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Boron hydrides, high potential hydrogen storage materials /
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York :
Nova, Nova Science Publishers, Inc.,
c2011.
|
| Colección: | Chemistry research and applications series.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- BORON HYDRIDES, HIGH POTENTIAL HYDROGEN STORAGE MATERIALS ; BORON HYDRIDES, HIGH POTENTIAL HYDROGEN STORAGE MATERIALS; Contents; Preface; Solid-State Hydrogen Storage; Abstract; Introduction; 2. Issues Encountering Hydrogen Economy; 3. Hydrogen Storage Issue; 3.1 Technical Targets; 3.2 Physical Methods for Hydrogen Storage; 3.2.1 High Pressure Storage; 3.2.2 Cryogenic Storage; 3.3 Chemical Methods for Hydrogen Storage; 4. Solids for Hydrogen Storage or Chemical Storage; 4.1 Adsorption in Porous Materials; 4.1.1 Activated Carbons including Carbon Nanostructures.
- 4.1.2 Hydrogen Physisorption in other Materials4.2 Storage by Absorption; 4.2.1 Metal Hydrides; 4.2.2 Complex Hydrides; 4.2.3 Storage via Chemical Reactions; Conclusion; References; Boron Hydrides; Abstract; 1. Introduction; 2. Boron Compounds; 2.1 Borides; 2.2 Boron Hydrides; 2.3 Boron Halides; 2.4 Boron-Oxygen Compounds; 2.5 Boron-Nitrogen Compounds; 2.6 Other Boron-Based Compounds; 2.7 Summary; 3. Borohydrides; 3.1 All of the Borohydrides; 3.2 Thermolysis of Borohydrides; 3.3 Hydrolysis of Borohydrides; 3.4 Safety Data; 3.5 Conclusion; 4. Ammoniaborane and its Derivatives.
- 4.1 Ammoniaborane4.2 Amidoboranes; 4.3 Safety Data; Conclusion; References; Lithium Borohydride: Synthesis, Properties and Thermal Decomposition; Abstract; 1. Introduction; 2. Synthesis Methods; 3. Crystal Structures; 4. Ionic Superconduction; 5. Thermal Decomposition; 6. Hydrogen Release Enhancement by Catalysts Addition; 7. Modification of Hydrogen Release by Confinement into Nanoporous Carbons; Conclusions; Acknowledgments; References; Hydrogen Cycle with Sodium Borohydride; Abstract; 1. Importance of Sodium Borohydride in Hydrogen Cycle; 2. Sodium Borohydride Production Techniques.
- 2.1. Borax Reactions2.2. Trimetyl Borate Reactions; 2.3. NaBH4 Reactions; 3. Dehydrogenation of NaBH4 and its usage as Hydrogen Carrier; 3.1. Thermal Dehydrogenation; 3.2. Catalytic Dehydrogenation; 3.2.1. Alkaline Hydrolysis Solution; 3.2.2. Water Requirement for Hydrolysis; 3.2.3. Catalyst Preparation and its Effect on Hydrolysis; 3.2.4. Supported Materials of Heterogeneous Catalysts; 3.2.5. Processing Magnetic Catalysts; 3.2.6. Co-Ni Couple Catalysts and Reaction Mechanism; 3.2.7. Electrochemical Catalysts; 3.2.8. Fuel Cell Application of Catalytic Hydrolysis; 4. NaBO2 Recycle.
- 5. NaBO2-Borax Conversion6. Characterization of NaBH4; Conclusion; References; Potential and Limitation of the Direct Borohydride Fuel Cell. Special Emphasis on the Borohydride Oxidation Reaction (BOR) Mechanism and Kinetics on Gold Electrocatalysts; Abstract; 1. Introduction; 2. Experimental; 2.1 Reagents and Solutions; 2.2 On-Line Electrochemical Mass Spectroscopy (OLEMSlems); 2.3 Ftir FTIR Spectroscopy; 2.4 CV and EIS; 3. The Ideal Reactant for DBFC; 3.1 Fuel Composition for DBFC; 3.2 Alternative Reactants; 3.3 Fuel Monitoring; 4. Principle of Operation of a DBFC.