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Molybdenum : its biological and coordination chemistry and industrial applications /
| Clasificación: | Libro Electrónico |
|---|---|
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York :
Nova Publishers,
[2013]
|
| Colección: | Chemistry research and applications
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- MOLYBDENUM ; MOLYBDENUM ; CONTENTS ; PREFACE ; ACKNOWLEDGMENTS ; DEDICATIONS AND MEMORIES OF TWO ICONS OF MOLY ; A DEDICATION TO DR. EDWARD (ED) I. STIEFEL ; A DEDICATION TO PROFESSOR A. GEOFFREY (GEOFF) SYKES ; MEMORIES OF TWO ICONS OF MOLY ; MOLYBDENUM (MOLYBDAENUM): ITS HISTORY, OCCURRENCE, BRIEF INORGANIC AND BIOINORGANIC CHEMISTRY ; ABSTRACT ; ABBREVIATIONS ; HISTORY ; OCCURRENCE AND PRODUCTION OF MOLYBDENUM ; PHYSICAL PROPERTIES ; USES OF MOLYBDENUM AND ITS COMPOUNDS ; THE ISOTOPES OF MOLYBDENUM AND THEIR MEDICINAL USES ; BASIC CHEMISTRY OF MOLYBDENUM.
- A GENERAL SURVEY OF THE GROUP(VI) OXOANIONS PREPARATION AND CHEMICAL PROPERTIES OF THE MOLYBDATE(VI) ION ; ISOPOLYACIDS AND SALTS OF MOLYBDENUM ; THE MOLYBDATE(VI) ANION IN COORDINATION CHEMISTRY ; REDOX CHEMISTRY OF THE "FREE" AND COORDINATED MOLYBDATE(VI) ANION ; 95 Mo/97Mo NMR: An Introduction ; 95 Mo NMR Spectroscopy Involving Aqueous Molybdate(VI) and Other Mo(VI) Species ; Catalysis Involving Molybdenum for Hydrogen Production; BIOLOGICAL ROLE OF MOLYBDENUM ; Molybdenum in Enzymes ; Molybdenum in Medicine ; REFERENCES.
- RECENT ADVANCES IN THE CHEMISTRY OF MOLYBDENUM-MOLYBDENUM MULTIPLE BONDS ABSTRACT ; INTRODUCTION ; THE QUINTUPLE BOND ; MO24+ IN HIGHER ORDER ASSEMBLIES: POLYGONS ; ELECTRONICALLY COUPLED QUADRUPLY BONDED CENTERS
- ELECTROCHEMICAL STUDIES ; MOLECULAR ORBITAL CONSIDERATIONS ; PHOTOPHYSICAL STUDIES ; TIME RESOLVED INFRARED STUDIES ; REACTIVITY OF MO-MO MULTIPLE BONDS; ACKNOWLEDGMENTS ; REFERENCES ; MOLYBDENUM AQUA IONS ; ABSTRACT ; 1. INTRODUCTION ; 2. MOLYBDENUM(II): CHEMISTRY OF THE AQUA DIMER: [MO2(OH2)8]4+ ; 2.1. Synthesis of [Mo2(OH2)8]4+ ; 2.2. Properties of [Mo2(OH2)8]4+
- 2.3. Reactions of [Mo2(OH2)8]4+ 3. MOLYBDENUM(III) ; 3.1. Synthesis and Properties of [Mo(OH2)6] r; 3.2. Complex Formation with [Mo(OH2)6]3+ ; 3.3. Redox reactions involving [Mo(OH)6]3+ ; 3.4. Hydrolytic Polymerized Ions of Mo(III) ; 4. MOLYBDENUM(IV): CHEMISTRY OF THE TRIANGULAR CLUSTER ION; [MO3( 3-O)( -O)3(OH2)9]4+ ; 4.1. Synthesis of the [Mo3( 3-O)( -O)3(OH2)9]4+ Ion ; 4.2. Water Exchange and Complex Formation on [Mo3( 3-O)( -O)33(OHand23)9]4+ ; 4.3. Redox Processes Involving [Mo3( 3-O)( -O)3(OH2)9]4+ ; 4.3.1. Reduction ; 4.3.2. Oxidation ; 5. MOLYBDENUM(V)
- 5.1. Preparation and Properties of the Dimeric Ion: [(Mo=O)2( -O)2 (OH2)6]2+(; 5.2. Complex Formation and Water Exchange on [(Mo=O)( -O)(OHex)6]32+