CO2 in seawater : equilibrium, kinetics, isotopes /

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Carbon dioxide is the most important greenhouse gas after water vapor in the atmosphere of the earth. More than 98% of the carbon of the atmosphere-ocean system is stored in the oceans as dissolved inorganic carbon. The key for understanding critical processes of the marine carbon cycle is a sound k...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autores principales: Zeebe, Richard E. (Autor), Wolf-Gladrow, Dieter A., 1953- (Autor)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Amsterdam ; New York : Elsevier, [2001]
Colección:Elsevier oceanography series ; 65.
Temas:
Seawater > Carbon dioxide content.
Chemical oceanography.
Eau de mer > Teneur en gaz carbonique.
Océanographie chimique.
SCIENCE > Earth Sciences > Oceanography.
NATURE > Ecosystems & Habitats > Oceans & Seas.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover
  • Contents
  • Chapter 1. Equilibrium
  • 1.1 The carbonate system
  • 1.2 Alkalinity
  • 1.3 pH scales
  • 1.4 Partial pressure and fugacity
  • 1.5 The Revelle factor
  • 1.6 Worked out problems
  • Chapter 2. Kinetics
  • 2.1 Basic concepts of kinetics
  • 2.2 Temperature dependence of rate constants
  • 2.3 Reactions and rate constants of the carbonate system
  • 2.4 Approaching equilibrium: the carbonate system
  • 2.5 Approaching isotopic equilibrium: 12C, 13C, and 14C
  • 2.6 Diffusion and Reaction
  • 2.7 Summary
  • Chapter 3. Stable Isotope Fractionation
  • 3.1 Notation, abundances, standards
  • 3.2 Carbon
  • 3.3 Oxygen
  • 3.4 Boron
  • 3.5 Thermodynamic properties of isotopic substances
  • Appendix A: Equilibrium constants
  • A.1 CO2: Acidity constants K1* and K2*
  • A.2 Acidity constant of true carbonic acid
  • A.3 CO2 solubility in water (Henry's law)
  • A.4 Ion product of water: KW*
  • A.5 Bisulfate ion
  • A.6 Hydrogen fluoride
  • A.7 Boric acid
  • A.8 Phosphoric acid
  • A.9 Silicic acid
  • A.10 Solubility product of calcite and aragonite
  • A.11 Effect of pressure on equilibrium constants
  • A.12 Chemical composition of seawater
  • A.13 The equation of state of seawater
  • Appendix B: From two to six
  • Appendix C: Details and Calculations
  • C.1 Total alkalinity and charge balance
  • C.2 Saturation vapor pressure of water
  • C.3 The fugacity of a pure gas
  • C.4 Equilibrium at air-sea interface and chemical potential
  • C.5 Change CO2 concentration while keeping pH constant
  • C.6 The rate constant for the hydroxylation of CO2, k+4
  • C.7 A formula for the equilibration time of CO2
  • C.8 Kinetic rate laws of the carbonate system
  • C.9 Derivation of oxygen isotope partitioning
  • C.10 Mathematical derivation of the partition function ratio
  • Appendix D: Answers to Exercises
  • Appendix E: Notation and Symbols
  • References
  • Index
  • Last Page.

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