Method of Domalski and Hearing
- 4.5 Modified Joback Method for Ideal Gas Heat Capacity
- 4.6 Quantum Mechanical Methods
- 4.7 Standard State Enthalpy of Formation and Enthalpy of Combustion
- 4.8 Discussion and Recommendations
- 4.9 Notation
- 4.10 References
- 5 Pure Fluid Thermodynamic Properties of the Single Variable Temperature
- 5.1 Scope
- 5.2 Saturated Liquid Density
- 5.3 Theory of Liquid Vapor Pressure and Enthalpy of Vaporization
- 5.4 Theory of Liquid Heat Capacity
- 5.5 Correlating Vapor-Pressure, Enthalpy of Vaporization, and Liquid Heat Capacity Data
- 5.6 Reliable Extrapolation of Vapor Pressure and Thermodynamic Consistency between Vapor Pressure, Enthalpy of Vaporization, and Liquid Heat Capacity
- 5.7 Prediction of Vapor Pressure
- 5.8 Extrapolation and Prediction of Enthalpy of Vaporization of Pure Compounds and Recommendations
- 5.9 Prediction of Liquid Heat Capacity
- 5.10 Discussion and Recommendations for Vapor-Pressure, Enthalpy of Vaporization, and Liquid Heat Capacity Estimation and Correlation
- 5.11 Enthalpy of Melting
- 5.12 Enthalpy of Sublimation
- 5.13 Solid Vapor Pressure (Sublimation Pressure)
- 5.14 Correlation and Estimation of Virial Coefficients
- 5.15 Notation
- 5.16 References
- 6 Thermodynamic Properties of Pure Gases and Liquids
- 6.1 Scope
- 6.2 Introduction to Equations of State
- 6.3 Theory of Equations of State
- 6.4 Fundamental Thermodynamic Relationships for Pure Compounds
- 6.5 Virial Equations of State
- 6.6 Cubic Equations of State
- 6.7 Multiparameter Equations of State
- 6.8 Perturbation Models with Customized Parameters
- 6.9 Perturbation Models with Transferable Parameters
- 6.10 Chemical Theory EOSs
- 6.11 Molecular Simulation Models
- 6.12 Residual Functions for Evaluated Models
- 6.13 Evaluations of Equations of State
- 6.14 Notation
- 6.15 References
- 7 Thermodynamic Properties of Mixtures
- 7.1 Scope
- 7.2 Mixture Properties?General Discussion
- 7.3 Theory of Mixture Modeling
- 7.4 Perturbation Models
- 7.5 Excess Gibbs Energy Mixing Rules
- 7.6 Mixing Rules for Multiparameter EOS
- 7.7 Virial Equations of State for Mixtures
- 7.8 Residual Functions for Evaluated Models
- 7.9 Empirical Correlations for Mixture Properties
- 7.10 Evaluations and Recommendations
- 7.11 Notation
- 7.12 References
- 8 Vapor-Liquid Equilibria in Mixtures
- 8.1 Scope
- 8.2 A Note about the Modeling of Temperature Effects
- 8.3 Thermodynamics of Vapor-Liquid Equilibria
- 8.4 Fugacity of a Pure Liquid
- 8.5 Simplifications in the Vapor-Liquid Equilibrium Relation
- 8.6 Activity Coefficients; Gibbs-Duhem Equation, and Excess Gibbs Energy
- 8.7 Theory of Activity Models
- 8.8 Correlating Low-Pressure Binary Vapor-Liquid Equilibria
- 8.9 Effect of Temperature on Low-Pressure Vapor-Liquid Equilibria
- 8.10 Multicomponent Vapor-Liquid Equilibria at Low Pressure
- 8.11 Predicting Activity Coefficients
- 8.12 Phase Equilibrium with Henry's Law
- 8.13 Vapor-Liquid Equilibria with Equations of State
- 8.14 Evaluations
- 8.15 Concluding Remarks
- 8.16 Acronyms
- 8.17 Notation
- 8.18 References
- 9 Specialized Phase Behavior in Mixtures
- 9.1 Scope
- 9.2 Infinite Dilution Activity Coefficients
- 9.3 Liquid-Liquid Equilibria
- 9.4 Solubilities of Solids in Liquids
- 9.5 Evaluations
- 9.6 Concluding Remarks
- 9.7 Notation New to Chapter 9
- 9.8 References
- 10 Viscosity
- 10.1 Scope
- 10.2 Definitions of Units of Viscosity
- 10.3 Theory of Gas Transport Properties
- 10.4 Estimation of Low-Pressure Gas Viscosity
- 10.5 Viscosities of Gas Mixtures at Low Pressures
- 10.6 Effect of Pressure on the Viscosity of Pure Gases
- 10.7 Viscosity of Gas Mixtures at High Pressures
- 10.8 Liquid Viscosity
- 10.9 Effect of High Pressure on Liquid Viscosity
- 10.10 Effect of Temperature on Liquid Viscosity
- 10.11 Estimation of Low-Temperature Liquid Viscosity
- 10.12 Estimation of Liquid Viscosity at High Temperatures
- 10.13 Liquid Mixture Viscosity
- 10.14 Notation
- 10.15 References
- 11 Thermal Conductivity
- 11.1 Scope
- 11.2 Theory of Thermal Conductivity
- 11.3 Thermal Conductivities of Polyatomic Gases
- 11.4 Effect of Temperature on the Low-Pressure Thermal Conductivities of Gases
- 11.5 Effect of Pressure on the Thermal Conductivities of Gases
- 11.6 Thermal Conductivities of Low-Pressure Gas Mixtures
- 11.7 Thermal Conductivities of Gas Mixtures at High Pressures
- 11.8 Thermal Conductivities of Liquids
- 11.9 Estimation of the Thermal Conductivities of Pure Liquids
- 11.10 Effect of Temperature on the Thermal Conductivities of Liquids
- 11.11 Effect of Pressure on the Thermal Conductivities of Liquids
- 11.12 Thermal Conductivities of Liquid Mixtures
- 11.13 Notation
- 11.14 References
- 12 Diffusion
- 12.1 Scope
- 12.2 Basic Concepts and Definitions
- 12.3 Progress in Self-Diffusivity Correlation
- 12.4 Diffusion Coefficients for Binary Gas Systems at Low Pressures: Prediction from Theory
- 12.5 Diffusion Coefficients for Binary Gas Systems at Low Pressures: Empirical Correlations
- 12.6 The Effect of Pressure on the Binary Diffusion Coefficients of Gases
- 12.7 The Effect of Temperature on Diffusion in Gases
- 12.8 Diffusion in Multicomponent Gas Mixtures
- 12.9 Diffusion in Liquids: Theory
- 12.10 Estimation of Binary Liquid Diffusion Coefficients at Infinite Dilution
- 12.11 Concentration Dependence of Binary Liquid Diffusion Coefficients
- 12.12 The Effects of Temperature and Pressure on Diffusion in Liquids
- 12.13 Diffusion in Multicomponent Liquid Mixtures
- 12.14 Diffusion in Electrolyte Solutions
- 12.15 Notation
- 12.16 References
- 13 Surface Tension
- 13.1 Scope
- 13.2 Introduction
- 13.3 Estimation of Pure-Liquid Surface Tension
- 13.4 Temperature Dependence of Pure-Liquid Surface Tension
- 13.5 Surface Tensions of Mixtures
- 13.6 Notation
- 13.7 References
- Appendix A Property Data Bank
- Appendix B Lennard-Jones Potentials as Determined from Viscosity Data
- Index.