Cobalt catalysis in organic synthesis : methods and reactions /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Hapke, Marko (Editor ), Hilt, Gerhard (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Weinheim : Wiley-VCH, 2020.
Temas:
Cobalt catalysts.
Organic compounds > Synthesis.
Catalyseurs au cobalt.
Composés organiques > Synthèse.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover
  • Title Page
  • Copyright
  • Contents
  • Preface
  • Chapter 1 Introduction to Cobalt Chemistry and Catalysis
  • 1.1 Introduction
  • 1.2 Organometallic Cobalt Chemistry, Reactions, and Connections to Catalysis
  • 1.2.1 Cobalt Compounds and Complexes of Oxidation States +3 to -1
  • 1.2.1.1 Co(III) Compounds
  • 1.2.1.2 Co(II) Compounds
  • 1.2.1.3 Co(I) Compounds
  • 1.2.1.4 Co(0) Compounds
  • 1.2.1.5 Co( -I) Compounds
  • 1.2.2 Bioorganometallic Cobalt Compounds
  • 1.3 Applications in Organic Synthesis and Catalytic Transformations
  • 1.4 Conclusion and Outlook
  • Abbreviations
  • References
  • Chapter 2 Homogeneous Cobalt-Catalysed Hydrogenation Reactions
  • 2.1 Introduction
  • 2.2 Hydrogenation of C C Multiple Bonds (Alkenes, Alkynes)
  • 2.3 Hydrogenation of Carbonyl Compounds (Ketones, Aldehydes, Carboxylic Acid Derivatives, CO2)
  • 2.3.1 Ketones and Aldehydes
  • 2.3.2 Carboxylic Acid Derivatives (Acids, Esters, Imides)
  • 2.3.3 Hydrogenation of Carbon Dioxide
  • 2.4 Hydrogenation of C X Multiple Bonds (Imines, Nitriles)
  • 2.4.1 Nitrile Hydrogenation
  • 2.4.2 Imine Hydrogenation
  • 2.4.3 Hydrogenation of N-Heterocycles
  • 2.5 Summary and Conclusions
  • 2.6 Selected Experimental Procedures
  • 2.6.1 Synthesis of Cobalt Complex [(PNHPCy)Co(CH2SiMe3)]BArF4 (8a)
  • Abbreviations
  • References
  • Chapter 3 Synthesis of C C Bonds by Cobalt-Catalysed Hydrofunctionalisations
  • 3.1 Introduction
  • 3.2 Cobalt-Catalysed C C Bond Formations via Hydrofunctionalisation
  • 3.2.1 Hydroformylation
  • 3.2.2 Hydroacylation
  • 3.2.3 Hydrovinylation
  • 3.2.4 Hydroalkylation
  • 3.2.5 Hydrocyanation
  • 3.2.6 Hydrocarboxylation
  • 3.3 Summary and Conclusions
  • Abbreviations
  • References
  • Chapter 4 Cobalt-Catalysed C-H Functionalisation
  • 4.1 Introduction
  • 4.2 Low-valent Cobalt Catalysis
  • 4.2.1 C-H Functionalisation with In Situ-Reduced Cobalt Catalysts
  • 4.2.1.1 Hydroarylation of Alkynes and Alkenes
  • 4.2.1.2 C-H Functionalisation with Electrophiles
  • 4.2.1.3 C-H Functionalisation with Organometallic Reagents
  • 4.2.1.4 C-H Functionalisation via 1,4-Cobalt Migration
  • 4.2.1.5 Hydroacylation
  • 4.2.2 C-H Functionalisation with Pincer-Type Ligands and Related Well-Defined Cobalt Catalysts
  • 4.3 High-valent Cobalt Catalysis
  • 4.3.1 Chelation-Assisted C-H Functionalisation with Cp*CoIII Catalysts
  • 4.3.1.1 C H Addition to Polar C X Bonds
  • 4.3.1.2 Reaction with Alkynes, Alkenes, and Allenes
  • 4.3.1.3 Reaction with Formal Nitrene or Carbene Precursors
  • 4.3.1.4 Reaction with E-X-type Electrophiles
  • 4.3.1.5 Miscellaneous
  • 4.3.2 Bidentate Chelation-Assisted C-H Functionalisation with CoIII Catalysts
  • 4.3.2.1 Reaction with Alkynes, Alkenes, and Allenes
  • 4.3.2.2 Dehydrogenative Cross-coupling Reactions
  • 4.3.2.3 Carbonylation and Related Transformations
  • 4.3.2.4 Miscellaneous Transformations
  • 4.3.3 Miscellaneous
  • 4.4 Summary and Outlook
  • Abbreviations
  • References

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