Advances in multi-photon processes and spectroscopy /

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In view of the rapid growth in both experimental and theoretical studies of multiphoton processes and multiphoton spectroscopy of atoms, ions and molecules in chemistry, physics, biology, materials science, etc., it is desirable to publish an advanced series of books containing review papers that ca...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Lin, S. H. (Sheng Hsien), 1937-, Villaeys, A. A., Fujimura, Y. (Yuichi)
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Singapore ; London : World Scientific, 1998.
Colección:Advances in Multi-Photon Processes and Spectroscopy.
Temas:
Fluorescence spectroscopy.
Multiphoton processes.
Molecular spectra.
Spectroscopie de fluorescence.
Processus à plusieurs photons.
Molécules > Spectre.
SCIENCE > Spectroscopy & Spectrum Analysis.
Fluorescence spectroscopy
Molecular spectra
Multiphoton processes
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Contents
  • Preface
  • PART ONE Resonance Raman Intensities: The Roundabout Way to
  • Resonance Raman Intensities: The Roundabout Way to Franck-Condon Analysis
  • 1. Introduction
  • 2. Symmetric triatomic molecules and ions
  • 2.A. Carbon disulfide
  • 2.A.i. Emission polarization and rotational lineshapes in vapor
  • 2.A.ii. Electronic dephasing in solution
  • 2.B. Sulfur dioxide
  • 2.C. Triiodide ion
  • 3. Other small photodissociative molecules
  • 3.A. Alkyl iodides
  • 3.B. Nitromethane
  • 4. Small linear polyenes
  • 4.A. Trans-hexatriene
  • 4.B. Cis-hexatriene4.C. Butadiene
  • 5. Stilbene
  • 5.A. Trans-stilbene
  • 5.B. Cis-stilbene
  • 6. Charge transfer systems
  • 6.A. Hexamethylbenzene/tetracyanoethylene complex
  • 6.B. Covalent charge-transfer molecules
  • 7. Azulene
  • 8. Conclusions
  • 9. Acknowledgments
  • 10. References
  • PART TWO Van der Waals Complexes and Small Molecular Clusters: A Tool to Understand and Control Chemical Reactions
  • Van der Waals Complexes and Small Molecular Clusters: A Tool to Understand and Control Chemical Reactions
  • Introduction
  • Experimental principle
  • REACTION IN VAN DER WAALS COMPLEXES.I. Preparation of the complex
  • i) The entrance channel:
  • ii) The final states.
  • iii) The intermediate state of reaction.
  • The van der Waals technique as a probe for a harpoon type chemical reaction
  • Two-photon excitation.
  • VUV excitation of the Xe-Cl2 complex: symmetry selection on the exit channel
  • Charge transfer mechanism in a T shaped Xe-Cl2 complex
  • Femto second investigation of the Xe-Cl2 reactive complex (73).
  • REACTION IN IONIC COMPLEXES
  • Ionic nucleophilic substitution reaction in halogenated benzene-NH3 complexesResults
  • SIZE EFFECT IN NUCLEOPHILIC SUBSTITUTION
  • Conclusions
  • REFERENCES
  • PART THREE Photofragmentation of Weakly Bound Complexes
  • Photofragmentation of Weakly Bound Complexes
  • 1 Introduction
  • 2 One-atom cage effect
  • 3 Complex induced electronic predissociation
  • 3.1 Golden rule wave packet treatment of electronic predissociation
  • 4 Discussion and conclusions
  • References
  • PART FOUR Off-Resonant Fifth and Seventh Order Time-Domain Nonlinear Spectroscopy on Vibrational Dephasing in LiquidsOff-Resonant Fifth and Seventh Order Time-Domain Nonlinear Spectroscopy on Vibrational Dephasing in Liquids
  • Abstract
  • 1. Introduction
  • 2. Vibrational Dephasing
  • 2.1. Introduction
  • 2.2. Stochastic Theory for Vibrational Lineshape; Homogeneous and Inhomogeneous Broadening
  • 3. Basic Theory of Nonlinear Spectroscopy
  • 3.1. Quantum Electrodynamics and Nonlinear Spectroscopy
  • 3.2. Nonlinear Response Function

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