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Adhesion and Adhesives Technology : An Introduction.

Detalles Bibliográficos
Clasificación:	Libro Electrónico
Autor principal:	Pocius, Alphonsus V.
Formato:	Electrónico eBook
Idioma:	Inglés
Publicado:	München : Hanser, 2021.
Edición:	4th ed.
Temas:	Adhesion. Adhesives. Adhésion (Physique) Adhésifs. adhesion. adhesive. Chemistry, Organic. Chemistry, Physical and theoretical.
Acceso en línea:	Texto completo

Tabla de Contenidos:

Intro
Preface
Contents
1 Introduction
1.1 Introduction and Chapter Objectives
1.2 Basic Definitions
1.3 Advantages and Disadvantages of Adhesive Bonding
1.4 Uses of Adhesive Bonding in Modern Industry
1.5 Economics of Adhesive Technology
1.6 Literature and Other Sources of Information
1.7 Summary
References
2 The Mechanical Properties of Materials as They Relate to Adhesion
2.1 Introduction
2.2 Definition of Mechanical Stresses for Materials Testing
2.3 Stress-Strain Plots and the Definition of Materials Property Parameters
2.3.1 Tensile Forces
2.3.2 Shear Forces
2.3.3 Strain Energy Density
2.4 Introduction to Linear Elastic Fracture Mechanics
2.5 Introduction to Rheology of Liquids
2.6 Introduction to Linear Viscoelasticity
2.7 An Application of Materials Properties and Mechanics: The Bending of Beams
2.8 Summary
Bibliography
Problems and Review Questions
3 Mechanical Tests of Adhesive Bond Performance
3.1 Introduction
3.2 Failure Modes and the Definition of Practical Adhesion
3.3 Tensile Testing of Adhesive Bonds
3.4 Shear Loading of Adhesive Bonds
3.4.1 The Standard Lap Shear Specimen
3.4.2 Variations on the Lap Shear Specimen
3.4.3 Specimen for Determining the True Shear Properties of an Adhesive
3.4.4 The Goland-Reissner Analysis of the Lap Shear Specimen
3.5 Cleavage Loading of Adhesive Bonds
3.5.1 Cleavage or Fracture Specimens
3.5.1.1 Double Cantilever Beam Specimens
3.5.1.2 Linear Elastic Fracture Mechanics Applied to the Double Cantilever Beam Specimen
3.5.2 Blister Test
3.5.3 Compact Tension Test
3.5.4 Wedge Test
3.6 Peel Tests
3.6.1 Stress Analysis in a Peel Specimen
3.7 Summary
Bibliography
References
Problems and Review Questions
4 The Basics of Intermolecular Forces and Surface Science.
4.1 Introduction
4.2 Fundamental Forces
4.2.1 Electrostatic Forces
4.2.2 van der Waals Interactions
4.2.2.1 Dipole-Dipole Interactions
4.2.2.2 Dipole-Induced Dipole
4.2.2.3 Dispersion Forces
4.2.3 Interactions through Electron Pair Sharing
4.2.4 Repulsive Forces
4.3 Surface Forces and Surface Energy
4.4 Work of Cohesion and Adhesion
4.5 Methods of Measurement of Surface Energy and Related Parameters
4.5.1 Surface Tension
4.5.1.1 Drop Weight/Volume Method
4.5.1.2 Du Nuoy Tensiometer
4.5.2 Surface Energy of Solids
4.5.2.1 Contact Angle Methods
4.5.2.2 Contact Mechanics and Direct Measurement of Solid Surface Energy
4.6 Surface Thermodynamics and Predictions of Surface and Interfacial Tensions
4.6.1 The Good-Girifalco Relationship
4.6.2 The Fowkes Hypothesis and Fractional Polarity
4.6.3 The Zisman Plot
4.6.4 Modern Application of Contact Angle Measurements
4.7 Modern Methods of Surface Analysis
4.7.1 Modern Methods for Analysis of the Chemistry of Surfaces
4.7.2 Topological Methods of Surface Analysis
4.8 Summary
Bibliography
References
Problems and Review Questions
5 Basic Physico/Chemical Properties of Polymers
5.1 Introduction
5.2 Basic Terminology
5.2.1 Monomers versus Polymers
5.2.2 Basic Types of Polymeric Materials
5.2.3 Molecular Weight
5.3 Thermal Transitions of Polymers
5.3.1 Measurement of Tg
5.4 Dynamic Mechanical Measurements and Viscoelasticity
5.4.1 Methods of Measurement of Dynamic Mechanical Properties
5.4.2 Examples of Dynamic Mechanical Data for Polymers
5.5 Time-Temperature Superposition
5.6 Summary
Bibliography
References
6 The Relationship of Surface Science and Adhesion Science
6.1 Introduction
6.2 Rationalizations of Adhesion Phenomena
6.3 Electrostatic Theory of Adhesion.
6.4 Diffusion Theory of Adhesion
6.4.1 Diffusive Adhesive Bonding and Block Copolymers at Interfaces
6.5 Mechanical Interlocking and Adhesion
6.5.1 Kinetics of Pore Penetration
6.6 Wettability and Adhesion
6.7 Acid-Base Interactions at Interfaces
6.8 Covalent Bonding at Interfaces
6.8.1 Coupling Agents
6.9 The Relationship of Fundamental Forces of Adhesion and Practical Adhesion
6.10 The Weak Boundary Layer
6.11 Summary
Bibliography
References
Problems and Review Questions
7 The Surface Preparation of Adherends for Adhesive Bonding
7.1 Introduction
7.2 Plastic Surface Preparation
7.2.1 Corona Discharge Treatment
7.2.1.1 Corona Discharge Treatment of Polyethylene
7.2.1.2 Corona Discharge Treatment of Polypropylene
7.2.1.3 Corona Discharge Treatment of Poly(ethylene terephthalate)
7.2.1.4 Corona Discharge Treatment of Other Materials
7.2.2 Flame Treatment
7.2.3 Plasma Treatment
7.2.3.1 Plasma Treatment of PE
7.2.3.2 Plasma Treatment of Other Substrates
7.2.4 Other Physical Treatment Methods of Polymer Surfaces
7.2.4.1 Treatments Using Ultraviolet Radiation
7.2.4.2 Other Vacuum Methods of Surface Preparation
7.2.5 Wet Chemical Methods of Treatment of Polymer Surfaces
7.2.5.1 Single Surface Chemical Functionalization and Chromic Acid Treatment of PE
7.2.5.2 Wet Chemical Surface Treatment of Poly(tetrafluoroethylene)
7.2.6 Priming of Polymer Surfaces
7.2.6.1 Priming of Polyolefins for Cyanoacrylates
7.2.6.2 Chlorinated Polyolefins
7.2.7 Surface of Composite Materials
7.2.7.1 Mechanical Surface Treatment of Composites
7.2.7.2 Peel-Plies as a Method of Composite Surface Preparation
7.2.7.3 A Comparison of Treatment Methods for Graphite Epoxy Reinforced Composite
7.2.7.4 Summary
7.3 Metal Surface Preparation.
7.3.1 Surface Preparation of Aluminum for Adhesive Bonding
7.3.1.1 The Forest Products Laboratory (FPL) Etch
7.4 Anodization Treatments for Adhesive Bonding of Aluminum
7.4.1 Mechanism of Anodization
7.4.2 Anodization Media
7.4.3 Phosphoric Acid Anodization in the Aerospace Industry
7.5 General Techniques for the Surface Preparation of Metals
7.5.1 Conversion Coatings
7.5.2 Abrasion
7.5.3 Electrochemical Methods for Treating Metals other than Aluminum
7.6 Summary
Bibliography
References
Problems and Review Questions
8 The Chemistry and Physical Properties of Structural Adhesives
8.1 Introduction to Chapters 8-11 and 13
8.2 Introduction to Structural Adhesives
8.2.1 Physical Forms of Uncured Structural Adhesives
8.3 Chemistry of Base Resins Used in Structural Adhesives
8.3.1 Phenolics
8.3.2 Proteins
8.3.3 Epoxy Resins
8.3.3.1 Time-Temperature-Transformation Diagrams and the Cure of Epoxy Resins
8.3.4 Urethane Resins
8.3.5 Acrylics
8.3.6 High Temperature Performance Structural Adhesives
8.4 Formulation of Structural Adhesives for Optimum Performance
8.4.1 Formulation of Phenolic Resins
8.4.2 Epoxy Resins
8.4.3 Acrylics
8.4.4 High Temperature Performance Structural Adhesives
8.5 Summary
Bibliography
References
Problems and Review Questions
9 Durability of Structural Adhesive Bonds
9.1 Introduction
9.2 Methods of Examining Durability of Structural Adhesive Bonds
9.3 Mechanisms of Durability Failure of Adhesive Bonds
9.4 Methods Used to Predict Durability
9.5 Summary
References
10 The Chemistry and Physical Properties of Elastomer-Based Adhesives
10.1 Introduction
10.2 Pressure-sensitive Adhesives
10.2.1 Chemistry of the Base Resins Used in PSAs
10.2.2 Chemistry of Tackifiers
10.2.2.1 Natural Product Based Tackifiers.
10.2.2.2 Petroleum Based Tackifiers
10.2.2.3 Other Tackifiers
10.2.3 Testing of Pressure-sensitive Adhesives
10.2.3.1 Measurements of Tack
10.2.3.2 Measurement of Peel
10.2.3.3 Measurement of Shear
10.2.4 Balance of Properties
10.2.5 PSA Performance Viewed as a Time Scale in Viscoelastic Response
10.2.6 PSA Viscoelasticity and Tack
10.2.7 PSA Peel and Viscoelasticity
10.2.8 Shear and Creep Behavior of PSAs
10.2.9 Summary
10.3 Rubber-Based, Contact Bond and Other Elastomeric Adhesives
10.3.1 Formulation of RBAs
10.3.2 Base Polymers
10.3.3 Tackifiers
10.3.4 Pigments and Fillers
10.3.5 Crosslinking/Vulcanization of RBAs
10.3.6 Solvents
10.3.7 Elastomeric Adhesives, Sealants and Release Coatings Based upon Silicone Chemistry
10.4 Summary
Bibliography
References
Problems and Review Questions
11 Thermoplastic, Pseudothermoplastic, and Other Adhesives
11.1 Introduction
11.2 Hot Melt Adhesives
11.2.1 Introduction
11.2.2 Polymer Physical Properties and Hot Melt Adhesives
11.2.3 Formulation of Hot Melt Adhesives
11.2.4 Synthetically Designed Hot Melt Adhesives
11.2.5 Curing Hot Melts
11.3 Polyvinyl Acetate-Based Adhesives
11.4 Polyvinyl Acetal Adhesives
11.5 Thermoplastic or Pseudo-thermoplastic Adhesives based upon Natural Products
11.5.1 Starches
11.5.2 Cellulosics
11.6 Summary
Bibliography
References
12 Adhesion in Biological Systems
12.1 Introduction
12.2 Adhesion in Microbiological Systems
12.3 Biofilm Formation
12.4 Growth Stages of Biofilms
12.4.1 Attachment to a Surface
12.4.2 Irreversible Attachment of Bacteria
12.4.3 Maturation Phase
12.4.4 Biofilm Dispersal
12.5 Maintenance or Elimination of Biofilms
12.6 Adhesion in the Cling Ability of the Tokai Gecko.

Adhesion and Adhesives Technology : An Introduction.

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