Cargando…

Kinetics of heterogeneous catalytic reactions /

This book is a critical account of the principles of the kinetics of heterogeneous catalytic reactions in the light of recent developments in surface science and catalysis science. Originally published in 1984. The Princeton Legacy Library uses the latest print-on-demand technology to again make ava...

Descripción completa

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Boudart, Michel
Formato: Electrónico eBook
Idioma:Inglés
Francés
Publicado: Princeton, N.J. : Princeton University Press, ©1984.
Colección:Physical chemistry (Princeton, N.J.)
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Figures ; Tables ; Preface to the French Edition ; Introduction ; 1. CONCEPTS AND DEFINITIONS; 1.1 Introduction; 1.2 Definitions; 1.3 Elementary step, reaction path, and overall reaction; 1.4 Determination of the Total Specific Surface Area of a Catalyst : Method of Brunauer, Emmett and Teller, (BET) Teller (BET); 1.5 Determination of the Number of Exposed Metal Atoms ; 1.6 Definition of catalysis; 2. KINETICS OF ELEMENTARY STEPS: ADSORPTION, DESORPTION, AND SURFACE REACTION ; 2.1 Introduction; 2.2 Kinetics of adsorption; 2.3 Kinetics of desorption.
  • 2.4 Unimolecular surface reactions2.5 Bimolecular surface reactions; 2.6 Temperature programmed reaction; 3. KINETICS OF OVERALL REACTIONS; 3.1 Introduction; 3.2 Kinetics of single reactions: uniform surfaces; 4. KINETICS OF TWO-STEP REACTIONS ON NON-UNIFORM SURFACES ; 4.1 Introduction; 4.2 Study of two-step single-path reactions; 4.3 Physical meaning of the distribution function; 4.4 Consequences of Temkin's formalism; 4.5 Determination of the Thermodynamic Activity of Adsorbed Species: Wagner's Method ; 5. STRUCTURE-INSENSITIVE AND STRUCTURE-SENSITIVE REACTIONS ON METALS.
  • 5.1 Operational definitions5.2 Low-pressure Oxidation of CO on Palladium: An Example of a Structure-Insensitive Reaction ; 5.3 Ammonia Synthesis on Iron: A Structure-Sensitive Reaction ; 5.4 Other structure-sensitive or -insensitive reactions; 5.5 Classification of Structure-Sensitive and -Insensitive Reactions ; 6. PARASITIC PHENOMENA; 6.1 Mass and heat transfer; 6.2 Classification of metal-support effects; Author Index; Subject Index.