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Supercritical fluids /

Detalles Bibliográficos
Clasificación:Libro Electrónico
Otros Autores: Belinsky, Marcel R.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: New York : Nova Science Publishers, ©2010.
Colección:Condensed matter research and technology series.
Temas:
Acceso en línea:Texto completo
Tabla de Contenidos:
  • SUPERCRITICAL FLUIDS
  • SUPERCRITICAL FLUIDS
  • Contents
  • Preface
  • Modification and Preparation of Membrane in Supercritical Carbon Dioxide
  • Abstract
  • 1. Introduction
  • 2. Mebrane Formation via SCCO2 Induced Phase Separation
  • 2.1. Phase Separation of Fluoropolymer Solution
  • 2.2. Crystallization of Fluoropolymer Solution
  • 2.3. Formation of Porous Membrane
  • 2.4. Effect of CO2 Pressure on Membrane Formation
  • 2.5. Effect of Temperature on Membrane Formation
  • 2.6. Effect of Polymer Concentration on Membrane Formation
  • 2.7. Effect of Solvents on Membrane Formation3. Supercritical Carbondioxide Extraction for Membrane Formation in TIPS
  • 3.1. Thermally Induced Phase Separation (TIPS)
  • 3.2. SCCO2 Extraction
  • 3.2.1. SCCO2 extraction procedures
  • 3.2.2. SCCO2 extraction conditions
  • 3.3. The Microstructure and Morphology of Membranes
  • 3.4. Comparison between Different Solvent Extraction
  • 4. Membrane of Polymer Blends by SCCO2
  • 4.1. Polymer Blending in SCCO2
  • 4.2. Strategy of Modification for Polymer/Substrate Blends
  • 4.3. Preparation of Polymer Blend Membranes
  • 4.4. Characterization of Polymer Blend Membranes4.5. Copolymerizations of Styrene and Maleic Anhydride
  • 5. Surface Modification of Membrane in SCCO2
  • 5.1. Surface-Grafted Membrane
  • 5.2. Mechanism for Graft Modification of Polymer Membrane
  • 5.3. Graft Copolymerization of Man/St onto the Surface of PVDF Membrane
  • 5.4 Characterization of the Grafted Chains
  • 5.5. Morphologies and Structure of the SMA-grfted PVDF Membrane
  • 5.6. Surface Properties of the SMA-Based Membrane
  • Surface hydrophilicity of the SMA-Based Membrane
  • Surface biocompatibility of the SMA-Based Membrane6. Conclusions
  • Acknowledgment
  • References
  • The Critical Properties of a Binary Aqueous and CO2 Containing Mixtures and the Krichevskii Parameter
  • Abstract
  • 1. Introduction
  • 1.1. Technological Applications of the Supercritical Fluid Mixtures Containing CO2
  • 1.2. Technological Applications of the Supercritical Fluid Mixtures Containing H2O
  • 1.3. Scientific Applications of the Supercritical Fluid Mixtures
  • 2. The Critical Properties of Binary Mixtures and Related Thermodynamic Properties
  • 2.1. The Critical Properties of Binary Mixtures and The Krichevskii Parameter2.2. Partial Molar Volume, Henryâ€?s Constant, Distribution Coefficient, Solubility, and Structurtal Properties of Dilute Mixtures and Krichevskii Parameter
  • 2.3. The Critical Curves Shape Behavior and Asymptotic Scaling Properties of Binary Mixtures near the Critical Points of Pure Solvent
  • 3. Experimental Methods
  • 3.1. Method-1. Observation of the Appearance and Disappearance of Meniscus at the Vapor-Liquid Interface. “Sealed Tubeâ€? Method
  • 3.2. Method-2. Law of Rectilinear Diameter