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Perspectives on the macromolecular condensed state /

The main topics discussed in this book are the formation of the macromolecular condensed state from isolated long chain macromolecules in dilute solution, the salient physical behavior of the polymeric amorphous state, the liquid crystalline state of rigid chain polymers, the crystallization process...

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Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Qian, Renyuan
Formato: Electrónico eBook
Idioma:Inglés
Publicado: River Edge, N.J. : World Scientific, ©2002.
Temas:
Acceso en línea:Texto completo

MARC

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245 1 0 |a Perspectives on the macromolecular condensed state /  |c Renyuan Qian. 
260 |a River Edge, N.J. :  |b World Scientific,  |c ©2002. 
300 |a 1 online resource (viii, 241 pages) :  |b illustrations 
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504 |a Includes bibliographical references and index. 
588 0 |a Print version record. 
520 2 |a The main topics discussed in this book are the formation of the macromolecular condensed state from isolated long chain macromolecules in dilute solution, the salient physical behavior of the polymeric amorphous state, the liquid crystalline state of rigid chain polymers, the crystallization process and the single chain condensed state, all based on experimental results. The role of intersegmental cohesion and the difference between the single chain condensed state and the interpenetrated multichain condensed state are emphasized. In addition, the book introduces and discusses some new physical concepts, such as dynamic contact concentration, the looped chain, cohesional entanglement, the GOLR state (the global chain is highly oriented while the segmental orientation is completely random) and solidification-induced band texture. 
505 0 |a Preface; Introduction; 0.1 In Retrospect; 0.2 Key Issues; 0.3 The Scope of This Book; References; Chapter 1 The Process of Formation of the Macromolecular Condensed State from Isolated Coils in a Dilute Solution; 1.1 Concentration Regimes; 1.2 Dynamic Contact Concentration; 1.3 Dilute and Semidilute Solutions; 1.4 Concentrated Solutions, ce and c+; 1.5 Formation of a Solid State Polymer from Solution; References; Chapter 2 Amorphous State; 2.1 Fluid State and Chain Entanglement; 2.2 Glass Transition Temperature; 2.3 Cooperative Internal Rotations; 2.4 Cohesional Entanglement 
505 8 |a 2.5 Sub-Tg Annealing2.6 GOLR State; 2.7 Molecular Relaxation; 2.8 Yielding and Postyield Deformation; References; Chapter 3 Liquid Crystalline State; 3.1 Low Molar Mass Liquid Crystalline Compounds and Liquid Crystalline State of Polymers; 3.2 Formation of a Polymeric Nematic Phase and Its Isotropization; 3.3 Band Texture Formation; 3.4 Disclinations; References; Chapter 4 Polymer Crystallization Process; 4.1 Controversies and the Basic Physical Issue; 4.2 Crystallization from Dilute Solution; 4.3 Crystallization from a Melt and from a Rubbery State 
505 8 |a 4.4 Crystallization from an Oriented Amorphous State4.5 Some Special Cases; References; Chapter 5 Single Chain Condensed State; 5.1 Single Chain Condensed State and Interpenetrated Multichain Condensed State; 5.2 Methods of Preparing Single Chain Particles; 5.3 Single Chain Single Crystal; 5.4 Single Chain Glass; 5.5 Single Chain in the Rubbery State; 5.6 Transition from Single Chain Condensed State to Interpenetrated Multichain Condensed State; References; Epilogue; I; II; Ill; References; Index 
546 |a English. 
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650 0 |a Crystalline polymers. 
650 6 |a Polymères cristaux liquides. 
650 6 |a Polymères cristallins. 
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