Polymer photovoltaics : materials, physics, and device engineering /
Polymer solar cells have gained much attention as they offer a potentially economic and viable way of commercially manufacturing lightweight, flexible and low-cost photovoltaics. With contributions from leading scientists, Polymer Photovoltaics provides an international perspective on the latest res...
Clasificación: | Libro Electrónico |
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Otros Autores: | , , |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
[Cambridge] :
Royal Society of Chemistry,
[2015]
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Colección: | RSC polymer chemistry series ;
17. |
Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover; Polymer Photovoltaics; Preface; Contents; Chapter 1
- New Chemistry for Organic Photovoltaic Materials; 1.1 Introduction; 1.2 Stille Polycondensation; 1.2.1 History and Mechanism of the Stille Coupling Reaction; 1.2.2 The Reaction Catalyst, Ligand and Solvent; 1.2.3 Monomers; 1.2.4 Advantages of the Stille Polycondensation; 1.2.5 Disadvantages of the Stille Polycondensation; 1.2.6 Examples of Synthesis of D-A Conjugated Polymers by Stille Coupling; 1.3 Suzuki Polycondensation; 1.3.1 History and Mechanism of the Suzuki Coupling Reaction; 1.3.2 Mechanism of the Suzuki Coupling Reaction.
- 1.3.3 Catalyst, Ligand and Solvents1.3.4 Monomers; 1.3.5 Advantages of the Suzuki Coupling Reaction; 1.3.6 Drawbacks of the Suzuki Coupling Reaction; 1.3.7 Examples of the Suzuki Coupling Reaction; 1.4 C-H Activation/Direct Arylation Polycondensation; 1.4.1 History and Mechanism of the C-H Activation Polycondensation; 1.4.2 Mechanistic Insight; 1.4.3 Catalysts, Additive and Solvents; 1.4.4 Monomers; 1.4.5 Advantages of the Direct Arylation Polycondensation; 1.4.6 Drawbacks of the Direct Arylation Polycondensation; 1.4.7 Examples of the Direct Arylation Polycondensation; References.
- Chapter 2
- New Polymer Donors for Polymer Solar Cells2.1 Introduction; 2.2 Design Requirements and Strategies for Highly Efficient Polymer Donors; 2.2.1 Design Requirements for Highly Efficient Polymer Donors; 2.2.1.1 Solubility; 2.2.1.2 Absorption Spectrum; 2.2.1.3 Energy Level; 2.2.1.4 Mobility; 2.2.1.5 Morphology; 2.2.2 Design Strategies for Highly Efficient Polymer Donors; 2.2.2.1 Tuning the Backbone; 2.2.2.2 Tuning the Side Chain; 2.2.2.3 Post-Production; 2.3 Novel D-A Copolymers for Polymer Solar Cells; 2.3.1 Design Considerations for D-A Polymer Donors.
- 2.3.2 D-A Copolymers Based on Thiophene Units2.3.3 D-A Copolymers Based on Bridged Biphenyl Derivatives; 2.3.4 D-A Copolymers Based on Bridged Bithiophene Derivatives; 2.3.5 D-A Copolymers Based on Benzodithiophene Analogues; 2.3.6 D-A Copolymers Based on Indacenodithiophene Analogues; 2.4 Novel Terpolymer Donors for Polymer Solar Cells; 2.4.1 Design Considerations for Terpolymer Donors; 2.4.2 Novel Terpolymers Based on One Donor Unit; 2.4.3 Novel Terpolymers Based on Two Donor Units; 2.5 Summary and Outlook; References.
- Chapter 3
- Fullerene Derivatives as Electron Acceptors in Polymer Solar Cells3.1 Design Concepts of Fullerene Acceptors; 3.2 PCBM; 3.2.1 Synthesis of PCBM; 3.2.2 Fundamental Properties of PCBMs; 3.2.3 PCBM Derivatives in Photovoltaic Applications; 3.2.4 [70]PCBM; 3.2.5 Mix-PCBM; 3.3 1,4-Di(organo)fullerene; 3.3.1 Silylmethylfullerene (SIMEF); 3.3.2 1,4-Di(aryl)fullerene; 3.4 Diphenylmethanofullerene (DPM); 3.4.1 Synthesis of Diphenylmethanofullerene; 3.4.2 Photovoltaic Application; 3.5 Fulleropyrrolidine; 3.5.1 Synthesis of Fulleropyrrolidine; 3.5.2 Photovoltaic Applications.