Cargando…
Thermodynamics of surfaces and capillary systems /
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
London, UK : Hoboken, NJ :
ISTE, Ltd. ; John Wiley & Sons,
2016.
|
| Colección: | Chemical thermodynamics set ;
v. 7. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Title Page; Copyright; Contents; Preface; Notations and Symbols; 1: Liquid Surfaces; 1.1. Mechanical description of the interface between a liquid and its vapor; 1.1.1. Gibbs' and Young's interface models; 1.1.2. Mechanical definition of the surface tension of the liquid; 1.1.3. Influence of the curvature of a surface
- Laplace's law; 1.2. Thermodynamic approach to the liquid-vapor interface; 1.2.1. Potential functions; 1.2.2. Functions of state of surface; 1.2.3. Equivalence between surface tension and interface energy between two fluids.
- 1.2.4. Sign of the energy associated with the surface of a pure liquid1.2.5. Extent of the area of the surface of a liquid; 1.3. Influence of temperature on surface energy; 1.4. Surface latent heat; 1.5. Surface specific heat capacity; 1.6. Influence of pressure on the surface tension of a liquid; 1.7. Evaluation of the surface energy of a pure liquid; 2: Interfaces Between Liquids and Fluid Solutions; 2.1. Surface concentrations and surface excess; 2.2. Thermodynamics of interfaces of polycomponent liquid-fluid systems; 2.2.1. Complete chemical potential of a component in a phase.
- 2.2.2. Chemical potentials and lateral chemical potentials2.2.3. Conditions of equilibrium in a capillary system; 2.2.4. Gibbs-Duhem relation for surface phenomena; 2.2.5. Adsorption and Gibbs isotherm; 2.3. Surface tension of solutions; 2.3.1. Perfect solutions; 2.3.2. Highly-dilute solutions; 2.4. Interface tension between two liquids; 2.5. Energy of adhesion of two liquids; 2.6. Spreading of a liquid over another liquid; 2.7. Example of the microscopic modeling of surfaces of solutions: the monolayer model for strictly-regular solutions; 2.7.1. Presentation of the model.
- 2.7.2. Chemical potentials of the surface and bulk components of a strictly-regular solution2.7.3. Surface tension and composition of the surface layer of a strictly-regular solution; 2.7.4. Monolayer model and interface tension between two strictly-regular solutions; 2.7.5. Critique of the monomolecular layer model; 3: Surfaces of Solids and Interfaces; 3.1. Surface tension and the surface energy of solids; 3.2. Surface energy of a pure crystallized solid: the macroscopic approach; 3.3. Surface energy in a mesoscopic model; 3.4. Effective surface energy: the Wulff crystal.
- 3.5. Interfacial energy between two solids3.6. Interfaces between pure solids and liquids; 3.6.1. Spreading and angle of contact of a liquid on a solid; 3.6.2. Work of adhesion between a liquid and a solid; 3.6.3. Solid surface in contact with two liquids: displacement of one liquid by another; 3.6.4. Conditions of stability of solid particles at fluid interfaces; 3.7. Adsorption of elements of a liquid solution by a solid; 3.8. Electrocapillary phenomena; 3.8.1. Definition of electrocapillarity; 3.8.2. Gibbs-Lippmann formula and Lippmann's formula.