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Phase equilibria in chemical engineering /
Phase Equilibria in Chemical Engineering is devoted to the thermodynamic basis and practical aspects of the calculation of equilibrium conditions of multiple phases that are pertinent to chemical engineering processes. Efforts have been made throughout the book to provide guidance to adequate theory...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Boston :
Butterworth,
©1985.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Front Cover; Phase Equilibria in Chemical Engineering; Copyright Page ; Table of Contents; List of Figures; List of Tables; List of Examples; Preface; A Guide for the Perplexed; Chapter 1. Equations of State; 1.1 Historical Notes; 1.2 Nonideal Gases; 1.3 Corresponding States; 1.4 The Virial Equation; 1.5 Cubic Equations; 1.6 Complex Equations of State; 1.7 Intermolecular Forces and Equations of State; 1.8 The Critical State and Critical Properties; 1.9 Comparisons and Tentative Recommendations; 1.10 Review Literature on Equations of State; 1.11 Problems.
- Chapter 2. Thermodynamic Functions and Equilibrium2.1 Energy Functions; 2.2 Fundamental Equations; 2.3 Total and Specific Properties; 2.4 Partial Molai Properties; 2.5 Derivatives with Respect to Mol Fractions; 2.6 Homogeneous Functions; 2.7 Variation of Properties with Temperature and Pressure; 2.8 Mixing and Excess Functions; 2.9 The Gibbs-Duhem Equation and Thermodynamic Consistency; 2.10 Conditions of Equilibrium; 2.11 Problems; Chapter 3. Fugacity and Fugacity Coefficient; 3.1 Definitions and Basic Relations; 3.2 Pure Substances; 3.3 Mixtures; 3.4 Ideal Mixtures.
- 3.5 Liquid and Solid Phases3.6 Applications; 3.7 Problems; Chapter 4. Activity Coefficients; 4.1 Activity and Activity Coefficients; 4.2 Standard States; 4.3 Thermodynamic Relations Involving Activity Coefficients; 4.4 Determination of Activity Coefficients; 4.5 Activity Coefficients and Equations of State; 4.6 Correlation of Data; 4.7 The Margules and Related Equations; 4.8 The van Laar Equation; 4.9 The Wilson Equation and Some Modifications; 4.10 The NRTL (Renon) Equation; 4.11 The UNIQUAC (Universal Quasi-Chemical) Equation; 4.12 Multicomponent Mixtures; 4.13 Comparison of Equations.
- 4.14 Multiple Roots4.15 Infinite Dilution; 4.16 Activity Coefficients from Pure Component Properties; 4.17 Activity Coefficients from Measurements of Equilibrium; 4.18 The Effect of Temperature and Excess Enthalpy; 4.19 Problems; Chapter 5. Phase Diagrams; 5.1 Geometric Representation; 5.2 The Phase Rule; 5.3 Unary Systems; 5.4 Binary Systems; 5.5 Ternary Systems; 5.6 More than Three Components; 5.7 Selected Books on Phase Diagrams; 5.8 Problems; Chapter 6. Vapor-Liquid Equilibrium; 6.1 Vapor and Liquid Phases; 6.2 Vaporization Equilibrium Ratio.
- 6.3 Equilibria with Ks Independent of Composition6.4 Equilibria with Ks Dependent on Composition; 6.5 Solubility of Gases in Liquids; 6.6 Binary VLE Diagrams; 6.7 Gibbs Energy Minimization; 6.8 Problems; Chapter 7. Liquid-Liquid Equilibria; 7.1 Liquid Mixtures; 7.2 Phase Diagrams; 7.3 Miscibility and Thermodynamic Stability; 7.4 Binary Mixtures; 7.5 Ternary and Multicomponent Mixtures; 7.6 Prediction of LLE with UNIFAC or ASOG; 7.7 Solubility of Liquids; 7.8 Vapor-Liquid-Liquid Equilibria; 7.9 Vapor-Liquid-Solid Equilibria; 7.10 Problems; Chapter 8. Liquid-Solid Equilibrium; 8.1 Introduction.