Cargando…
Kinetic and thermodynamic stability of cerium (IV) complexes with a series of aliphatic organic compounds /
An approach to the investigation of the thermodynamic and kinetic stability of variable-valence metal complexes has been developed. Concepts of the generalized inverse problems of quantitative instrumental analysis and the complex formation equilibria are introduced. The procedure for this investiga...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés Ruso |
| Publicado: |
New York :
Nova Publishers,
[2013]
|
| Colección: | Chemistry research and applications series.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- KINETIC AND THERMODYNAMIC STABILITY OF CERIUM(IV) COMPLEXES WITH A SERIES OF ALIPHATIC ORGANIC COMPOUNDS; LIBRARY OF CONGRESS CATALOGING-IN-PUBLICATION DATA; CONTENTS; PREFACE; ABSTRACT; Chapter 1: INTRODUCTION; 1. Applications of Tetravalent Cerium Compounds; 2. Investigations of Interaction between Cerium(IV) and Organic Ligands; 3. Generalized Methods for Investigating Complexes Stability in Terms of Inverse and Direct Problems; References; Chapter 2: METHODS FOR INVESTIGATION OF THERMODYNAMIC AND KINETIC STABILITY OF CERIUM(IV) COMPLEXES.
- 1. Classical Methods for Investigating the Complex Formation2. Possibility of Kinetic Modifications for Classical Thermodynamic Methods; 3. Benesi-Hildebrand-Ardon Method and Its Modifications; 4. Thermodynamic Methods for Studying Thermodynamic and Kinetic Stability of Complexes with Cations in an Unstable OS; 5. Kinetic Methods for Solving Inverse Problem of Complex Formation; 6. Further Generalizations of the Methods for Investigating the Thermodynamic and Kinetic Stability of Complexes with Cations in an Unstable OS; References.
- Chapter 3: INVESTIGATING STABILITY OF CERIUM(IV) COMPLEXES WITH SOME ALIPHATIC ORGANIC COMPOUNDS1. Experiment and Calculations; 2. Thermodynamic and Kinetic Stability of Cerium(IV) Complexes with Some Dicarboxylic Acids; 3. Formation and Intracomplex Redox Decomposition of Cerium(IV) Complexes With a Series of Oxycarboxylic Acids; 4. Thermodynamic and Kinetic Stability of Cerium(IV) Complexes with Some Polyatomic Alcohols; References; Chapter 4: A COMPARATIVE STUDY OF THE INVESTIGATED SYSTEMS; 1. Spectroscopic Evidence for Existence of Intermediate Complexes; 2. Stoichiometry.
- 3. Stability Constants of the Complexes4. Intracomplex Redox Decomposition Rate Constants and Activation Energies; 5. Correlation between Thermodynamic and Kinetic Stability of the Complexes; 6. Reaction Order, Rate Law and Mechanism; 7. Detailed Mechanism for Systems with Two Intermediates; 8. Some Computational Aspects; 9. Conclusion; References; INDEX.