Cargando…
The aqueous chemistry of oxides /
The Aqueous Chemistry of Oxides is a comprehensive reference volume and special topics textbook that explores all of the major chemical reactions that take place between oxides and aqueous solutions. The book highlights the enormous impact that oxide-water reactions have in advanced technologies, ma...
| Clasificación: | Libro Electrónico |
|---|---|
| Autores principales: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York, NY :
Oxford University Press,
2016.
|
| Edición: | First edition. |
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Contents; Cover Art Figure Captions; Plates; PART ONE An Introduction to Oxides; 1. The Importance of Oxides and Oxide-Water Reactions; 1.1. Geochemical Importance; 1.2. The Technological Importance of Oxides; 1.3. The Physical Properties of Oxides; 1.4. The Chemical Properties of Oxides; 1.5. The Aqueous Chemistry of Oxides: A Road Map; 2. An Overview of Oxide Structures and Compositions; 2.1. Local Oxide Structures: The Oxide (O2- ) Anion; 2.2. Predicting Oxygen-Bonding Configurations: An Introduction to the Formal-Charge Model; 2.3. Close-Packed Crystalline Lattices.
- 2.4. Oxides Containing Octahedral Cations2.5. Oxides Containing Tetrahedral Cations; 2.6. Oxides Containing Both Octahedral and Tetrahedral Cations; 2.7. Engineered Oxide Nanostructures; PART TWO Fundamental Oxide Reactions in Aqueous Solutions; 3. The Structure and Properties of Water; 4. Solvated Ions in Water; 4.1. Introduction; 4.2. Solvated Anions; 4.3. Solvated Cations; 4.4. The Structure of Solvated Cations; 4.5. The Acid-Base Properties of the First Solvation Shell; 4.6. Using Formal Charge Models to Predict and Rationalize pKa Values; 4.7. An Introduction to Ligand-Exchange Reactions.
- 4.8. The Thermodynamics of Ligand Exchange4.9. The Kinetics of Ligand-Exchange Reactions; 5. The Hydrolysis Products: Soluble Multi-cation Clusters; 5.1. Introduction; 5.2. Structures of the Hydrolysis Products; 5.3. The Occurrence of Hydrolysis Products: Reading Hydrolysis Diagrams; 5.4. Trends in Cation Hydrolysis; 5.5. Hydrolysis Diagrams as Predictors of Oxide Chemistry; 5.6. Speciation Diagrams Involving Foreign Ligands; 5.7. The Acid-Base Chemistry of Multi-Cation Hydrolysis Products; 5.8. Mechanisms for Reversible Condensation Reactions.
- 5.9. Hydrolysis Product Stability: Dimer Reaction Pathways5.10. The Stability of Larger Hydrolysis Products; 5.11. The Polyoxometalates: Covalent Oxide Clusters; 6. The Chemistry of Extended Oxide Surfaces; 6.1. Introduction; 6.2. Ideal Oxide Surfaces in the Absence of Water; 6.3. Interactions between Pristine Surfaces and Water Molecules; 6.4. The Interface between Liquid Water and Oxide Surfaces; 6.5. Acid-Base Reactions on Oxide Surfaces in Liquid Water; 6.6. Ligand-Exchange Reactions Involving Water: Oxide Dissolution; 6.7. Reactions Involving Foreign Ligands.
- PART THREE The Aqueous Synthesis and Processing of Oxides7. Nucleation and Growth of Solid Oxide and Hydroxide Phases; 7.1. Introduction; 7.2. Classic Nucleation Theory; 7.3. Chemical Control of Oxide Nucleation; 7.4. Classic Growth Theory; 8. The Colloidal Chemistry of Oxides; 8.1. Introduction; 8.2. Fundamental Colloidal Interactions; 8.3. The Chemical Origin of Surface Charge; 8.4. The Impact of Aggregation on the Properties of Colloidal Slurries; 8.5. Ceramic Processing: The Role of Organic Additives; 9. Bio-inspired Synthesis of Oxide Nanostructures; 9.1. Introduction.