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Molecular theory of water and aqueous solutions. Part 1, Understanding water /
The aim of this book is to explain the unusual properties of both pure liquid water and simple aqueous solutions, in terms of the properties of single molecules and interactions among small numbers of water molecules. It is mostly the result of the author's own research spanning over 40 years i...
| Clasificación: | Libro Electrónico |
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| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
Singapore ; Hackensack, NJ :
World Scientific,
©2009.
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| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- 1. Survey of the properties of water. 1.1. Introduction and some historical notes. 1.2. Properties of water in the gaseous phase. 1.3. Properties of water in the solid phase. 1.4. Properties of water in the liquid phase. 1.5. The Kirkwood-Buff integral. 1.6. Solvation of water in water. 1.7. The importance of water in biological systems
- 2. Theoretical approaches to the study of liquid water. 2.1. Introduction. 2.2. The general theoretical framework. 2.3. The mixture-model approach to liquid water. 2.4. Lattice models for water. 2.5. A one-dimensional model for water. 2.6. A two-dimensional model for water. 2.7. Three-dimensional models for water
- 3. Water with one simple solute. 3.1. Introduction and some historical notes. 3.2. Survey of some properties of simple aqueous solutions. 3.3. Solvation and conditional solvation. 3.4. Statistical mechanical expressions for the solvation thermodynamic quantities. 3.5. Application of the mixture-model approach to water. 3.6. Application of an interstitial model for water to aqueous solutions. 3.7. The problem of stabilization of the structure of water. 3.8. Application of the scaled particle theory. 3.9. Application of a one-dimensional model. 3.10. Applications of two-dimensional models. 3.11. Applications of three-dimensional models
- 4. Water with two solute molecules ; hydrophobic hydrophilic phenomena. 4.1. Introduction. 4.2. The experimental evidence. 4.3. Redefinition of the HøO interaction. 4.4. A simple measure of the strength of the "Pure" HøO interaction. 4.5. Intramolecular HøO interactions. 4.6. Application of the scaled particle theory. 4.7. Temperature and pressure dependence. 4.8. Solvent induced interactions between two hydrophilic HøI groups. 4.9. Application of one-dimensional models to study hydrophobic interactions. 4.10. Application of two-dimensional models. 4.11. Application of three-dimensional models. 4.12. Hydrophobic or hydrophilic? That is the question!