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Tabla de Contenidos:
  • Introduction
  • History of discovery
  • Ethylmagnesiation of olefins catalyzed by Zr complexes
  • Catalytic cycloalumination and cyclomagnesiation of olefins, acetylenes, and allenes mediated by Mg or Al alkyls
  • Catalytic cycloalumination of olefins and 1,2-dienes to aluminacyclopentanes
  • Catalytic cycloalumnation of acetylenes to aluminacyclopentenes and aluminacyclopentadienes
  • Cyclomagnesiation of olefins and 1,2-dienes to magnesacyclopentanes affected by Zr- and Ti-catalysts
  • Catalytic cyclomagnesiation of acetylenes
  • On mechanism of olefin ethylmagnesiation and cycloalumination catalyzed by Zr complexes
  • Synthesis of macro metallacarbocycles through the catalytic cyclometalation reaction of unsaturated compounds.