Cargando…
Organic Structure Determination Using 2-D NMR Spectroscopy : a Problem-Based Approach.
This book contains 30-40 quality 2D NMR data sets following an introductory section describing the methodology employed. Many other books describe the methods used, but none offer a large number of problems. Instructors at universities and colleges at the present time are forced to cobble together p...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Burlington :
Elsevier Science,
2012.
|
| Edición: | 2nd ed. |
| Temas: | |
| Acceso en línea: | Texto completo |
MARC
| LEADER | 00000cam a2200000Mi 4500 | ||
|---|---|---|---|
| 001 | KNOVEL_ocn769344337 | ||
| 003 | OCoLC | ||
| 005 | 20231027140348.0 | ||
| 006 | m o d | ||
| 007 | cr |n|---||||| | ||
| 008 | 111226s2012 vtu o 000 0 eng d | ||
| 040 | |a EBLCP |b eng |e pn |c EBLCP |d MHW |d YDXCP |d KNOVL |d OCLCQ |d KNOVL |d OCLCF |d KNOVL |d ZCU |d OCLCO |d KNOVL |d AU@ |d OCLCO |d OCLCQ |d OCLCO |d OCLCQ |d DEBSZ |d OCLCO |d OCLCQ |d OCLCO |d U3G |d PHUST |d LIP |d BUF |d OCLCQ |d CEF |d RRP |d YOU |d TKN |d OCLCQ |d OCLCO |d OCLCQ |d EBLCP |d SFB |d OCLCQ |d OCLCO | ||
| 019 | |a 816495127 |a 973349109 |a 1144196021 | ||
| 020 | |a 9780123849717 |q (electronic bk.) | ||
| 020 | |a 0123849713 |q (electronic bk.) | ||
| 029 | 1 | |a AU@ |b 000050144181 | |
| 029 | 1 | |a DEBSZ |b 452504295 | |
| 029 | 1 | |a NZ1 |b 14691028 | |
| 035 | |a (OCoLC)769344337 |z (OCoLC)816495127 |z (OCoLC)973349109 |z (OCoLC)1144196021 | ||
| 050 | 4 | |a QD461 .S468 2012 | |
| 072 | 7 | |a SCI |2 ukslc | |
| 072 | 7 | |a PN |2 bicssc | |
| 072 | 7 | |a PNFS |2 bicssc | |
| 072 | 7 | |a PNR |2 bicssc | |
| 082 | 0 | 4 | |a 541.22 |
| 049 | |a UAMI | ||
| 100 | 1 | |a Simpson, Jeffrey H. | |
| 245 | 1 | 0 | |a Organic Structure Determination Using 2-D NMR Spectroscopy : |b a Problem-Based Approach. |
| 250 | |a 2nd ed. | ||
| 260 | |a Burlington : |b Elsevier Science, |c 2012. | ||
| 300 | |a 1 online resource (591 pages) | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 347 | |a data file |2 rda | ||
| 588 | 0 | |a Print version record. | |
| 505 | 0 | |a Front Cover; Organic Structure Determination Using 2-D NMR Spectroscopy: A Problem-Based Approach; Copyright; Dedicated to; Contents; Preface; Preface to the First Edition; Chapter 1 -- Introduction; 1.1 What Is Nuclear Magnetic Resonance?; 1.2 Consequences of Nuclear Spin; 1.3 Application of a Magnetic Field to a Nuclear Spin; 1.4 Application of a Magnetic Field to an Ensemble of Nuclear Spins; 1.5 Tipping the Net Magnetization Vector from Equilibrium; 1.6 Signal Detection; 1.7 The Chemical Shift; 1.8 The 1-D NMR Spectrum; 1.9 The 2-D NMR Spectrum. | |
| 505 | 8 | |a 1.10 Information Content Available Using NMR SpectroscopyProblems for Chapter One; Chapter 2 -- Instrumental Considerations; 2.1 Sample Preparation; 2.2 Locking; 2.3 Shimming; 2.4 Temperature Regulation; 2.5 Modern NMR Instrument Architecture; 2.6 Pulse Calibration; 2.7 Sample Excitation and the Rotating Frame of Reference; 2.8 Pulse Rolloff; 2.9 Probe Variations; 2.10 Analog Signal Detection; 2.11 Signal Digitization; Problems for Chapter Two; References; Chapter 3 -- Data Collection, Processing, and Plotting; 3.1 Setting the Spectral Window. | |
| 505 | 8 | |a 3.2 Determining the Optimal Wait (Delay) Between Scans3.3 Setting the Acquisition Time; 3.4 How Many Points to Acquire in a 1-D Spectrum; 3.5 Zero Filling and Digital Resolution; 3.6 Setting the Number of Points to Acquire in a 2-D Spectrum; 3.7 Truncation Error and Apodization; 3.8 The Relationship Between T2 * and Observed Line Width; 3.9 Resolution Enhancement; 3.10 Forward Linear Prediction; 3.11 Pulse Ringdown and Backward Linear Prediction31; 3.12 Phase Correction; 3.13 Baseline Correction39; 3.14 Integration; 3.15 Measurement of Chemical Shifts and J-Couplings. | |
| 505 | 8 | |a 3.16 Data RepresentationProblems for Chapter Three; Chapter 4 -- 1H and 13C Chemical Shifts; 4.1 The Nature of the Chemical Shift; 4.2 Aliphatic Hydrocarbons; 4.3 Saturated, Cyclic Hydrocarbons; 4.4 Olefinic Hydrocarbons; 4.5 Acetylenic Hydrocarbons; 4.6 Aromatic Hydrocarbons; 4.7 Heteroatom Effects; Problems for Chapter Four; Reference; Chapter 5 -- Symmetry and Topicity; 5.1 Homotopicity; 5.2 Enantiotopicity; 5.3 Diastereotopicity; 5.4 Chemical Equivalence; 5.5 Magnetic Equivalence; Problems for Chapter Five; Reference; Chapter 6 -- Through-Bond Effects: Spin-Spin (J) Coupling. | |
| 505 | 8 | |a 6.1 Origin of J-Coupling6.2 Skewing of the Intensity of Multiplets; 6.3 Prediction of First-Order Multiplets; 6.4 The Karplus Relationship for Spins Separated by Three Bonds; 6.5 The Karplus Relationship for Spins Separated by Two Bonds; 6.6 Long Range J-Coupling; 6.7 Decoupling Methods; 6.8 One-Dimensional Experiments Utilizing J-Couplings; 6.9 Two-Dimensional Experiments Utilizing J-Couplings; Problems for Chapter Six; References; Chapter 7 -- Through-Space Effects: The Nuclear Overhauser Effect (NOE); 7.1 The Dipolar Relaxation Pathway. | |
| 500 | |a 7.2 The Energetics of an Isolated Heteronuclear Two-Spin System. | ||
| 520 | |a This book contains 30-40 quality 2D NMR data sets following an introductory section describing the methodology employed. Many other books describe the methods used, but none offer a large number of problems. Instructors at universities and colleges at the present time are forced to cobble together problems from a wide range of sources. The fragmentary approach to assembling course materials has a negative impact on course continuity and thus adversely impacts student retention. This book will stand as a single source to which instructors and students can go to obtain a comprehensive compe. | ||
| 504 | |a Includes bibliographical references and index. | ||
| 546 | |a English. | ||
| 590 | |a Knovel |b ACADEMIC - Chemistry & Chemical Engineering | ||
| 650 | 0 | |a Molecular structure. | |
| 650 | 0 | |a Organic compounds |x Analysis. | |
| 650 | 0 | |a Nuclear magnetic resonance spectroscopy. | |
| 650 | 6 | |a Structure moléculaire. | |
| 650 | 6 | |a Composés organiques |x Analyse. | |
| 650 | 6 | |a Spectroscopie de la résonance magnétique nucléaire. | |
| 650 | 7 | |a molecular structure. |2 aat | |
| 650 | 7 | |a Molecular structure |2 fast | |
| 650 | 7 | |a Nuclear magnetic resonance spectroscopy |2 fast | |
| 650 | 7 | |a Organic compounds |x Analysis |2 fast | |
| 776 | 0 | 8 | |i Print version: |a Simpson, Jeffrey H. |t Organic Structure Determination Using 2-D NMR Spectroscopy : A Problem-Based Approach. |d Burlington : Elsevier Science, ©2012 |z 9780123849700 |
| 856 | 4 | 0 | |u https://appknovel.uam.elogim.com/kn/resources/kpOSDUDNM1/toc |z Texto completo |
| 938 | |a ProQuest Ebook Central |b EBLB |n EBL7264161 | ||
| 938 | |a ProQuest Ebook Central |b EBLB |n EBL829957 | ||
| 938 | |a YBP Library Services |b YANK |n 7305628 | ||
| 994 | |a 92 |b IZTAP | ||