Polyolefins : processing, structure development and properties /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: White, James Lindsay, 1938-
Otros Autores: Choi, David D.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Munich : Cincinnati : Hanser ; Hanser Gardner Publications, ©2005.
Temas:
Polyolefins.
Polyoléfines.
TECHNOLOGY & ENGINEERING > Chemical & Biochemical.
Polyolefins
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Machine derived contents note: Contents
  • 1 Origins of Polyolefins 1
  • 1.1 Introduction and Prehistory 1
  • 1.2 Polyethylene 2
  • 1.2.1 Low Density Polyethylene 2
  • 1.2.2 Karl Ziegler and High Density Polyethylene 3
  • 1.2.3 Standard Oil of Indiana 5
  • 1.2.4 Phillips Petroleum and High Density Polyethylene 5
  • 1.2.5 Linear Low Density Polyethylene 6
  • 1.3 Isotactic Polypropylene 7
  • 1.3.1 Giulio Natta, Milan Politechnico and Montecatini 7
  • 1.3.2 Standard Oil of Indiana and Phillips Petroleum 8
  • 1.4 Isotactic Polybutene-1 9
  • 1.5 Isotactic Polymers of Higher Olefins and Poly(4-Methyl Pentene-1) 10
  • 1.6 Ethylene-Propylene Rubber 11
  • 1.7 Metallocene Polymerization 12
  • 1.8 Stereoregular Polystyrenes 13
  • 1.8.1 Isotactic Polystyrene 13
  • 1.8.2 Syndiotactic Polystyrene 13
  • 1.9 Syndiotactic Polypropylene 14
  • 1.10 Cyclopolyolefins 14
  • 1.11 New Metallocene Polyolefin Copolymers 16
  • 1.12 Current Production Levels 16
  • 1.13 Bulk Polymer Properties and Chemical Stability 17
  • References 19
  • 2 Characterization Methods 23
  • 2.1 Introduction 23
  • 2.2 Asymmetric Carbon Atoms and Tacticity 23
  • 2.2.1 Low Molecular Weight Compounds 23
  • 2.2.2 Polyolefins [5] 24
  • 2.2.3 Tacticity Levels 26
  • 2.3 Crystallinity 27
  • 2.4 Crystal Structure [16, 17] 28
  • 2.5 Chain Conformations in Crystals 32
  • 2.6 Molecular Weight Distribution [7, 34, 35] 33
  • 2.7 Orientation 37
  • 2.7.1 Uniaxial Orientation 37
  • 2.7.2 Biaxial Orientation 40
  • 2.8 Superstructure 43
  • References 44
  • 3 Crystallography of Polyolefins 49
  • 3.2 Introduction 49
  • 3.2 Early Investigations of Low Molecular Weight Paraffinic Compounds 49
  • 3.3 Polyethylene 55
  • 3.4 Isotactic Polypropylene 58
  • 3.5 Syndiotactic Polypropylene 60
  • 3.6 Isotactic Polybutene-1 62
  • 3.7 Syndiotactic Polybutene-1 63
  • 3.8 Isotactic Poly(4-Methyl Pentene-1) 63
  • 3.9 Isotactic Polymers of Other a-Olefins 65
  • 3.10 Isotactic Polystyrene 66
  • 3.11 Syndiotactic Polystyrene 67
  • 3.12 Summary and Trends 68
  • References 69
  • 4 Single Crystals: Structural Hierarchy and Morphology 75
  • 4.1 Introduction 75
  • 4.2 Polyethylene 75
  • 4.2.1 Single Crystals 75
  • 4.2.2 Flow-Induced Structures from Solution 77
  • 4.2.3 Bulk Structure 78
  • 4.3 Isotactic Polypropylene 80
  • 4.3.1 Single Crystals 80
  • 4.3.2 Flow Induced Structures from Solution 80
  • 4.3.3 Bulk Structure 81
  • 4.4 Syndiotactic Polypropylene 82
  • 4.5 Isotactic Polybutene-1 83
  • 4.5.1 Single Crystals 83
  • 4.5.2 Bulk Structure 83
  • 4.6 Isotactic Poly(4-Methyl Pentene-1) 84
  • 4.6.1 Single Crystals 84
  • 4.6.2 Flow Induced Structures from Solution 84
  • 4.6.3 Bulk Structures 85
  • 4.7 Isotactic Polystyrene 85
  • 4.7.1 Single Crystals 85
  • 4.7.2 Flow Induced Structures from Solution 86
  • 4.7.3 Bulk Structure 86
  • 4.8 Syndiotactic Polystyrene 87
  • 4.8.1 Single Crystals 87
  • 4.8.2 Bulk Structures 87
  • 4.9 Summary 87
  • References 88
  • 5 Spherulites and Quiescent Crystallization 91
  • 5.1 Introduction 91
  • 5.2 Spherulites 91
  • 5.2.1 Quiescently Crystallized Polymers 91
  • 5.2.2 Polyethylene 91
  • 5.2.3 Isotactic Polypropylene 93
  • 5.2.4 Syndiotactic Polypropylene 94
  • 5.2.5 Isotactic Polybutene-1 94
  • 5.2.6 Isotactic Poly(4-methyl pentene-1) 95
  • 5.2.7 Isotactic Polystyrene 95
  • 5.2.8 Syndiotactic Polystyrene 95
  • 5.3 Quiescent Crystallization Kinetics 96
  • 5.3.1 General 96
  • 5.3.2 Polyethylene 98
  • 5.3.3 Isotactic Polypropylene 99
  • 5.3.4 Syndiotactic Polypropylene 100
  • 5.3.5 Isotactic Polybutene-

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