Nitroxides : synthesis, properties and applications /

Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Ouari, Olivier (Editor ), Gigmes, Didier (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cambridge : Royal Society of Chemistry, 2021.
Temas:
Nitroxides.
Radicaux aminoxyles.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Intro
  • Title
  • Copyright
  • Contents
  • Chapter 1 A Brief History and Outlook of Nitroxides
  • 1.1 Brief History
  • 1.2 Nitroxide Reactivity
  • 1.3 Conclusion
  • References
  • Chapter 2 General Approaches to Synthesis of Nitroxides
  • 2.1 What are Nitroxides. Limits of Nitroxide Stability
  • 2.2 Nitroxide Group Formation
  • 2.2.1 From Amines
  • 2.2.2 From Hydroxylamines
  • 2.2.3 From Alkoxyamines
  • 2.2.4 From Nitrones
  • 2.3 Some Contemporary Trends in Nitroxide Chemistry
  • 2.3.1 Influence of Structural Factors upon Redox Properties of Nitroxides: The Fight for Stability in Biological Systems
  • 2.3.2 Electron Spin Relaxation
  • 2.4 The Most Important Nitroxide Classes
  • 2.4.1 Piperidine Nitroxides
  • 2.4.2 Pyrroline Nitroxides
  • 2.4.3 Pyrrolidine Nitroxides
  • 2.4.4 Isoindoline Nitroxides
  • 2.4.5 3-Imidazoline and Imidazolidine Nitroxides
  • 2.5 Cyclic Conjugated Nitroxides
  • 2.5.1 4,5-Dihydroimidazole-1-oxyls
  • 2.5.2 Nitronyl Nitroxides of Benzimidazole Series (BenzoNNRs)
  • 2.5.3 Heterocyclic Vinyl Nitroxides
  • 2.6 Conclusion
  • Acknowledgements
  • 3.6 Nitroxide-mediated C-C Bond Formation Reactions
  • 3.7 Miscellaneous Reactions Mediated by Nitroxides
  • 3.8 Conclusion
  • References
  • Chapter 4 Spin Probes and Imaging Using Nitroxides
  • 4.1 Introduction
  • 4.2 NR Oxymetric Probes and EPR Oximetry
  • 4.2.1 Basics of EPR Sensitivity of the Nitroxide Probes to Oxygen
  • 4.2.2 In Vivo EPR Oximetry Using Nitroxide Probes
  • 4.3 NR pH Probes
  • 4.3.1 Basics of Spectral Sensitivity of the Nitroxides to pH
  • 4.3.2 In Vivo Spectroscopy and Imaging of pH Using Nitroxide Probes
  • 4.4 NRs as Thiol-sensitive Probes
  • 4.4.1 Basics of GSH Detection Using Nitroxide Probes
  • 4.4.2 In Vivo EPR Measurements of Intracellular Glutathione
  • 4.5 NRs as Probes for Assessment of Enzymatically Catalyzed Reactions
  • 4.6 Conclusion
  • Acknowledgements
  • References
  • Chapter 5 Nitroxides in Battery-related Applications
  • 5.1 Context
  • 5.2 Organic Batteries Based on Nitroxide Radicals
  • 5.3 Variations of Nitroxide Polymer Structures and Their Related Properties
  • 5.4 Nanostructures in Nitroxide Polymer Electrodes
  • 5.5 Grafting of Nitroxide-containing Polymers onto Carbon Nanotubes

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