Atomic and molecular physics : a primer /
This book introduces the fundamental quantum physics of atoms and molecules. Divided into three parts, the first provides a historical perspective leading to the contemporary view of atomic and molecular physics, outlining the principles of non-relativistic quantum mechanics. The second part covers...
Clasificación: | Libro Electrónico |
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Autor principal: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Bristol [England] (Temple Circus, Temple Way, Bristol BS1 6HG, UK) :
IOP Publishing,
[2019]
|
Colección: | IOP (Series). Release 6.
IOP expanding physics. |
Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- part I. Preliminary concepts. 1. The overall picture
- 1.1. The atomistic structure of matter
- 1.2. The quantum nature of physical laws
- 1.3. The dual nature of physical phenomena
- 2. Essential quantum mechanics
- 2.1. The wavefunction
- 2.2. Quantum operators
- 2.3. Time evolution
- 2.4. Systems of identical particles
- 2.5. Matrix notation
- 2.6. Perturbation theory
- part II. Atomic physics. 3. One-electron atoms
- 3.1. The hydrogen atom
- 3.2. Hydrogenic atoms
- 3.3. Magnetic moments and interactions
- 3.4. Spin-orbit interaction
- 3.5. Other relativistic effects
- 3.6. Classifying the fine structure levels : the spectroscopic notation
- 3.7. Anomalous Zeeman and Paschen-Back effects
- 3.8. The action of an electric field
- 4. Interaction of one-electron atoms with radiation
- 4.1. Emission and absorption of radiation
- 4.2. Microscopic theory of Einstein coefficients
- 4.3. Electric dipole selection rules for hydrogenic states
- 4.4. Forbidden transitions
- 4.5. The LASER
- 5. Multi-electron atoms
- 5.1. Singlet-triplet states and exchange forces
- 5.2. A first step : the helium atom
- 5.3. The central-field approximation
- 5.4. The periodic system of the elements
- 5.5. Beyond the central-field approximation
- 5.6. Selection rules
- 5.7. The action of an external magnetic field
- part III. Molecular physics. 6. Molecules : general features
- 6.1. What is a molecule?
- 6.2. The Born-Oppenheimer approximation
- 6.3. Molecular bonding
- 7. Molecular vibrations and rotations
- 7.1. Molecular motions in diatomic molecules
- 7.2. Rayleigh and Raman scattering
- 7.3. Nuclear motions in polyatomic molecules
- 8. Electronic structure of molecules
- 8.1. Problem definition
- 8.2. Molecular orbitals
- 8.3. Electronic configurations
- 8.4. Electronic transitions : the Franck-Condon principle
- part IV. Concluding remarks. 9. What is missing in this 'primer'
- part V. Appendices. A. The formal solution of the Schrödinger equation
- B. The spin-orbit interaction energy in hydrogenic atoms
- C. The hyperfine structure in hydrogenic atoms
- D. The 'minimal coupling' scheme
- E. Screening effects in He atom
- F. The Thomas-Fermi method
- G. The formal proof of the Born-Oppenheimer approximation
- H. The one-dimensional quantum harmonic oscillator.