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Organometallic compounds : preparation, structure and properties /
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York :
Nova Science Publishers, Inc.,
[2010]
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| Colección: | Materials science and technologies series.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- ORGANOMETALLIC COMPOUNDS:PREPARATION, STRUCTUREAND PROPERTIES; ORGANOMETALLIC COMPOUNDS:PREPARATION, STRUCTUREAND PROPERTIES; CONTENTS; PREFACE; TOXICOLOGY OF ORGANOTINS IN MARINEORGANISMS: A REVIEW; ABSTRACT; INTRODUCTION; ORGANOTINS IN THE MARINE ENVIRONMENT; In Saline Waters; In Sediments; ORGANOTINS IN MARINE ORGANISMS; Introduction; Bioconcentration and Bioaccumulation of Organotins; Biomagnification; Degradation in Tissues; TOXICITY TO MARINE ORGANISMS; Algae and Seagrass; Invertebrates; Fish; Marine Mammals; MECHANISMS OF ACTION OF ORGANOTINS; Algae; Invertebrates; Fish; Marine Mammals.
- CONCLUSIONREFERENCES; DZHEMILEV REACTION FOR THE SYNTHESIS OFCYCLIC AND ACYCLIC ORGANOMETALLICCOMPOUNDS; ABSTRACT; 1. INTRODUCTION; 2. HISTORY OF DISCOVERY; 3. ETHYLMAGNESIATION OF OLEFINS CATALYZED BY ZRCOMPLEXES; 4. CATALYTIC CYCLOALUMINATION AND CYCLOMAGNESIATION OFOLEFINS, ACETYLENES, AND ALLENES MEDIATED BY MG ORAL ALKYLS; 4.1. Catalytic Cycloalumination of Olefins and 1,2-Dienes toAluminacyclopentanes; 4.2. Catalytic Cycloalumnation of Acetylenes to Aluminacyclopentenes andAluminacyclopentadienes.
- 4.3. Cyclomagnesiation of Olefins and 1,2-Dienes to MagnesacyclopentanesAffected by Zr- and Ti-Catalysts4.4. Catalytic Cyclomagnesiation of Acetylenes; 5. ON MECHANISM OF OLEFIN ETHYLMAGNESIATION ANDCYCLOALUMINATION CATALYZED BY ZR COMPLEXES; 6. SYNTHESIS OF MACRO METALLACARBOCYCLES THROUGH THECATALYTIC CYCLOMETALATION REACTION OF UNSATURATEDCOMPOUNDS; CONCLUSION; REFERENCES; THE INFLUENCE FACTORS ON THIRD-ORDERNONLINEAR OPTICAL (NLO) PROPERTIES OFMETAL-ORGANIC COMPLEXES; ABSTRACT; ABBREVIATIONS; INTRODUCTION; 2. EXPERIMENT TECHNOLOGIES; 3. INFLUENCE FACTORS OF THIRD-ORDER NLO PROPERTIES.
- 3.1 The Influence of Central Metal Ions3.2 The Influence of Ligands; 3.3 The Influence of Structures; 3.4 The Collaboration of Structures, Ligands and Metal Ions to Third-Order NLO Properties; 4. THEORY BASE ABOUT THE INFLUENCE FACTORS OF THIRD-ORDERNLO PROPERTIES -WHETHER CENTRAL METAL IONS ORLIGANDS PLAY A MORE IMPORTANT ROLEON THE THIRD-ORDER NLO PROPERTIES; 5. USING FRONTIER ORBITAL THEORY TO STUDY THE INFLUENCEFACTORS OF THIRD-ORDER NLO PROPERTIES; 6. ONE KIND OF POTENTIAL EXCELLENT THIRD-ORDER NLOMATERIALS
- AG(I) COMPLEXES.
- 6.1 Theoretical Foundation of Ag(I) Complexes Acting as Potential ExcellentThird-Order NLO Materials6.2 Design and Synthesis of Ag(I) Complexes with Excellent Third-OrderNLO Properties; 7. SUMMARY AND FORECAST; ACKNOWLEDGMENTS; REFERENCES; PHOTOPHYSICS OF GROUP IV METALLOCENES; ABSTRACT; INTRODUCTION; I. STRUCTURE AND FRONTIER MOLECULAR ORBITALS OF D0BENT METALLOCENES; II. COMBINATION OF ELECTROCHEMICAL ANDPHOTOPHYSICAL STUDIES; 1. Redox Properties and Electrochemical Potentials; 2. Trends of Reduction and Oxidation Potentials; III. LIGAND-TO-METAL CHARGE TRANSFER PHOTOPHYSICS.