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Engineering catalysis /

With well over 90% of all processes in the industrial chemical production being of catalytic nature, catalysis is a mature though ever interesting topic. The idea of this book is to tackle various aspects of heterogeneous catalysis from the engineering point of view and go all the way from engineeri...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Murzin, Dmitry, 1963-
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Berlin : Walter de Gruyter GmbH, [2013]
Colección:De Gruyter graduate.
Temas:
Acceso en línea:Texto completo

MARC

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100 1 |a Murzin, Dmitry,  |d 1963- 
245 1 0 |a Engineering catalysis /  |c Dmitry Yu. Murzin. 
264 1 |a Berlin :  |b Walter de Gruyter GmbH,  |c [2013] 
300 |a 1 online resource (xi, 364 pages) :  |b illustrations (some color 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
490 1 |a De Gruyter Graduate 
504 |a Includes bibliographical references and index. 
588 0 |a Print version record. 
505 0 |a Preface; 1 The basics; 1.1 Catalytic concepts; 1.1.1 Definitions; 1.1.2 Length and time scales in catalysis; 1.1.3 Catalytic trinity: activity, selectivity, stability; 1.1.4 Composition of catalysts; 1.2 Reactivity of solids; 1.2.1 Physisorption and chemisorption; 1.2.2 Basics of chemisorption theory; 1.2.3 Surface crystallography; 1.2.4 Mechanisms of some catalytic reactions; 1.3 Catalysis in industry; References; 2 Engineering catalysts; 2.1 Catalyst design; 2.1.1 Being in shape; 2.1.2 Scaling of catalysts; 2.2 Toolbox in catalysis; 2.2.1 General overview of the characterization methods. 
505 8 |a 2.2.2 Adsorption methods2.2.3 Physisorption methods; 2.2.4 Chemisorption; 2.2.5 Temperature-programmed methods; 2.2.6 Calorimetry; 2.2.7 X-ray diffraction; 2.2.8 X-ray photoelectron spectroscopy and X-ray fluorescence; 2.2.9 Infrared and Raman spectroscopies; 2.2.10 Catalyst particle size measurements; 2.2.11 Electron paramagnetic/spin resonance; 2.2.12 Mössbauer spectroscopy; 2.2.13 X-ray absorption spectroscopy; 2.2.14 Nuclear magnetic resonance; 2.2.15 Imaging of catalysts; 2.2.16 Catalytic reactions: product analysis; 2.2.17 Theory as a part of a toolbox. 
505 8 |a 2.3 Preparation of catalytic materials2.3.1 General overview; 2.3.2 Unsupported metals; 2.3.3 Preparation of bulk oxides by precipitation; 2.3.4 Heteropolyacids; 2.3.5 Catalysts supports; 2.3.6 Supported catalysts; 2.3.7 Catalyst forming operations; References; 3 Engineering reactions; 3.1 Introduction; 3.2 Thermodynamics; 3.3 Kinetics; 3.3.1 Definitions; 3.3.2 Reaction mechanism; 3.3.3 Kinetics of complex reactions; 3.3.4 Relationship between thermodynamics and kinetics; 3.3.5 Non-ideal surfaces; 3.4 Kinetic aspects of selectivity; 3.4.1 Structure sensitivity. 
505 8 |a 3.4.2 Mechanism-free kinetics -- kinetic polynomial3.4.3 What is behind a rate constant?; 3.4.4 Dynamic catalysis; 3.4.5 Deactivation; 3.4.6 Mathematical treatment of experimental data; 3.5 Mass transfer; 3.5.1 Diffusion effects in heterogeneous catalysis; 3.5.2 Reactor dependent external diffusion (interphase mass transfer, film diffusion); 3.5.3 Calculation of diffusion coefficients; 3.5.4 Size dependent internal (pore) diffusion; 3.5.5 Non-isothermal conditions; 3.5.6 Multiple reactions and diffusional limitations; 3.5.7 Diffusion in micropores. 
505 8 |a 3.5.8 Criteria for the absence of diffusional limitations3.6 Catalytic reactors; 3.6.1 Laboratory reactors; 3.6.2 Industrial reactors; 3.6.3 Two-phase reactors; 3.6.4 Three-phase catalytic reactors; 3.6.5 Reactor modeling; 3.6.6 Catalyst handing in a plant; References; 4 Engineering technology; 4.1 General structures of chemical processes; 4.1.1 Safety in design; 4.1.2 Conceptual process design: examples; 4.1.3 Conceptual process design: general comments; 4.1.4 Reactor selection; 4.2 (Petro)chemical industry; 4.3 Fluid catalytic cracking; 4.3.1 Feedstock; 4.3.2 Reactions/mechanism. 
520 |a With well over 90% of all processes in the industrial chemical production being of catalytic nature, catalysis is a mature though ever interesting topic. The idea of this book is to tackle various aspects of heterogeneous catalysis from the engineering point of view and go all the way from engineering of catalysis, catalyst preparation, characterization, reaction kinetics, mass transfer to catalytic reactors and the implementation of catalysts in chemical technology. Aimed for graduate students it is also a useful resource for professionals coming from the more academic side. 
546 |a English. 
590 |a Knovel  |b ACADEMIC - Biochemistry, Biology & Biotechnology 
590 |a Knovel  |b ACADEMIC - Chemistry & Chemical Engineering 
650 0 |a Catalysis. 
650 0 |a Catalysis  |x Industrial applications. 
650 0 |a Chemical reactors. 
650 0 |a Chemical engineering. 
650 6 |a Catalyse. 
650 6 |a Catalyse  |x Applications industrielles. 
650 6 |a Génie chimique. 
650 7 |a chemical engineering.  |2 aat 
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650 7 |a TECHNOLOGY & ENGINEERING  |x Chemical & Biochemical.  |2 bisacsh 
650 7 |a Catalysis  |2 fast 
650 7 |a Chemical engineering  |2 fast 
650 7 |a Chemical reactors  |2 fast 
650 7 |a Technische Chemie  |2 gnd 
650 7 |a Katalyse  |2 gnd 
650 7 |a Katalysator  |2 gnd 
650 7 |a Heterogene Katalyse  |2 gnd 
650 7 |a Online-Ressource  |2 gnd 
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830 0 |a De Gruyter graduate. 
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