Practical guide to flexible polyurethane foams /
Annotation
Clasificación: | Libro Electrónico |
---|---|
Autor principal: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Shrewsbury :
Smithers Rapra,
2013.
|
Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Machine generated contents note: 1. Introduction
- 1.1. Brief History
- 1.1.1. Flexible Foams
- 1.1.2. Rigid Polyurethane Foams
- 1.1.3. Automotives
- 1.1.4. Elastomers
- 1.1.5. Insulation
- 1.1.6. Moulded Parts
- 1.1.7. Spray Roofing Systems
- 1.1.8. Speciality Urethane Systems
- 1.2. Types of Foams
- 1.3. Basic Foam Grades
- 1.4. Viscoelastic Foam Mattresses: Marketing Hype or Molecular Miracle?
- 1.5. Flexible Slabstock Foams
- 1.6. What is a Flexible Polyurethane Foam?
- 1.7. What is a Viscoelastic Foam?
- 1.8. Characteristics of Viscoelastic Foams
- 1.9. Physical Properties of Viscoelastic Foams
- 1.10. Performance Testing of Viscoelastic Foams
- 1.10.1. Reduction and Relief of Pressure
- 1.10.2. Hyper or Pseudo Effects?
- 1.10.3. Viscoelastic Foam: Summary
- 1.10.4. End Applications
- 2. Basic Chemistry
- 2.1. Brief Introduction
- 2.2. Organic Chemistry
- 2.2.1. Basics
- 2.2.2. History
- 2.2.3. Characteristics
- 2.2.4. Properties
- 2.2.5. Melting and Boiling Properties
- 2.2.6. Solubility
- 2.2.7. Nomenclature
- 2.2.8. Structural Presentation
- 2.3. Classification of Organic Compounds
- 2.3.1. Functional Groups
- 2.3.2. Aliphatic Compounds
- 2.3.3. Aromatic Compounds
- 2.3.4. Heterocyclic Compounds
- 2.3.5. Polymers
- 2.3.6. Organic Synthesis
- 2.3.7. Organic Reactions
- 2.4. Inorganic Chemistry
- 2.4.1. Industrial Inorganic Chemistry
- 2.5. Classification of Inorganic Chemistry
- 2.5.1. Coordination Compounds
- 2.5.2. Main Group Compounds
- 2.5.3. Transition Metal Compounds
- 2.5.4. Organometallic Compounds
- 2.5.5. Cluster Compounds
- 2.5.6. Bio-inorganic Compounds
- 2.5.7. Solid State Compounds
- 2.5.8. Qualitative Theories
- 2.5.9. Molecular Symmetry Group Theory
- 2.6. Basics of Analytical Chemistry
- 2.6.1. Qualitative Analyses
- 2.6.1.1. Flame Test
- 2.6.1.2. Gravimetric Analyses
- 2.6.1.3. Volumetric Analyses
- 2.6.1.4. Mass Spectrometry
- 2.6.1.5. Electrochemical Analyses
- 2.6.1.6. Microscopy
- 3. Basic Polymer Chemistry
- 3.1. What is a Polymer?
- 3.1.1. Polymer Synthesis
- 3.1.2. Modification of Natural Polymers
- 3.2. Polymer Properties
- 3.2.1. Monomers
- 3.2.2. Microstructure
- 3.2.3. Chain Length!
- 3.2.4. Molecular Mass (Weight)
- 3.2.5. Polymerisation
- 3.2.6. Condensation Polymerisation
- 3.3. Mechanical Properties
- 3.3.1. Tensile Strength
- 3.3.2. Young's Modulus of Elasticity
- 3.3.3. Melting Point
- 3.3.4. Glass Transition Temperature
- 3.3.5. Mixing Behaviour
- 3.3.6. Polymer Degradation
- 4. Polyurethane Raw Materials
- 4.1. Polyols
- 4.1.1. Graft Polyols
- 4.1.2. Isocyanates
- 4.1.3. Bio-polyols
- 4.2. Catalysts
- 4.3. Blowing. Agents
- 4.4. Surfactants
- 4.5. Methylene Chloride
- 4.6. Additives
- 4.6.1. Pigments
- 4.6.2. Fillers
- 4.6.3. Retardants
- 4.6.4. Anti-oxidants
- 4.6.5. Anti-static Agents
- 4.6.6. Cell Openers
- 4.6.7. Plasticisers
- 4.6.8. Anti-bacterial Agents
- 4.6.9. Ultraviolet Stabilisers
- 4.6.10. Colorants
- 4.6.11. Colour Basics
- 4.6.12. Foam Hardeners
- 4.6.13. Crosslinkers
- 4.6.14. Compatibilisers
- 4.7. Accessories
- 4.7.1. Kraft Paper
- 4.7.2. Machine-glazed Paper
- 4.7.3. Polyethylene-coated Paper
- 4.7.4. Peelable Kraft Paper
- 4.7.5. Plastic Films
- 4.7.6. Mould Release Agents
- 4.8. Summary
- 5. Properties and Foaming Technology of Polyurethane Foam
- 5.1. Properties of-Polyurethane Foam
- 5.1.1. Basic Physical Properties
- 5.1.2. Tension Test (Tensile Strength)
- 5.1.3. Tear Resistance
- 5.1.4. Airflow
- 5.1.5. Resilience
- 5.1.6. Fogging
- 5.1.7. Durability
- 5.2. In Industrial Applications
- 5.2.1. Foam is a Good Air Sealant
- 5.3. Closed Cell Foams
- 5.3.1. Foams have Structural Advantages
- 5.3.2. Foam usage in Sound Control
- 5.4. Foaming Technology
- 5.4.1. Raw Materials and Their Functions
- 5.4.2. Polyols
- 5.4.3. Di-isocyanate
- 5.4.4. Water
- 5.4.5. Auxiliary Blowing Agents
- 5.4.6. Catalysts
- 5.4.7. Silicone Surfactants
- 5.4.8. Graft Polyols
- 5.4.9. Extenders
- 5.4.10. Colourants
- 5.4.11. Fillers
- 5.4.12. Additives
- 5.5. Foaming Process
- 5.5.1. Mixing
- 5.5.2. Nucleation
- 5.5.3. Expansion
- 5.5.4. Cell Opening
- 5.5.5. Gelation
- 5.5.6. Curing
- 5.6. Storage of Foam Blocks
- 5.7. Cutting and Fabrication
- 5.8. Filled Foam
- 5.8.1. Type of Filler
- 5.8.2. How Much Filler can be used?
- 5.9. Effects of Changes in Physical Properties
- 5.10. Processing Difficulties
- 5.11. Description of Additional Equipment
- 5.12. Procedure
- 6. Foaming Calculations, Other Calculations and Formulations
- 6.1. Calculations
- 6.1.1. Density
- 6.1.2. Mixing Ratio
- 6.1.3. Isocyanate Index
- 6.1.4. Ratio Calculation
- 6.1.5. Pump Rates Per Minute versus Flow Rate
- 6.1.6. Machine Flow Rate versus Mould Volume
- 6.2. Calculations for Making Large Foam Blocks: Discontinuous Process
- 6.2.1. Calculation of Material Required
- 6.2.2. Calculating Raw Material Components
- 6.3. Typical Formulations
- 6.3.1. Conventional Foam (Density Range 16.0-32 kg/m3)
- 6.3.2. High-resilience Foams
- 6.3.3. Viscoelastic Foam
- 6.3.4. Slab Stock Foam (Continuous Foaming)
- 6.4. Calculating Indentation Force Deflection
- 6.5. Calculating Electrical Power
- 6.5.1. Basic Example as a Guideline
- 6.6. Calculating Water Requirements
- 6.7. Compressed Air
- 6.7.1. Air Pressure versus Volume Calculator
- 6.8. Financial Indicators
- 6.8.1. Breakeven Point
- 6.8.2. Return on Equity
- 6.8.3. Return on Assets
- 6.8.4. Gross Profit Margin
- 6.8.5. Cash Flow
- 6.8.6. Contribution Margin
- 6.8.7. Debt to Equity Ratio
- 6.9. Quick Performance Indicators
- 6.9.1. Return per Kilogramme
- 6.9.2. Cost per Kilogramme
- 6.9.3. Breakeven Analysis
- 6.10. Recommended Basic Foam Formulations
- 6.11. To Save Waste on Foam Buns (Blocks)
- 7. Plant Machinery, and Equipment
- 7.1. Mould Design
- 7.1.1. Design Philosophy
- 7.1.2. Defining Product Requirements
- 7.1.3. Loading Conditions
- 7.1.4. Environmental Conditions
- 7.1.5. Dimensional Requirements
- 7.1.6. Preliminary Computer-aided Design Model
- 7.1.7. Material Selection
- 7.1.8. Process Selection
- 7.1.9. Process Influences
- 7.1.10. Orientation of the Final ̀Product'
- 7.1.11. Computer Simulation
- 7.1.12. Shrinkage and Warping
- 7.1.13. Basic Moulds for Flexible Foams
- 7.2. Foaming Machinery and Equipment
- 7.2.1. Low-pressure Machines
- 7.2.2. High-pressure Machines
- 7.2.3. Images of Foaming Machines
- 7.3. Foam Cutting and Fabrication
- 7.3.1. Horizontal Cutting
- 7.3.2. Vertical Cutting
- 7.3.3. Specialised Cutting
- 8. Manufacturing Processes for Flexible Foams
- 8.1. Box Process for Small-volume Producers
- 8.1.1. Process
- 8.1.2. Advantages
- 8.1.3. Disadvantages
- 8.2. Discontinuous Process
- 8.2.1. Manual Process
- 8.2.2. Advantages
- 8.2.3. Disadvantages
- 8.3. Semi-automatic and Automatic Processes
- 8.3.1. Advantages
- 8.3.2. Disadvantages
- 8.4. Viscoelastic Discontinuous Block Foaming
- 8.5. Continuous Process
- 8.5.1. Advantages
- 8.5.2. Disadvantages
- 8.6. Maxfoam System
- 8.6.1. Basic Principles
- 8.6.2. Basic Features of the Maxfoam System
- 8.7. Vertifoam Vertical Foaming System
- 8.8. Varimax Continuous System
- 8.9. C-Max High-pressure System
- 8.10. CarDio Process
- 8.11. Viscoelastic Continuous Foaming
- 8.12. Laboratory-scale Production
- 8.13. Inherent Waste Factors
- 8.14. Moulded Flexible Polyurethane Foams
- 8.14.1. Component A
- 8.15. Effects of Temperature on Diphenylmethane Di-isocyanate
- 8.16. Polyol Blends
- 8.17. Basic Chemical Reactions
- 8.18. Shipping Containers for Component Systems
- 8.19. Checking for Water Contamination
- 8.20. Unloading and Storage of Chemicals
- 8.21. Preparing for Production
- 8.21.1. Filling the Day Tanks
- 8.21.2. Calibration of Processing Equipment
- 8.21.3. Foam Re-activities
- 8.21.4. Throughput
- 8.21.5. Free Rise Density
- -- 8.21.6. Foam Structure
- 8.21.7. Filling the Moulds
- 8.21.8. Pouring Pattern Tips
- 8.21.9. About Moulds
- 8.21.10. Mould-release Agents
- 8.21.11. In-mould Coatings
- 8.21.12. Moulding with Inserts
- 8.21.13. Mould Clamping
- 8.21.14. Mould Cleaning
- 8.21.15. Flushing the Mixhead
- 8.21.16. Lead-lag
- 8.21.17. Recharging Day Tanks
- 8.22. Examples of Typical Processing
- 8.22.1. Material Storage
- 8.22.2. Handling of Raw Material
- 8.22.3. Moulds
- 8.22.4. Mixing and Weighing Procedures
- 8.22.5. Tips for Minimising Waste
- 9. Basic Safety Factors
- 9.1. Buildings
- 9.2. Storage of Raw Materials
- 9.3. Production
- 9.4. Safety Provisions
- 9.5. Basics of Spill Management
- 9.6. Recommended Safety Equipment
- 9.7. Handling Precautions
- 9.8. Health and Industrial Hygiene
- 9.8.1. Polyols
- 9.8.2. Isocyanates and Prepolymers
- 9.8.3. Component Systems
- 9.8.4. Other Raw Materials
- 9.9. Spill Management
- 10. Setting-up a Manufacturing Plant for an. Entrepreneur
- 10.1. Example A: Manual Operation
- 10.1.1. Raw Materials
- 10.1.2. Moulds
- 10.1.3. Cutting and Fabrication.
- Note continued: 10.1.4. Hot-wire Cutting Machine
- 10.1.5. Production Method
- 10.2. Example B: Making Large Foam Blocks
- 10.2.1. Foaming Systems
- 10.3. Description of a Typical Semi-automatic Batch Foaming Plant
- 10.3.1. Foaming Machine
- 10.3.2. Foam Cutting Machines
- 10.3.2.1. One Circular (Carousel) Cutting Machine
- 10.3.2.2. Vertical Cutting Machine
- 10.3.3. Foam-shredding Machine
- 10.4. Fully Automatic Operation
- 10.4.1. Production (Manual or Semi-automatic)
- 11. Manufacturing Plants for Large-Volume Producers
- 11.1. Planned Production
- 11.2. Location and Factory Buildings
- 11.3. Storage of Raw Materials
- 11.3.1. Storage Conditions
- 11.3.2. Tank Room
- 11.4. Trough Paper
- 11.5. General Machinery
- 11.6. Basic Equipment
- 11.7. Utilities
- 11.8. Plant Layout
- 11.9. In-house Laboratory
- 11.10. Quality Control
- 11.11. Safety Systems
- 11.12. Foam Production
- 11.13. Foam Cutting and Fabrication
- 11.14. Recycling of Foam Waste
- 12. Recommendations for Process Efficiency
- 12.1. Basic Laboratory Equipment
- 12.2. Recommendations for the Efficiency of Foam Plants
- 12.1.1. Key Factors on a Production Floor
- 12.2.2. Preventive Maintenance in Foam Plants
- 12.3. Guidelines for a Quality Control System
- 12.3.1. What is a Control Chart?
- 12.3.2. What is an X-R Chart?
- 12.3.3. What is a P Chart?
- 12.4. General Recommendations for Troubleshooting.