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Facets of coordination chemistry /
A concise account of coordination chemistry since its inception is given here together with some of the newer significant facets. This book covers a broad spectrum of various topics on Environment, Cyclic Voltammetry, Chromatography, Metal Complexes of biological interest, Alkoxides, NMR spectroscop...
| Clasificación: | Libro Electrónico |
|---|---|
| Otros Autores: | , , |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Singapore ; [River Edge], NJ :
World Scientific,
[©1993]
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| Temas: | |
| Acceso en línea: | Texto completo |
MARC
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| 245 | 0 | 0 | |a Facets of coordination chemistry / |c edited by B.V. Agarwala, K.N. Munshi. |
| 260 | |a Singapore ; |a [River Edge], NJ : |b World Scientific, |c [©1993] | ||
| 300 | |a 1 online resource (xiv, 253 pages) : |b illustrations, portrait | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a computer |b c |2 rdamedia | ||
| 338 | |a online resource |b cr |2 rdacarrier | ||
| 500 | |a Articles by the students and colleagues of Arun K. Dey in honor of his 70th birthday. | ||
| 504 | |a Includes bibliographical references and index. | ||
| 588 | 0 | |a Print version record. | |
| 505 | 0 | |a PREFACE; CONTENTS; FOREWORD; CHAPTER 1 INTRODUCTION : COORDINATION CHEMISTRY AND ITS MULTIFACETS; CHAPTER 2 COORDINATION CHEMISTRY OF ENVIRONMENT; Introduction; Special Aspects of the Coordination Chemistry of the Environment; Examples of the Application of Coordination Chemistry; Metal species in the environment; Coordination by fluoride versus hydroxide; Species concentration from formation constants; Other metal-ligand associations in water; Factors Affecting Distribution of Trace Metals in Waterhyacinth; Carbonate Geochemistry and Coordination Chemistry; Background information. | |
| 505 | 8 | |a Application of Coordination ChemistryThe Red Tide Problem; Abstract; Acknowledgments; References; CHAPTER 3 RETROSPECTIVE STUDIES ON METAL COMPLEXES AS SYNTHETIC DIOXYGEN CARRIERS OF BIOLOGICAL INTEREST; 1. Introduction; 2. Cobalt Complexes; 2.1. Discovery of Monomeric Dioxygen Adducts; 2.2. Bonding, Spectra and Solution; 2.3. Dioxygen Affinities; 2.4. Coboglobins; 3. Iron complexes; 3.1. Requirements for Synthetic O2-carriers; 3.2. Steric; 3.3. Low Temperature; 3.4. Attachment to Rigid Surfaces; 4. Manganese Complexes; Acknowledgements; References. | |
| 505 | 8 | |a CHAPTER 4 HETEROMETAL ALKOXIDES -- A NOVEL SERIES OF STABLE POLYMETALLIC COORDINATION COMPOUNDS*1. Historical; 2. Synthesis of Bimetallic Alkoxides:; 2.1 From the component alkoxides:; 2.2 From the Reactions of Metal halides with Alkali Aikoxometallates :; 3. Tri- and higher Heterometal Alkoxides :; 4. Conclusion:; Abstract; References; CHAPTER 5 SOLVENT EFFECTS ON THE REACTIONS OF COORDINATION COMPLEXES; Introduction; Principles of Analysis; Reactions involving Neutral Reactions :; Reactions involving ions :; Substitution Reactions of Complex Ions. | |
| 505 | 8 | |a Correlation between solvolysis rate constant (ks) and Bulk dielectric constant of the Medium:Correlation of Solvolysis rates with solvent Y parameter :; Solvatochromic solvent Polarity Scale :; Solvent Acity and Basity Parameters :; Preferential Solvation Effects :; Metal Ion Catalysed Reactions in Mixed Solvent Media :; Miscellaneous Reactions :; Gibbs Free Energy of the Transition State :; Influence of Solvent Structure on the Energetics of Solvolysls Reactions :; Abstract; Acknowledgements; References; CHAPTER 6 A SIMPLE MODEL FOR FITTING PROPERTIES OF BINARY MIXTURES; Introduction. | |
| 505 | 8 | |a The modelExamples; Enthalpy of mixing; Concluding remarks; Abstract; References; CHAPTER 7 DONOR-ACCEPTOR INTERACTIONS AND STRUCTURAL FLEXIBILITY OF COORDINATION-COMPOUNDS IN SOLUTION; 1. Introduction; 2. The first Bond Length Variation Rule; 3. The Second Bond Length Variation Rule :; 4. The ""Pile Up"" and ""Spill Over"" Effects; 5. Variations in Bond-Angles; 5.1 Bond Angle Variation in Trimethylchlorostannane; 5.2 Bond Angle Variation in Tetranuclear Cu(lI)-complexes.; 6. Chemical Functionality; 7. Solvent and Substituerrt Effects on Coordination Compounds in Solution. | |
| 520 | |a A concise account of coordination chemistry since its inception is given here together with some of the newer significant facets. This book covers a broad spectrum of various topics on Environment, Cyclic Voltammetry, Chromatography, Metal Complexes of biological interest, Alkoxides, NMR spectroscopy and others. These are useful to the scientific community engaged in the field of Inorganic Chemistry and Analytical Chemistry. | ||
| 590 | |a eBooks on EBSCOhost |b EBSCO eBook Subscription Academic Collection - Worldwide | ||
| 650 | 0 | |a Coordination compounds. | |
| 650 | 6 | |a Composés de coordination. | |
| 650 | 7 | |a SCIENCE |x Chemistry |x Computational & Molecular Modeling. |2 bisacsh | |
| 650 | 7 | |a Coordination compounds |2 fast | |
| 650 | 7 | |a Composés de coordination. |2 ram | |
| 700 | 1 | |a Agarwala, B. V. |q (Badri Vishal) | |
| 700 | 1 | |a Munshi, K. N. |q (Kailash Nath) | |
| 700 | 1 | |a Dey, Arun K., |d 1922- | |
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