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The art of problem solving in organic chemistry /
This long-awaited new edition helps students understand and solve the complex problems that organic chemists regularly face, using a step-by-step method and approachable text. With solved and worked-through problems, the author orients discussion of each through the application of various problem-so...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Hoboken, New Jersey :
Wiley,
2014.
|
| Edición: | Second edition. |
| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 100 | 1 | |a Alonso-Amelot, Miguel E., |e author. | |
| 245 | 1 | 4 | |a The art of problem solving in organic chemistry / |c Miguel E. Alonso-Amelot, University of the Andes, Department of Chemistry, Merida, Venezuela. |
| 250 | |a Second edition. | ||
| 264 | 1 | |a Hoboken, New Jersey : |b Wiley, |c 2014. | |
| 300 | |a 1 online resource | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 504 | |a Includes bibliographical references and index. | ||
| 588 | 0 | |a Print version record and CIP data provided by publisher. | |
| 520 | |a This long-awaited new edition helps students understand and solve the complex problems that organic chemists regularly face, using a step-by-step method and approachable text. With solved and worked-through problems, the author orients discussion of each through the application of various problem-solving techniques. Teaches organic chemists structured and logical techniques to solve reaction problems and uses a unique, systematic approach. Stresses the logic and strategy of mechanistic problem solving -- a key piece of success for organic chemistry, beyond just specific reactions and factsHas. | ||
| 505 | 0 | |6 880-01 |a The Art of Problem Solving in Organic Chemistry; Contents; Preface; Text Organization; Reference; Preface to the First Edition; Acknowledgments; 1 Problem Analysis in Organic Reaction Mechanism; 1.1 Overview; 1.2 Introduction; 1.2.1 "Pushing Forward" a Solution in Formal and Exhaustive Terms; 1.2.2 Lessons from this Example; 1.3 Avoiding the Quagmire; 1.4 The Basic Steps of Problem Analysis; 1.4.1 Recognizing the Problem; 1.4.2 Analyzing Problems by Asking the Right Questions, Discarding the Irrelevant; 1.4.3 Drawing a First Outline for Guidance. | |
| 505 | 8 | |a 2.3.4.3 Case C: When Reactivity Patterns Seem to Break Down2.3.5 Issue 5: Electron Traffic and Electronic Density Differences; 2.3.5.1 M0 Metals as Electron Source; 2.3.5.2 Metal Hydrides and Organic Hydrides as Electron Source; 2.3.6 Issue 6: Creating Zones of High Electron Density; 2.3.6.1 The Natural Polarization; 2.3.6.2 Reversing the Natural Polarization; 2.3.7 Issue 7: Electron Flow and Low Electron Density Zones; 2.3.7.1 Identifying LEDZs; 2.3.7.2 Creating a New LEDZ in the Substrate; 2.3.7.3 Finding Unsuspected LEDZs among the Other Reagents in the Mixture. | |
| 505 | 8 | |a 2.3.7.4 When Compounds Show Double Personality2.4 Summing Up; 2.5 A Flowchart of Organized Problem Analysis; References and Notes; 3 Additional Techniques to Postulate Organic Reaction Mechanisms; 3.1 Overview; 3.2 Take Your Time; 3.3 Clear and Informative Molecular Renderings; 3.3.1 The Value of Molecular Sketches; 3.3.2 Two- Versus Three-Dimensional Renderings and the "Flat" Organic Compounds; 3.4 Element and Bond Budgets; 3.5 Looking at Molecules from Various Perspectives; 3.6 Separate the Grain from the Chaff; 3.7 Dissecting Products in Terms of Reactants: Fragmentation Analysis. | |
| 505 | 8 | |a 3.7.1 The Fundamental Proposition3.7.2 Adding Potentially Nucleophilic or Electrophilic Character to Fragments; 3.7.3 When Fragmentation Analysis Fails, Getting Help from Atom Labels; 3.8 Oxidation Levels and Mechanism; 3.8.1 Methods to Estimate Oxidation Status; 3.9 The Functionality Number; 3.9.1 What Exactly Is FN?; 3.9.2 Properties of FN; 3.10 Combining Fragmentation Analysis and Functionality Numbers; 3.11 Summing up; References; 4 Solved Problem Collection; Problem 1; Prolem 1: Discussion; Part I: Explaining Products 2 and 3; References; Problem 2; Problem 2: Discussion. | |
| 506 | |a Access restricted to Ryerson students, faculty and staff. |5 CaOTR | ||
| 590 | |a Knovel |b ACADEMIC - Chemistry & Chemical Engineering | ||
| 650 | 0 | |a Chemistry, Organic. | |
| 650 | 0 | |a Problem solving. | |
| 650 | 6 | |a Chimie organique. | |
| 650 | 6 | |a Résolution de problème. | |
| 650 | 7 | |a organic chemistry. |2 aat | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Organic. |2 bisacsh | |
| 650 | 7 | |a Chemistry, Organic |2 fast | |
| 650 | 7 | |a Problem solving |2 fast | |
| 776 | 0 | 8 | |i Print version: |a Alonso-Amelot, Miguel E. |t Art of problem solving in organic chemistry. |b Second edition. |d Hoboken, New Jersey : John Wiley & Sons, Inc., 2014 |z 9781118530214 |w (DLC) 2014002867 |
| 856 | 4 | 0 | |u https://appknovel.uam.elogim.com/kn/resources/kpAPSOCE05/toc |z Texto completo |
| 880 | 0 | 0 | |6 505-01/(S |g 1. |t Problem Analysis in Organic Reaction Mechanism -- |g 1.1. |t Overview -- |g 1.2. |t Introduction -- |g 1.2.1. |t "Pushing Forward" a Solution in Formal and Exhaustive Terms -- |g 1.2.2. |t Lessons from this Example -- |g 1.3. |t Avoiding the Quagmire -- |g 1.4. |t The Basic Steps of Problem Analysis -- |g 1.4.1. |t Recognizing the Problem -- |g 1.4.2. |t Analyzing Problems by Asking the Right Questions, Discarding the Irrelevant -- |g 1.4.3. |t Drawing a First Outline for Guidance -- |g 1.4.4. |t Asking the Right Questions and Proposing the Right Answers ... is enough-- |g 1.5. |t Intuition and Problem Solving -- |g 1.6. |t Summing Up -- -- |g 2. |t Electron Flow in Organic Reactions -- |g 2.1. |t Overview -- |g 2.2. |t Introduction -- |g 2.3. |t Practical Rules Governing Electron Redeployment -- |g 2.3.1. |t Issue 1: Electrons within Orbitals -- |g 2.3.2. |t Issue 2: Electron Transfer and Stereochemistry -- |g 2.3.3. |t Issue 3: Electron Energy Level and Accessibility -- |g 2.3.4. |t Issue 4: Electron Flow and Molecular Active Sectors -- |g 2.3.4.1. |t Case A: n-π Interactions -- |g 2.3.4.2. |t Case B: π -- σ Interactions -- |g 2.3.4.3. |t Case C: When Reactivity Patterns Seem to Break Down -- |g 2.3.5. |t Issue 5: Electron Traffic and Electronic Density Differences -- |g 2.3.5.1. |t M0 Metals as Electron Source -- |g 2.3.5.2. |t Metal Hydrides and Organic Hydrides as Electron Source -- |g 2.3.6. |t Issue 6: Creating Zones of High Electron Density -- |g 2.3.6.1. |t The Natural Polarization -- |g 2.3.6.2. |t Reversing the Natural Polarization -- |g 2.3.7. |t Issue 7: Electron Flow and Low Electron Density Zones -- |g 2.3.7.1. |t Identifying LEDZs -- |g 2.3.7.2. |t Creating a New LEDZ in the Substrate -- |g 2.3.7.3. |t Finding Unsuspected LEDZs among the Other Reagents in the Mixture -- |g 2.3.7.4. |t When Compounds Show Double Personality -- |g 2.4. |t Summing Up -- |g 2.5. |t A Flowchart of Organized Problem Analysis -- -- |g 3. |t Additional Techniques to Postulate Organic Reaction Mechanisms -- |g 3.1. |t Overview -- |g 3.2. |t Take Your Time -- |g 3.3. |t Clear and Informative Molecular Renderings -- |g 3.3.1. |t The Value of Molecular Sketches -- |g 3.3.2. |t Two- Versus Three-Dimensional Renderings and the "Flat" Organic Compounds -- |g 3.4. |t Element and Bond Budgets -- |g 3.5. |t Looking at Molecules from Various Perspectives -- |g 3.6. |t Separate the Grain from the Chaff -- |g 3.7. |t Dissecting Products in Terms of Reactants: Fragmentation Analysis -- |g 3.7.1. |t The Fundamental Proposition -- |g 3.7.2. |t Adding Potentially Nucleophilic or Electrophilic Character to Fragments -- |g 3.7.3. |t When Fragmentation Analysis Fails, Getting Help from Atom Labels -- |g 3.8. |t Oxidation Levels and Mechanism -- |g 3.8.1. |t Methods to Estimate Oxidation Status -- |g 3.9. |t The Functionality Number -- |g 3.9.1. |t What Exactly Is FN-- |g 3.9.2. |t Properties of FN -- |g 3.10. |t Combining Fragmentation Analysis and Functionality Numbers -- |g 3.11. |t Summing up. |
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