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Chemistry of silica and zeolite-based materials : synthesis, characterization and applications /
Chemistry of Silica and Zeolite-Based Materials covers a wide range of topics related to silica-based materials from design and synthesis to applications in different fields of science and technology. Since silica is transparent and inert to the light, it is a very attractive host material for const...
| Clasificación: | Libro Electrónico |
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| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Amsterdam, Netherlands . :
Elsevier,
[2019]
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| Colección: | Chemical, Physical and Biological Aspects of Confined Systems ;
2 |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Chemistry of Silica and Zeolite-Based Materials; Copyright Page; Contents; List of Contributors; About the Editors; Preface; 1 Synthesis and Applications of Periodic Mesoporous Organosilicas; 1.1 Introduction; 1.2 Synthesis of Periodic Mesoporous Organosilicas; 1.2.1 Fundamentals of Periodic Mesoporous Organosilica Synthesis; 1.2.2 Functional Periodic Mesoporous Organosilicas; 1.2.3 Control of the Arrangement of Organic Moieties in the Pore Walls; 1.3 Applications; 1.3.1 Light-Harvesting Antennae; 1.3.2 Periodic Mesoporous Organosilica-Based Photocatalysis
- 1.3.3 Hole-Transporting Properties and Photovoltaic Devices1.3.4 Substrates for Laser Desorption/Ionization Mass Spectrometry; 1.3.5 Solid Supports for Metal Complex Catalysts; 1.3.5.1 Phenylene-Periodic Mesoporous Organosilica; 1.3.5.2 Phenylpyridin-Periodic Mesoporous Organosilica; 1.3.5.3 2,2′-Bipyridine-Periodic Mesoporous Organosilica; 1.3.5.4 Catalysis of Well-Defined Metal Complexes on 2,2′-Bipyridine-Periodic Mesoporous Organosilica; 1.4 Conclusion and Outlook; References; 2 Silica Hosts for Acid and Basic Organosilanes: Preparation, Characterization, and Application in Catalysis
- 2.1 Introduction2.2 Functionalization of Mesoporous Silicas by Organosilanes Containing Acidic Groups; 2.2.1 Hybrid Materials Containing Strong -SO3H Acidic Centers; 2.2.1.1 Different Ways for Preparation of Functionalized Materials; 2.2.1.2 The Role of Additives in Silica Support; 2.2.1.3 Characterization of Surface Properties; 2.2.1.4 Application in Catalysis; 2.2.2 Hybrid Materials Containing Moderate Acidic -PO3H2 and Weak Acidic -COOH Groups; 2.2.2.1 Preparation and Characterization; 2.2.2.2 Application in Catalysis
- 2.3 Functionalization of Mesoporous Silicas by Organosilanes Containing Basic Centers2.3.1 Preparation of Mesoporous Silicas Functionalized With Basic Species Containing Nitrogen; 2.3.2 Characterization of Surface Properties of Hybrid Materials Containing Basic Species; 2.3.3 Application in Catalysis; 2.4 Multifunctional Catalysts Based on Amino-Grafted Silica Hybrid Materials; 2.4.1 Base-BrØnsted Acid Pairs on Silica Surface; 2.4.2 Base-Lewis Acid Pairs on Silica Surface; 2.4.3 Base-Redox Pairs on Silica Surface; 2.4.4 Trifunctional Mesoporous Silica Containing Amine
- 2.5 Transition Metals Anchored on Mesoporous Silicas Functionalized With Organosilanes2.5.1 Location of Organosilane; 2.5.2 Position of Metal Particles and Metal Dispersion; 2.5.3 Role of Mature of Functional Group in Organosilane; 2.6 Concluding Remarks; Acknowledgments; References; 3 Catalytic Interconversion of Sugars with Zeolite and Zeotype Materials; 3.1 Introduction; 3.2 Isomerization of Glucose; 3.2.1 Sn-Modified Zeolite Catalysts; 3.2.2 Other Zeolite Catalysts; 3.3 Isomerization of Xylose; 3.4 Isomerization of Erythrose; 3.5 Isomerization of Dihydroxyacetone; 3.5.1 Sn-Beta Zeolite