Cargando…
Facets of coordination chemistry /
A concise account of coordination chemistry since its inception is given here together with some of the newer significant facets. This book covers a broad spectrum of various topics on Environment, Cyclic Voltammetry, Chromatography, Metal Complexes of biological interest, Alkoxides, NMR spectroscop...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Singapore ; [River Edge], NJ :
World Scientific,
[©1993]
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- PREFACE; CONTENTS; FOREWORD; CHAPTER 1 INTRODUCTION : COORDINATION CHEMISTRY AND ITS MULTIFACETS; CHAPTER 2 COORDINATION CHEMISTRY OF ENVIRONMENT; Introduction; Special Aspects of the Coordination Chemistry of the Environment; Examples of the Application of Coordination Chemistry; Metal species in the environment; Coordination by fluoride versus hydroxide; Species concentration from formation constants; Other metal-ligand associations in water; Factors Affecting Distribution of Trace Metals in Waterhyacinth; Carbonate Geochemistry and Coordination Chemistry; Background information.
- Application of Coordination ChemistryThe Red Tide Problem; Abstract; Acknowledgments; References; CHAPTER 3 RETROSPECTIVE STUDIES ON METAL COMPLEXES AS SYNTHETIC DIOXYGEN CARRIERS OF BIOLOGICAL INTEREST; 1. Introduction; 2. Cobalt Complexes; 2.1. Discovery of Monomeric Dioxygen Adducts; 2.2. Bonding, Spectra and Solution; 2.3. Dioxygen Affinities; 2.4. Coboglobins; 3. Iron complexes; 3.1. Requirements for Synthetic O2-carriers; 3.2. Steric; 3.3. Low Temperature; 3.4. Attachment to Rigid Surfaces; 4. Manganese Complexes; Acknowledgements; References.
- CHAPTER 4 HETEROMETAL ALKOXIDES
- A NOVEL SERIES OF STABLE POLYMETALLIC COORDINATION COMPOUNDS*1. Historical; 2. Synthesis of Bimetallic Alkoxides:; 2.1 From the component alkoxides:; 2.2 From the Reactions of Metal halides with Alkali Aikoxometallates :; 3. Tri- and higher Heterometal Alkoxides :; 4. Conclusion:; Abstract; References; CHAPTER 5 SOLVENT EFFECTS ON THE REACTIONS OF COORDINATION COMPLEXES; Introduction; Principles of Analysis; Reactions involving Neutral Reactions :; Reactions involving ions :; Substitution Reactions of Complex Ions.
- Correlation between solvolysis rate constant (ks) and Bulk dielectric constant of the Medium:Correlation of Solvolysis rates with solvent Y parameter :; Solvatochromic solvent Polarity Scale :; Solvent Acity and Basity Parameters :; Preferential Solvation Effects :; Metal Ion Catalysed Reactions in Mixed Solvent Media :; Miscellaneous Reactions :; Gibbs Free Energy of the Transition State :; Influence of Solvent Structure on the Energetics of Solvolysls Reactions :; Abstract; Acknowledgements; References; CHAPTER 6 A SIMPLE MODEL FOR FITTING PROPERTIES OF BINARY MIXTURES; Introduction.
- The modelExamples; Enthalpy of mixing; Concluding remarks; Abstract; References; CHAPTER 7 DONOR-ACCEPTOR INTERACTIONS AND STRUCTURAL FLEXIBILITY OF COORDINATION-COMPOUNDS IN SOLUTION; 1. Introduction; 2. The first Bond Length Variation Rule; 3. The Second Bond Length Variation Rule :; 4. The ""Pile Up"" and ""Spill Over"" Effects; 5. Variations in Bond-Angles; 5.1 Bond Angle Variation in Trimethylchlorostannane; 5.2 Bond Angle Variation in Tetranuclear Cu(lI)-complexes.; 6. Chemical Functionality; 7. Solvent and Substituerrt Effects on Coordination Compounds in Solution.