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Polymer photovoltaics : materials, physics, and device engineering /

Polymer solar cells have gained much attention as they offer a potentially economic and viable way of commercially manufacturing lightweight, flexible and low-cost photovoltaics. With contributions from leading scientists, Polymer Photovoltaics provides an international perspective on the latest res...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Huang, Fei (Writer on polymer optoelectronics) (Editor ), Yip, Hin-Lap (Editor ), Cao, Yong (Writer on optoelectronics) (Editor )
Formato: Electrónico eBook
Idioma:Inglés
Publicado: [Cambridge] : Royal Society of Chemistry, [2015]
Colección:RSC polymer chemistry series ; 17.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover; Polymer Photovoltaics; Preface; Contents; Chapter 1
  • New Chemistry for Organic Photovoltaic Materials; 1.1 Introduction; 1.2 Stille Polycondensation; 1.2.1 History and Mechanism of the Stille Coupling Reaction; 1.2.2 The Reaction Catalyst, Ligand and Solvent; 1.2.3 Monomers; 1.2.4 Advantages of the Stille Polycondensation; 1.2.5 Disadvantages of the Stille Polycondensation; 1.2.6 Examples of Synthesis of D-A Conjugated Polymers by Stille Coupling; 1.3 Suzuki Polycondensation; 1.3.1 History and Mechanism of the Suzuki Coupling Reaction; 1.3.2 Mechanism of the Suzuki Coupling Reaction.
  • 1.3.3 Catalyst, Ligand and Solvents1.3.4 Monomers; 1.3.5 Advantages of the Suzuki Coupling Reaction; 1.3.6 Drawbacks of the Suzuki Coupling Reaction; 1.3.7 Examples of the Suzuki Coupling Reaction; 1.4 C-H Activation/Direct Arylation Polycondensation; 1.4.1 History and Mechanism of the C-H Activation Polycondensation; 1.4.2 Mechanistic Insight; 1.4.3 Catalysts, Additive and Solvents; 1.4.4 Monomers; 1.4.5 Advantages of the Direct Arylation Polycondensation; 1.4.6 Drawbacks of the Direct Arylation Polycondensation; 1.4.7 Examples of the Direct Arylation Polycondensation; References.
  • Chapter 2
  • New Polymer Donors for Polymer Solar Cells2.1 Introduction; 2.2 Design Requirements and Strategies for Highly Efficient Polymer Donors; 2.2.1 Design Requirements for Highly Efficient Polymer Donors; 2.2.1.1 Solubility; 2.2.1.2 Absorption Spectrum; 2.2.1.3 Energy Level; 2.2.1.4 Mobility; 2.2.1.5 Morphology; 2.2.2 Design Strategies for Highly Efficient Polymer Donors; 2.2.2.1 Tuning the Backbone; 2.2.2.2 Tuning the Side Chain; 2.2.2.3 Post-Production; 2.3 Novel D-A Copolymers for Polymer Solar Cells; 2.3.1 Design Considerations for D-A Polymer Donors.
  • 2.3.2 D-A Copolymers Based on Thiophene Units2.3.3 D-A Copolymers Based on Bridged Biphenyl Derivatives; 2.3.4 D-A Copolymers Based on Bridged Bithiophene Derivatives; 2.3.5 D-A Copolymers Based on Benzodithiophene Analogues; 2.3.6 D-A Copolymers Based on Indacenodithiophene Analogues; 2.4 Novel Terpolymer Donors for Polymer Solar Cells; 2.4.1 Design Considerations for Terpolymer Donors; 2.4.2 Novel Terpolymers Based on One Donor Unit; 2.4.3 Novel Terpolymers Based on Two Donor Units; 2.5 Summary and Outlook; References.
  • Chapter 3
  • Fullerene Derivatives as Electron Acceptors in Polymer Solar Cells3.1 Design Concepts of Fullerene Acceptors; 3.2 PCBM; 3.2.1 Synthesis of PCBM; 3.2.2 Fundamental Properties of PCBMs; 3.2.3 PCBM Derivatives in Photovoltaic Applications; 3.2.4 [70]PCBM; 3.2.5 Mix-PCBM; 3.3 1,4-Di(organo)fullerene; 3.3.1 Silylmethylfullerene (SIMEF); 3.3.2 1,4-Di(aryl)fullerene; 3.4 Diphenylmethanofullerene (DPM); 3.4.1 Synthesis of Diphenylmethanofullerene; 3.4.2 Photovoltaic Application; 3.5 Fulleropyrrolidine; 3.5.1 Synthesis of Fulleropyrrolidine; 3.5.2 Photovoltaic Applications.