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Molecular theory of capillarity /

History of thought on molecular origins of surface phenomena offers a critical and detailed examination and assessment of modern theories, focusing on statistical mechanics and application of results in mean-field approximation to model systems. Emphasis on liquid-gas surface, with a focus on liquid...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Rowlinson, J. S. (John Shipley), 1926-
Otros Autores: Widom, B.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Mineola, N.Y. : Dover Publications, 2002.
Edición:Dover ed.
Temas:
Acceso en línea:Texto completo

MARC

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100 1 |a Rowlinson, J. S.  |q (John Shipley),  |d 1926- 
245 1 0 |a Molecular theory of capillarity /  |c J.S. Rowlinson and B. Widom. 
250 |a Dover ed. 
260 |a Mineola, N.Y. :  |b Dover Publications,  |c 2002. 
300 |a 1 online resource (xi, 327 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
500 |a Originally published: Oxford, Oxfordshire : Clarendon Press, 1982. 
504 |a Includes bibliographical references and index. 
505 0 0 |g 1  |t Mechanical Molecular Models --  |g 1.2  |t Molecular mechanics  |g 2 --  |g 1.3  |t Capillary phenomena  |g 7 --  |g 1.4  |t The internal energy of a liquid  |g 13 --  |g 1.5  |t The continuous surface profile  |g 16 --  |g 1.6  |t The mean molecular field  |g 17 --  |g 2  |t Thermodynamics --  |g 2.1  |t Thermodynamics and kinetic theory  |g 25 --  |g 2.2  |t The thermodynamics of the surface  |g 26 --  |g 2.3  |t Surface functions  |g 31 --  |g 2.4  |t The spherical surface  |g 38 --  |g 2.5  |t Quasi-thermodynamics -- a first look  |g 43 --  |g 3  |t The Theory of van der Waals --  |g 3.2  |t The surface tension  |g 56 --  |g 3.3  |t Independently variable densities  |g 57 --  |g 3.4  |t Gibbs adsorption equation in the van der Waals theory  |g 62 --  |g 3.5  |t Constraints on the range of fluctuations  |g 64 --  |g 4  |t Statistical Mechanics of the Liquid-Gas Surface --  |g 4.2  |t Distribution and correlation functions  |g 69 --  |g 4.3  |t The pressure tensor  |g 85 --  |g 4.4  |t The virial route to the surface tension  |g 89 --  |g 4.5  |t Functionals of the distribution functions  |g 93 --  |g 4.6  |t The surface tension from the direct correlation function  |g 98 --  |g 4.7  |t Equivalence of the two expressions for the surface tension  |g 104 --  |g 4.8  |t The spherical surface  |g 109 --  |g 4.9  |t Density fluctuations and their correlation  |g 115 --  |g 4.10  |t Local thermodynamic functions  |g 122 --  |g 5  |t Model Fluids in the Mean-Field Approximation --  |g 5.1  |t Introduction: mean-field theory of a homogeneous fluid of attracting hard spheres  |g 129 --  |g 5.2  |t Liquid-gas interface in the model of attracting hard spheres  |g 133 --  |g 5.3  |t Lattice-gas model: one component  |g 135 --  |g 5.4  |t Lattice-gas model: two components  |g 140 --  |g 5.5  |t Penetrable-sphere model: theory  |g 151 --  |g 5.6  |t Penetrable-sphere model: applications  |g 159 --  |g 5.7  |t Penetrable-sphere model: spherical surfaces  |g 167 --  |g 6  |t Computer Simulation of the Liquid-Gas Surface --  |g 6.1  |t The experimental background  |g 173 --  |g 6.2  |t The methods of computer simulation  |g 175 --  |g 6.3  |t The density profile  |g 178 --  |g 6.4  |t The surface tension  |g 181 --  |g 6.5  |t Further work  |g 185 --  |g 7  |t Calculation of the Density Profile --  |g 7.2  |t Solution of the YBG equation  |g 190 --  |g 7.3  |t Approximations for the direct correlation function  |g 195 --  |g 7.4  |t Modified van der Waals theories  |g 198 --  |g 7.5  |t Perturbation theories  |g 200 --  |g 7.6  |t Surface tension  |g 202 --  |g 8  |t Three-Phase Equilibrium --  |g 8.2  |t Contact angles and Neumann's triangle  |g 209 --  |g 8.3  |t Spreading and Antonow's rule  |g 212 --  |g 8.4  |t The [alpha gamma] interface  |g 221 --  |g 8.5  |t Phase transitions in interfaces. The Cahn transition  |g 225 --  |g 8.6  |t Three-phase line and line tension  |g 232 --  |g 9  |t Interfaces Near Critical Points --  |g 9.1  |t Introduction: mean-field approximation  |g 249 --  |g 9.2  |t Digression on the Ornstein-Zernike theory of the pair-correlation function  |g 255 --  |g 9.3  |t Digression on critical-point exponents  |g 261 --  |g 9.4  |t Van der Waals theory with non-classical exponents  |g 270 --  |g 9.5  |t Tricritical points  |g 276 --  |g 9.6  |t Non-critical interface near a critical endpoint  |g 285 --  |g 9.7  |t Renormalization-group theory; field-theoretical models  |g 296 --  |g Appendix 1  |t Thermodynamics  |g 307 --  |g Appendix 2  |t Dirac's delta-function  |g 314. 
588 0 |a Print version record. 
520 |a History of thought on molecular origins of surface phenomena offers a critical and detailed examination and assessment of modern theories, focusing on statistical mechanics and application of results in mean-field approximation to model systems. Emphasis on liquid-gas surface, with a focus on liquid-liquid surfaces in the final chapters. 1989 edition. 
590 |a Knovel  |b ACADEMIC - Plastics & Rubber 
590 |a Knovel  |b ACADEMIC - Electronics & Semiconductors 
650 0 |a Capillarity. 
650 0 |a Molecular theory. 
650 6 |a Capillarité. 
650 6 |a Théorie moléculaire. 
650 7 |a capillarity.  |2 aat 
650 7 |a SCIENCE  |x Chemistry  |x General.  |2 bisacsh 
650 7 |a Capillarity.  |2 fast  |0 (OCoLC)fst00846265 
650 7 |a Molecular theory.  |2 fast  |0 (OCoLC)fst01024857 
650 7 |a Kapillarität  |2 gnd 
700 1 |a Widom, B. 
776 0 8 |i Print version:  |a Rowlinson, J.S. (John Shipley), 1926-  |t Molecular theory of capillarity.  |b Dover ed.  |d Mineola, N.Y. : Dover Publications, 2002  |z 0486425444  |w (DLC) 2002074022  |w (OCoLC)50253267 
856 4 0 |u https://appknovel.uam.elogim.com/kn/resources/kpMTC00001/toc  |z Texto completo 
938 |a YBP Library Services  |b YANK  |n 12220190 
994 |a 92  |b IZTAP