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121212s2013 nyu ob 001 0 eng |
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|a 2020679293
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|a UAMI
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0 |
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|a New developments in aldehydes research /
|c Luca Torrioni and Emilia Pescasseroli, editors.
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264 |
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|a New York :
|b Nova Publishers,
|c [2013]
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|a 1 online resource
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|a text
|b txt
|2 rdacontent
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|a Chemical engineering methods and technology
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|a Includes bibliographical references and index.
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|a Print version record.
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|a NEW DEVELOPMENTS IN ALDEHYDES RESEARCH ; NEW DEVELOPMENTS IN ALDEHYDES RESEARCH ; CONTENTS ; PREFACE ; SYNTHESIS AND PROPERTIES OF INTERMEDIATES IN REACTIONS OF ALDEHYDES WITH P (III) CHLORIDES ; ABSTRACT ; INTRODUCTION ; 1. THE BRIEF HISTORICAL SURVEY OF REACTIONS OF ALDEHYDES WITH P(III) CHLORIDES ; 2. SYNTHETIC METHODS AND STRUCTURE OF PRIMARY INTERMEDIATES ; 3. CHEMICAL PROPERTIES OF THEPRIMARY INTERMEDIATES ; 3.1. Interaction of Intermediates 12with Ethylene Oxide, Acetal, Trialkyl Orthoformates and Trialkyl Phosphites.
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|a 3.2. Reactions of Intermediates10b-C with Acetals and Trialkyl Orthoformates 3.3. Oxidation of Primary Intermediates (R; 3.4. Interaction of Intermediates 12f-Iwith Phosphorus Pentachloide and Chlorine ; 4. REACTIONS OF THE PRIMARY INTERMEDIATESWITH ALDEHYDES AND DETECTION OF THE SECONDARY INTERMEDIATES ; Conclusion; 5. DESCRIPTION OF THE EXPERIMENTS ; 5.1. Removing of HCl Contaminant from P(III) Chlorides; 5.1.1. By Treatment with Tertiary Amines ; 5.1.2. By Treatment with AVE Ethy; 5.2. Reactions of P(III) Chlorides with Aldehydes.
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|a 5.2.1. Interaction of P(III) Chlorides with Acetaldehyde in the Absence of Catalyst 5.2.2. Reaction of P(III) Chloride with Aldehydes in the Presence of Tertiary Amines ; General Procedure The ; 1-Chloro-2-Methylpropyl Phosphorodichloridite 10c ; 1-Chlorobutyl Phosphorodichloridite 10b ; 1-Chloroethyl Phosphorodichloridite 10a ; Di(1-chloroethyl) phosphorochloridite 11a The rea; Tri(1-chloroethyl) Phosphite 12a 3; 5.2.3. Reaction of P(III) Chlorides with Aldehydes in Presence of EVE ; General Procedure Ethy; Catechol 1-chloro-2,2-dimethylpropyl Phosphite 12i.
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|a Catechol 1-chloro-2-methylpropyl Phosphite 12f. The reac1-Chloro-2-methylpropyl bis(2,2,2-trichloroethyl) Phosphite 12b ; Di(1-chloroethyl) 2,2,2-trichloroethyl Phosphite 12e ; 5.3. Reactions of Primary Intermediates with Nucleophiles ; 5.3.1. With Ethylene Oxide ; 5.3.2. With Trialkylphosphite ; 5.3.3. With the Acetals ; 5.3.4. With Trialkyl Orthoformate ; 5.3.5. With Ü-Chlorodiethyl Ether ; 5.4. Oxidation of the Primary Intermediates ; 5.4.1. With Dimethylsulfoxide (DMSO) ; 1-Chloroethyl Dichlorophosphate 65a Benz; 1-Chlorobutyl Dichlorophosphate 65b On anal.
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|a 1-Chloro-2-methylpropyl Dichlorophosphate65c Catechol 1-chloroethyl Phosphate 65f O; Catechol 1-chlorobutyl Phosphate 65g ; 1,2,2,2-Tetrachloroethyl Dichlorophosphate 65l; Di(1-chloroethyl) Chlorophosphate 65d O; Di(1-Chloro-2-Methylpropyl) 2,2,2-Trichloroethyl Phosphate 65n ; 1-Chloro-2-Methylpropyl Bis (2,2,2-Trichloroethyl) Phosphate 65h. ; Di(1-Chloroethyl) 2,2,2-Trichloroethyl Phosphate 65o.; 5.4.2. With t-BuOCl ; 1-Chloroethyl Dichlorophosphate 65a BuO; 1-Chlorobutyl Dichlorophosphate 65b O; 1-Chloro-2-Methylpropyl Dimethyl Phosphate 65i ; 1-Chloro-2-Methylprophyl Diethyl Phosphate 65j.
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546 |
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|a English.
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590 |
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|a eBooks on EBSCOhost
|b EBSCO eBook Subscription Academic Collection - Worldwide
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650 |
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|a Aldehydes.
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650 |
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6 |
|a Aldéhydes.
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650 |
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7 |
|a SCIENCE
|x Chemistry
|x Organic.
|2 bisacsh
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650 |
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7 |
|a Aldehydes.
|2 fast
|0 (OCoLC)fst00804652
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700 |
1 |
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|a Torrioni, Luca,
|e editor.
|
700 |
1 |
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|a Pescasseroli, Emilia,
|e editor.
|
776 |
0 |
8 |
|i Print version:
|t New developments in aldehydes research.
|d New York : Nova Publishers, [2013]
|z 9781624170904
|w (DLC) 2012037325
|
830 |
|
0 |
|a Chemical engineering methods and technology.
|
856 |
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