Spatial-energy principles of the processes for complex structure formation /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Korablev, G. A.
Formato: Electrónico eBook
Idioma:Inglés
Ruso
Publicado: Leiden : VSP/Brill, ©2005.
Temas:
Chemistry, Physical and theoretical.
Chemistry, Physical
Chimie physique et théorique.
physical chemistry.
SCIENCE > Chemistry > Physical & Theoretical.
Chemistry, Physical and theoretical
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Preface
  • Introduction
  • Chapter 1. Problems of isomorphism and phase-formation
  • 1.1. Theoretical studies of isomorphic replacements
  • 1.2. Basic phase-formation factors
  • 1.3. Some modern theories about phase-formation problems
  • Chapter 2. Spatial-energy parameter (P-parameter)
  • 2.1. Dependencies between energy, charge and dimensional characteristics inside an atom
  • 2.2. Principle of adding reverse values of energy parameters of oppositely charged systems. P-parameter
  • 2.3. Calculations of total energy of valence electrons inside an atom using SEP method. Comparison with a statistic model2.4. Calculations of electron density inside an atom via P-parameter and principle of adding reverse values of P-parameters
  • 2.5. Dependence of P-parameter upon the modulus of maximum values of Y-function radial part
  • 2.6. Dependence of spectral characteristics of atoms upon their spatial-energy parameters
  • 2.7. Wave equation of P-parameter
  • 2.8. Wave properties of P-parameter and addition principles of P-parameters
  • 2.9. Some additive properties of P-parameter2.10. P-parameter as an objective characteristics of electronegativity
  • Chapter 3. Experimental evidence of spatial-energy criterion of isomorphism and solubility
  • 3.1. Elementary systems of Mâ€?
  • Mâ€? type
  • 3.2. Estimation of isomorphic replacements in complex systems
  • 3.3. Experimental check of P-parameter application taking atom coordination into account
  • 3.4. Morphology of state diagrams of quasi-binary systems of vanadates of metals of II group
  • 3.5. Application of effective PE-parameter
  • Chapter 4. Temperature characteristics of solid solution expansion with the help of Pparameter (at given temperature)4.1. Estimation of mutual solubility of binary system components
  • 4.2. Systems of Mâ€?0
  • Mâ€?0 type
  • 4.3. Phase-formation and thermal properties in systems A12O3-M2O3
  • 4.4. Estimation of carbon solubility in metals for refractory compounds at given temperature
  • 4.5. Calculations of oxygen solubility in metals
  • 4.6. Method experimental check; directed search of inorganic materials
  • Chapter 5. Spatial-energy criterion of compound formation
  • 5.1. P-parameter as a basic criterion of stable phase formation5.2. Crystals with basic ionic bond
  • 5.3. Crystals with ionic-covaience and metallic bonds. Intermetallides
  • 5.4. Crystalline penetration structures
  • 5.5. Estimation of ultimate carbon content value in carbide systems MCl-x
  • Chapter 6. Other applications of P-parameter in inorganic chemistry and chemistry of solids
  • 6.1. Calculations of effective ionization sections of atoms and molecules at electron shock
  • 6.2. Shift modulus determination for metals and carbide compounds

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