Fluoroelastomers handbook : the definitive user's guide /
Fluoroelastomers Handbook: The Definitive User's Guide, Second Edition is a comprehensive reference on fluoroelastomer chemistry, processing technology, and applications. It is a must-have reference for materials scientists and engineers in the automotive, aerospace, chemical, chemical process,...
Clasificación: | Libro Electrónico |
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Autor principal: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Cambridge, MA :
William Andrew is an imprint of Elsevier,
[2016]
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Edición: | Second edition. |
Colección: | PDL handbook series.
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Fluoroelastomers Handbook; Copyright Page; Contents; Preface to the Second Edition; Preface to the First Edition; I. Fluoroelastomers Overview; 1 Fundamentals; 1.1 Introduction; 1.2 Scope: Fluorocarbon Elastomers; 1.3 Nature of Fluoroelastomers; 1.4 Fundamental Properties; 1.4.1 VDF Copolymers; 1.4.2 TFE/Olefin Copolymers; 1.4.3 Perfluoroelastomers; 1.4.4 Other Compositions; 1.5 Developmental History: Compositions, Cure Technology; 1.6 Major Uses of Fluoroelastomers; 1.7 Producers of Fluoroelastomers; References; 2 Market and Consumption Statistics and Future Trends
- 2.1 Introduction2.2 Consumption, Demand, and Trends; References; 3 Fluoroelastomer Composition and Properties; 3.1 Major Families of Fluorocarbon Elastomers; 3.2 VDF/HFP/TFE Elastomers; 3.3 VDF/PMVE/TFE Elastomers; 3.4 TFE/PMVE Perfluoroelastomers; 3.5 TFE/P Elastomers; 3.6 E/TFE/PMVE Elastomers; References; II. Fluoroelastomers Technology; 4 Fluoroelastomer Monomers; 4.1 Introduction; 4.2 Vinylidene Fluoride; 4.2.1 VDF Properties; 4.2.2 VDF Synthesis; 4.3 Tetrafluoroethylene; 4.3.1 TFE Properties; 4.3.2 TFE Synthesis; 4.4 Hexafluoropropylene; 4.4.1 HFP Properties; 4.4.2 HFP Synthesis
- 4.5 Perfluoro(methyl vinyl ether)4.5.1 PMVE Properties; 4.5.2 PMVE Synthesis; 4.6 Olefins: Ethylene and Propylene; 4.7 Cure-Site Monomers; 4.7.1 Types of Cure-Site Monomers; 4.7.2 Halogenated Vinyl Monomers; 4.7.3 Functional Vinyl Ethers; 4.8 Safety Aspects of Monomer Handling; 4.8.1 Toxicity Considerations; 4.8.2 Flammability; 4.8.3 Explosivity; References; 5 Production of Fluoroelastomers; 5.1 Introduction; 5.2 General Process Description; 5.3 Free Radical Copolymerization; 5.3.1 General Reaction Scheme; 5.3.2 Copolymer Composition Relationships; 5.3.3 Monomer Reactivity Ratios
- 5.4 Emulsion Polymerization5.4.1 Emulsion Polymerization Kinetics; 5.4.2 Continuous Emulsion Polymerization; 5.4.3 Semibatch Emulsion Polymerization; 5.5 Suspension Polymerization; 5.5.1 Polymer Compositions; 5.5.2 Polymerization Mechanism and Kinetics; 5.5.3 Reactor Design and Operation; 5.5.4 Polymerization Control; 5.6 Process Conditions and Polymer Characteristics; 5.6.1 Molecular Weight Distribution; 5.6.2 End Groups; 5.6.3 Composition and Monomer Sequence Distributions; 5.7 Monomer Recovery; 5.8 Isolation; 5.9 Process Safety; 5.10 Commercial Process Descriptions; References
- 6 Cure Systems for Fluoroelastomers6.1 Introduction; 6.2 VDF/HFP/TFE Copolymers: Diamine, Bisphenol, and Peroxide; 6.2.1 Diamine Cure; 6.2.2 Bisphenol Cure; 6.2.3 Peroxide Cure; 6.3 VDF/PMVE/TFE Elastomers: Peroxide (Bisphenol); 6.4 Perfluoroelastomers-Various Systems; 6.5 TFE/Propylene Elastomers: Peroxide, Bisphenol; 6.6 Ethylene/TFE/PMVE Elastomers: Peroxide, Bisphenol; 6.7 Cross-Linking by Ionizing Radiation; References; 7 Processing of Fluoroelastomers; 7.1 Introduction; 7.2 Compounding; 7.3 Mixing; 7.3.1 Handling and Storing of Compounding Ingredients; 7.3.2 Mill Mixing