Proton Conductors : Solids, Membranes and Gels - Materials and Devices /

Protonic conduction in liquid electrolytes is commonplace but is relatively rare in solids. There is much interest worldwide in proton conducting solids, both from the scientific aspect, as materials with novel properties, but also for their possible applications in high-density solid-state batterie...

Descripción completa

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Colomban, Philippe
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cambridge : Cambridge University Press, 1992.
Colección:Chemistry of solid state materials ; no. 2.
Temas:
Energy band theory of metals.
Protons.
Electric conductors.
Solid state physics.
Solid state chemistry.
Protons
Conducteurs électriques.
Physique de l'état solide.
Chimie de l'état solide.
electric conductor.
SCIENCE / Energy.
SCIENCE / Mechanics / General.
SCIENCE / Physics / General.
Electric conductors
Solid state chemistry
Solid state physics
Aufsatzsammlung
Festkörper
Protonenleitung
Protonentransfer
Superionenleiter
FÍSICA DA MÁTERIA CONDENSADA.
FÍSICA DO ESTADO SÓLIDO.
Conduction électrique.
Énergie, Bandes d' (physique).
Électrons libres dans les métaux, Théorie des.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Cover
  • Half-title
  • Title
  • Copyright
  • Contents
  • List of contributors
  • Preface
  • Symbols
  • I. HYDROGEN BOND AND PROTONIC SPECIES
  • 1 The hydrogen bond and chemical parameters favouring proton mobility in solids
  • 1.1 From ionic to protonic conduction
  • 1.2 The lone proton migration mechanism (translocation)
  • 1.3 Proton-carrying mechanisms (the vehicle mechanism or V-mechanism)
  • 1.4 Structural effects.
  • 1.5 Chemical 'equilibrium' and the 'ionic defect': towards a chemical classification
  • 1.6 References
  • 2 Protonic species and their structures
  • 2.1 General introduction
  • 2.2 Proton hydrates
  • 2.3 Nitrogenous protonic species
  • 2.4 References
  • 3 Proton conductors: classification and conductivity
  • 3.1 Introduction
  • 3.2 Classification of protonic conductors
  • 3.3 References
  • 4 Defects, non-stoichiometry and phase transitions
  • 4.1 Introduction
  • 4.2 Ionic mobility and conductivity.
  • 4.3 Electronic conduction and non-stoichiometry
  • 4.4 Water vapour pressure
  • 4.5 References
  • 5 Structural studies of proton conductors
  • 5.1 The structural situation
  • 5.2 Proton jumps
  • 5.3 Proton jumps and molecular reorientations
  • 5.4 Short hydrogen bonds
  • 5.5 Ordered and disordered networks
  • 5.6 References
  • 6 Hydrogen in metals: structure, diffusion and tunnelling
  • 6.1 Introduction
  • 6.2 Hydrogen absorption in metals
  • 6.3 Hydrogen diffusion and tunnelling
  • 6.4 A model of tunnelling
  • 6.5 Other theories of tunnelling
  • 6.6 References.
  • II. MATERIALS: PREPARATION, STRUCTURES AND PROPERTIES
  • 7 Structure and characterization of hydrogen insertion compounds of metal oxides
  • 7.1 Introduction
  • 7.2 Preparations
  • 7.3 Thermodynamic aspects of hydrogen insertion
  • 7.4 Location of hydrogen in HxMOn
  • 7.5 Conclusions
  • 7.6 References
  • 8 High temperature proton conductors based on perovskitetype oxides
  • 8.1 Introduction
  • 8.2 Proton conducting solids at high temperature
  • 8.3 Preparation and properties of ceramics
  • 8.4 Verification of protonic conduction
  • 8.5 Conduction properties.
  • 8.6 Proton formation in oxides
  • 8.7 Migration of protons
  • 8.8 References
  • 9 Highly ionic hydroxides: unexpected proton conductivity in Mg(OH)2 and homologues
  • 9.1 Introduction
  • 9.2 Non-hydrogen bonded systems
  • 9.3 Potential energy curve of the O-H oscillator
  • 9.4 Direct current proton conductivity measurements
  • 9.5 Proton conductivity results
  • 9.6 Proton carrier density on the conduction band
  • 9.7 Summary
  • 9.8 References
  • 10 Ice
  • 10.1 Introduction
  • 10.2 Structure of ordinary ice
  • 10.3 Defects and conduction mechanism.

Ejemplares similares