Cargando…

Theory of Molecular Rydberg States.

The first single-authored book dedicated to the theory of molecular Rydberg states by multi-channel quantum defect and ab initio methods.

Detalles Bibliográficos
Clasificación:Libro Electrónico
Autor principal: Child, M. S.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Cambridge : Cambridge University Press, 2011.
Colección:Cambridge molecular science series.
Temas:
Acceso en línea:Texto completo

MARC

LEADER 00000cam a2200000Mu 4500
001 EBSCO_ocn768731911
003 OCoLC
005 20231017213018.0
006 m o d
007 cr |n|---|||||
008 111219s2011 enk ob 001 0 eng d
040 |a EBLCP  |b eng  |e pn  |c EBLCP  |d OCLCQ  |d AUD  |d OCLCO  |d DEBSZ  |d OCLCQ  |d OCLCO  |d OCLCF  |d N$T  |d MYG  |d YDXCP  |d E7B  |d IUL  |d UIU  |d REDDC  |d CAMBR  |d OCLCQ  |d COO  |d VGM  |d OCLCQ  |d INT  |d OCLCQ  |d OL$  |d OCLCQ  |d UKAHL  |d LUN  |d OCLCQ  |d SFB  |d OCLCO  |d OCLCQ 
019 |a 759123332  |a 767732960  |a 1167041876  |a 1264759733  |a 1274013343  |a 1292397887  |a 1300569716 
020 |a 9781139100861 
020 |a 1139100866 
020 |a 9781139101523  |q (electronic bk.) 
020 |a 1139101528  |q (electronic bk.) 
020 |a 9781139099516  |q (electronic bk.) 
020 |a 1139099515  |q (electronic bk.) 
020 |a 9780511994814  |q (electronic bk.) 
020 |a 0511994818  |q (electronic bk.) 
020 |z 9780521769952 
020 |z 0521769957 
020 |a 1107218063 
020 |a 9781107218062 
020 |a 1139098837 
020 |a 9781139098830 
029 1 |a AU@  |b 000057022684 
029 1 |a DEBSZ  |b 372909817 
029 1 |a DEBSZ  |b 379324377 
035 |a (OCoLC)768731911  |z (OCoLC)759123332  |z (OCoLC)767732960  |z (OCoLC)1167041876  |z (OCoLC)1264759733  |z (OCoLC)1274013343  |z (OCoLC)1292397887  |z (OCoLC)1300569716 
050 4 |a QC454.A8 C45 2011 
072 7 |a SCI  |x 051000  |2 bisacsh 
082 0 4 |a 539.7 
084 |a SCI074000  |2 bisacsh 
049 |a UAMI 
100 1 |a Child, M. S. 
245 1 0 |a Theory of Molecular Rydberg States. 
260 |a Cambridge :  |b Cambridge University Press,  |c 2011. 
300 |a 1 online resource (332 pages) 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
490 1 |a Cambridge Molecular Science 
505 0 |a Cover; THEORY OF MOLECULAR RYDBERG STATES; Cambridge Molecular Science; Title; Copyright; Contents; Preface; 1 Molecular Rydberg states; 1.1 The nature of Rydberg states; 1.2 Organization of the text; References; 2 The quantum defect picture; 2.1 Introduction; 2.2 Coulomb wavefunctions; 2.2.1 Closed-channel solutions: E <I; 2.2.2 Strongly closed channels; 2.3 Single-channel quantization; 2.4 Coupled channels; 2.4.1 Open-channel case; 2.4.2 Resonant case; 2.4.3 Closed-channel case; References; 3 Ab-initio quantum defects; 3.1 Traditional quantum chemistry. 
505 8 |a 3.2 Constrained ab-initio wavefunctions3.3 The R-matrix matching procedure; 3.4 The Wigner-Eisbud R-matrix; 3.4.1 R-matrix derivation; 3.4.2 Buttle correction; 3.5 Variational R-matrix theory; 3.5.1 Standard method; 3.5.2 Eigenchannel method; 3.5.3 Convergence tests; 3.5.4 Spheroidal basis functions; 3.6 Rydberg-valence interactions; 3.7 The influence of positive ion dipoles; 3.7.1 General considerations; 3.7.2 Group II mono-fluorides; 3.7.3 Dipole modified Coulomb functions; References; 4 Frame transformations and channel interactions; 4.1 Physical assumptions; 4.1.1 The classical picture. 
505 8 |a 4.1.2 Frame transformation types4.2 Rotational channel interactions; 4.2.1 Elementary case (b)? case (d) transformation; 4.2.2?-doubling; 4.2.3 l-uncoupling in non-penetrating series; 4.2.4 Stroboscopic beats between electronic and nuclear motion; 4.3 Vibrational channel interactions; 4.3.1 Bound-state eigenvalues; 4.3.2 Vibrationally induced auto-ionization and rotational branching ratios; 4.4 Vibronic channel interactions; 4.4.1 Configuration interaction; 4.4.2 Jahn-Teller channel coupling; References; 5 Competitive fragmentation; 5.1 Perturbation model for diatomic species. 
505 8 |a 5.2 Diatomic predissociation5.3 Dissociative recombination and related phenomena; 5.3.1 Competing processes; 5.3.2 Two-step theory; 5.4 R-matrix formulation; 5.5 Vibronically induced dissociative recombination of H3+; 5.5.1 The Jahn-Teller mechanism; 5.5.2 A spectroscopic related model; References; 6 Photo-excitation; 6.1 Introduction; 6.2 n-photon discrete absorption; 6.2.1 Single-photon absorption; 6.2.2 Coherent two-photon absorption; 6.3 Spherical tensor representation; 6.4 Spatial selectivity; 6.5 Resonant two-photon excitation; 6.6 Multiphoton band structure; 6.6.1 Symmetric tops. 
505 8 |a 6.6.2 Asymmetric tops6.7 Angular momentum decoupling in high Rydberg states; 6.8 ZEKE intensities; 6.8.1 Asymmetric band profiles; 6.8.2 Symmetry selection rules; References; 7 Photo-ionization; 7.1 Boundary conditions and cross-sections; 7.2 The photo-ionization matrix element; 7.3 Integrated cross-section; 7.3.1 General formulation; 7.3.2 Photo-ionization selection rules; 7.4 Differential cross-section; 7.4.1 General formulation; 7.4.2 Asymmetry parameters; 7.4.3 Information content; 7.5 Fixed molecule angular distribution; 7.6 Resonant two-photon ionization. 
500 |a 7.6.1 The optical density matrix. 
520 |a The first single-authored book dedicated to the theory of molecular Rydberg states by multi-channel quantum defect and ab initio methods. 
588 0 |a Print version record. 
504 |a Includes bibliographical references and index. 
546 |a English. 
590 |a eBooks on EBSCOhost  |b EBSCO eBook Subscription Academic Collection - Worldwide 
650 0 |a Rydberg states. 
650 0 |a Energy levels (Quantum mechanics) 
650 0 |a Ionization. 
650 6 |a États de Rydberg. 
650 6 |a Niveaux d'énergie (Mécanique quantique) 
650 6 |a Ionisation. 
650 7 |a ionization.  |2 aat 
650 7 |a SCIENCE  |x Molecular Physics.  |2 bisacsh 
650 7 |a SCIENCE  |x Physics  |x Nuclear.  |2 bisacsh 
650 7 |a Energy levels (Quantum mechanics)  |2 fast  |0 (OCoLC)fst00910185 
650 7 |a Ionization.  |2 fast  |0 (OCoLC)fst00978621 
650 7 |a Rydberg states.  |2 fast  |0 (OCoLC)fst01102627 
776 0 8 |i Print version:  |a Child, M.S.  |t Theory of Molecular Rydberg States.  |d Cambridge : Cambridge University Press, ©2011  |z 9780521769952 
830 0 |a Cambridge molecular science series. 
856 4 0 |u https://ebsco.uam.elogim.com/login.aspx?direct=true&scope=site&db=nlebk&AN=375951  |z Texto completo 
938 |a Askews and Holts Library Services  |b ASKH  |n AH13438901 
938 |a Askews and Holts Library Services  |b ASKH  |n AH28322014 
938 |a EBL - Ebook Library  |b EBLB  |n EBL803068 
938 |a ebrary  |b EBRY  |n ebr10502767 
938 |a EBSCOhost  |b EBSC  |n 375951 
938 |a YBP Library Services  |b YANK  |n 7167212 
938 |a YBP Library Services  |b YANK  |n 7205334 
938 |a YBP Library Services  |b YANK  |n 7284000 
938 |a YBP Library Services  |b YANK  |n 7295040 
994 |a 92  |b IZTAP