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Sustainable catalysis, Without metals or other endangered elements. Part 1 /
Catalysis is a fundamentally sustainable process which can be used to produce a wide range of chemicals and their intermediates. Focussing on those catalytic processes which offer the most sustainability, this two-part book explores recent developments in this field, as well as examining future chal...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
[Cambridge] :
Royal Society of Chemistry,
[2015]
|
| Colección: | RSC green chemistry series ;
40. |
| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 245 | 0 | 0 | |a Sustainable catalysis, |p Without metals or other endangered elements. |n Part 1 / |c [editor] Michael North. |
| 246 | 3 | 0 | |a Without metals or other endangered elements. |n Part 1 |
| 264 | 1 | |a [Cambridge] : |b Royal Society of Chemistry, |c [2015] | |
| 264 | 4 | |c ©2016 | |
| 300 | |a 1 online resource | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 490 | 1 | |a RSC green chemistry ; |v 40 | |
| 520 | |a Catalysis is a fundamentally sustainable process which can be used to produce a wide range of chemicals and their intermediates. Focussing on those catalytic processes which offer the most sustainability, this two-part book explores recent developments in this field, as well as examining future challenges. Focussing on catalysis without metals or other endangered elements, each chapter covers a different type of organocatalyst. Beginning with chapters on acid and base catalysis, the book then concentrates on asymmetric catalysis. Several chapters cover pyrrolidine-based and cinchona alkaloid-based catalysts, whilst other chapters examine further organoctalysts which are constructed only from sustainable elements. Together with Sustainable Catalysis: With Non-endangered Metals, these books examine the progress in sustainable catalysis in all areas of chemistry, and are an important reference for researchers working in catalysis and green chemistry. | ||
| 500 | |a Title from publisher supplied information (Royal Society of Chemistry; title not viewed). | ||
| 504 | |a Includes bibliographical references and index. | ||
| 505 | 0 | |6 880-01 |a Cover; Contents; Preface; References; Part 1; Chapter 1 Introduction; 1.1 Introduction; 1.2 Historical Perspective; References; Chapter 2 Base Catalysis in Nonasymmetric Synthesis; 2.1 Nitrogenated Lewis Bases; 2.1.1 Acylations and Silylations of Alcohols and Amines, C-Acylation; 2.1.2 Amide and Ester Formation; 2.1.3 CO2 Activation; 2.1.4 Baylis-Hillman Reactions; 2.1.5 Aldol Reactions and Unsaturated Carbonyl Compound Formation; 2.1.6 Cycloadditions; 2.1.7 Conjugate Additions; 2.1.8 Synthesis of Heterocycles; 2.1.9 Methylation and Transesterification Reactions; 2.1.10 Bromination Reactions. | |
| 505 | 8 | |a 2.1.11 Miscellaneous Reactions2.2 Proline and Proline Derivatives; 2.2.1 Knoevenagel Reaction in Domino Methodologies; 2.2.2 Aldol and Mannich Reactions; 2.2.3 Multicomponent Reactions; 2.2.4 Synthesis of Aromatic Compounds. (Formal) Cycloaddition Reactions; 2.3 N-Heterocyclic Carbenes; 2.3.1 Acyl Anion Chemistry; 2.3.2 Enolate and Homoenolate Chemistry; 2.3.3 Dipolar Cycloadditions; 2.3.4 Transesterification Reactions; 2.3.5 Redox Reactions with NHCs; 2.3.6 Nucleophilic Catalysis; 2.3.7 Polymerisations; References; Chapter 3 Homogeneous Acid Catalysis in Nonasymmetric Synthesis. | |
| 505 | 8 | |a 3.1 Historical Perspective3.2 Mechanisms of Acid Catalysis; 3.3 Solvent Effects on Acid Catalysis; 3.3.1 Acid Catalysis in High-temperature and Supercritical Fluids; 3.3.2 Acid Catalysis in Ionic Liquids; 3.4 Recent Developments in Acid-catalysed Reactions in Green Chemistry; 3.5 Conclusions and Future Outlook; References; Chapter 4 Heterogeneous Acid Catalysis in Nonasymmetric Synthesis; 4.1 Introduction; 4.2 Major Groups of Solid Acid Catalysts; 4.2.1 Sulfated Metal Oxides; 4.2.2 Sulfated Carbons; 4.3 Uses of Heterogeneous Acid Catalysts; 4.3.1 Friedel-Crafts Acylation. | |
| 546 | |a English. | ||
| 590 | |a Knovel |b ACADEMIC - Chemistry & Chemical Engineering | ||
| 650 | 0 | |a Catalysis. | |
| 650 | 6 | |a Catalyse. | |
| 650 | 7 | |a Sustainability. |2 bicssc | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Physical & Theoretical. |2 bisacsh | |
| 650 | 7 | |a Catalysis |2 fast | |
| 700 | 1 | |a North, Michael, |d 1964- |e editor. | |
| 700 | 1 | |a Clark, James H., |e editor. | |
| 776 | 0 | 8 | |i Print version: |t Sustainable catalysis, without metals or other endangered elements. Part 1. |d Cambridge, England : Royal Society of Chemistry, ©2016 |h xxv, 366 pages |k RSC green chemistry series ; Number 40 |x 1757-7039 |z 9781782626404 |
| 830 | 0 | |a RSC green chemistry series ; |v 40. | |
| 856 | 4 | 0 | |u https://appknovel.uam.elogim.com/kn/resources/kpSCWMOEE6/toc |z Texto completo |
| 880 | 8 | |6 505-00/(S |a 4.3.2 Heterogeneous Acid Catalysts in the Synthesis of Biodiesel4.3.3 Production of Furans from Biomass-derived Sources; 4.4 Conclusions; References; Chapter 5 Proline as an Asymmetric Organocatalyst; 5.1 The Rediscovery of Proline Catalysis: Asymmetric Aldol Reactions; 5.2 Mechanistic Considerations; 5.3 Michael Reactions; 5.4 Mannich Reactions; 5.5 Morita-Baylis-Hillman Reactions; 5.6 α-Functionalisation ; 5.6.1 α-Amination of Ketones and Aldehydes ; 5.6.2 Aminoxylation of Ketones and Aldehydes; 5.6.3 α-Alkylation ; 5.6.4 α-Allylation ; 5.6.5 α-Anomerisation ; 5.6.6 α-Fluorination. | |
| 880 | 8 | |6 505-01/(S |a 5.6.7 α-Chlorination 5.6.8 α-Sulfamidation of α-Branched Aldehydes ; 5.7 Cycloadditions; 5.7.1 Diels-Alder Reactions; 5.7.2 Knoevenagel-Hetero-Diels-Alder Reactions; 5.7.3 1,3-Dipolar Cycloaddition; 5.7.4 [3+2] Cyclisation; 5.8 Formation/Ring Opening of Epoxides and Cyclopropanes; 5.9 Oxidative Coupling; 5.10 Selected Process-scale Application of Proline Catalysis; 5.11 Where to, Asymmetric Proline Catalysis; 5.12 Expansion of the Field of Proline Organocatalysis; References; Chapter 6 Prolinamides as Asymmetric Organocatalysts; 6.1 Aldol Reaction. | |
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