The aqueous chemistry of the elements /
Most fields of science, applied science, engineering, and technology deal with solutions in water. This volume is a comprehensive treatment of the aqueous solution chemistry of all the elements. The information on each element is centered around an E-pH diagram which is a novel aid to understanding....
Clasificación: | Libro Electrónico |
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Autor principal: | |
Otros Autores: | |
Formato: | Electrónico eBook |
Idioma: | Inglés |
Publicado: |
Oxford ; New York :
Oxford University Press,
2010.
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Temas: | |
Acceso en línea: | Texto completo |
Tabla de Contenidos:
- 1 E-pH Diagrams
- 1. Introduction
- 2. The Na E-pH Diagram
- 3. The Al E-pH Diagram
- 4. The Fe E-pH Diagram
- 5. The V E-pH Diagram
- 6. The HOH E-pH Diagram
- 2 The Construction of E-pH Diagrams
- 1. Introduction
- 2. Constructing the Ga E-pH Diagram
- 3. Constructing the Ga E-pH Diagram with Concentration Variations
- 4. Constructing the Mn E-pH Diagram
- 5. E-pH Computer Programs
- 6. Species Selection and Treatment
- 3 Reactions and Applications
- 1. Introduction
- 2. Reactions with HOH
- 3. The Mn-Fe-HOH System (Excess Mn Species)
- 4. The Mn-Fe-HOH System (Excess Fe Species)
- 5. Combining Redox Reactions
- 6. The HOH E-pH Diagram Revisited
- 7. General Conclusions
- 4 Precipitation and Complexation
- 1. Introduction
- 2. Precipitation and E-pH Diagrams
- 3. Addition of Cl[sup(
- )] to the Ag E-pH System
- 4. Addition of S[sup( -2)] to the Zn E-pH System
- 5. Review of Complexation and Complex Species
- 6. Complexation and E-pH Diagrams
- 7. Addition of Cl[sup(
- )] to the Pd E-pH System to Form PdCl[sub(4)][sup( -2)]
- 8. Multiple Complexes and E-pH Diagrams
- 5 The Lithium Group
- 1. Introduction
- 2. Lithium (Li) 2s[sup(1)]
- 3. Sodium (Na) 3s[sup(1)]
- 4. Potassium (K) 4s[sup(1)]
- 5. Rubidium (Rb) 5s[sup(1)]
- 6. Cesium (Cs) 6s[sup(1)]
- 7. Francium (Fr) 7s[sup(1)]
- 8. The Ammonium Ion (NH[sub(4)][sup(+)]
- 6 The Beryllium Group
- 1. Introduction
- 2. Beryllium (Be) 2s[sup(2)]
- 3. Magnesium (Mg) 3s[sup(2)]
- 4. Calcium (Ca) 4s[sup(2)]
- 5. Strontium (Sr) 5s[sup(2)]
- 6. Barium (Ba) 6s[sup(2)]
- 7. Radium (Ra) 7s[sup(2)]
- 7 The Boron Group
- 1. Introduction
- 2. Boron (B) 2s[sup(2)]2p[sup(1)]
- 3. Aluminum (Al) 3s[sup(2)]3p[sup(1)]
- 4. Gallium (Ga) 4s[sup(2)]4p[sup(1)]
- 5. Indium (In) 5s[sup(2)]5p[sup(1)]
- 6. Thallium (Tl) 6s[sup(2)]6p[sup(1)]
- 8 The Carbon Group.
- 1. Introduction
- 2. Carbon (C) 2s[sup(2)]2p[sup(2)]
- 3. Silicon (Si) 3s[sup(2)]3p[sup(2)]
- 4. Germanium (Ge) 4s[sup(2)]4p[sup(2)]
- 5. Tin (Sn) 5s[sup(2)]5p[sup(2)]
- 6. Lead (Pb) 6s[sup(2)]6p[sup(2)]
- 9 The Nitrogen Group
- 1. Introduction
- 2. Nitrogen (N) 2s[sup(2)]2p[sup(3)]
- 3. Phosphorus (P) 3s[sup(2)]3p[sup(3)]
- 4. Arsenic (As) 4s[sup(2)4p[sup(3)]
- 5. Antimony (Sb) 5s[sup(2)]5p[sup(3)]
- 6. Bismuth (Bi) 6s[sup(2)]6p[sup(3)]
- 10 The Oxygen Group
- 1. Introduction
- 2. Oxygen (O) 2s[sup(2)]2p[sup(4)]
- 3. Sulfur (S) 3s[sup(2)]3p[sup(4)]
- 4. Selenium (Se) 4s[sup(2)]4p[sup(4)]
- 5. Tellurium (Te) 5s[sup(2)]5p[sup(4)]
- 6. Polonium (Po) 6s[sup(2)]6p[sup(4)]
- 11 The Fluorine Group
- 1. Introduction
- 2. Fluorine (F) 2s[sup(2)]2p[sup(5)]
- 3. Chlorine (Cl) 3s[sup(2)]3p[sup(5)]
- 4. Bromine (Br) 4s[sup(2)]4p[sup(5)]
- 5. Iodine (I) 5s[sup(2)]5p[sup(5)]
- 6. Astatine (At) 6s[sup(2)]6p[sup(5)]
- 12 The Scandium Group
- 1. Introduction
- 2. Occurrences
- 3. Discoveries
- 4. Scandium (Sc) 4s[sup(2)]3d[sup(1)]
- 5. The Lanthanoids (La-Lu) 6s[sup(2)]5d[sup(0-1)]4f[sup(n)], Including Y, 5s[sup(2)]4d[sup(1)] (All Referred to as Ln)
- 6. Actinium (Ac) 6s[sup(2)]5d[sup(1)]
- 13 The Ti Group and the 5B, 6B, 7B and 8B Heavy Elements
- 1. General Introduction
- 2. Introduction to the Insoluble-oxide Elements: Ti, Zr, Hf, Nb, Ta
- 3. Titanium (Ti) 4s[sup(2)]3d[sup(2)]
- 4. Zirconium (Zr) 5s[sup(2)]4d[sup(2)] and Hafnium (Hf) 6s[sup(2)]5d[sup(2)]
- 5. Niobium (Nb) 5s[sup(2)]4d[sup(3)]
- 6. Tantalum (Ta) 6s[sup(2)]5d[sup(3)]
- 7. Introduction to the High Oxidation State Oxyanion Elements: Mo, W, Tc, Re
- 8. Molybdenum (Mo) 5s[sup(1)]4d[sup(5)]
- 9. Tungsten (W) 6s[sup(1)]5d[sup(5)]
- 10. Rhenium (Re) 6s[sup(2)]5d[sup(5)]
- 11. Technetium (Tc) 5s[sup(2)]4d[sup(5)].
- 12. Introduction to the Noble Metal Elements: Ru, Rh, Pd, Os, Ir, Pt
- 13. Ruthenium (Ru) 5s[sup(1)]4d[sup(7)]
- 14. Osmium (Os) 6s[sup(2)]5d[sup(6)]
- 15. Rhodium (Rh) 5s[sup(1)]4d[sup(8)]
- 16. Iridium (Ir) 6s[sup(2)]5d[sup(7)]
- 17. Palladium (Pd) 5s[sup(0)]4d[sup(10)]
- 18. Platinum (Pt) 6s[sup(1)]5d[sup(9)]
- 14 The V-Cr-Mn Group
- 1. Introduction
- 2. Vanadium (V) 4s[sup(2)]3d[sup(3)]
- 3. Chromium (Cr) 4s[sup(1)]3d[sup(5)]
- 4. Manganese (Mn) 4s[sup(2)]3d[sup(5)]
- 15 The Fe-Co-Ni Group
- 1. Introduction
- 2. Iron (Fe) 4s[sup(2)]3d[sup(6)]
- 3. Cobalt (Co) 4s[sup(2)]3d[sup(7)]
- 4. Nickel (Ni) 4s[sup(2)]3d[sup(8)]
- 16 The Cu Group
- 1. Introduction
- 2. Copper (Cu) 4s[sup(1)]3d[sup(10)]
- 3. Silver (Ag) 5s[sup(1)]4d[sup(10)]
- 4. Gold (Au) 6s[sup(1)]5d[sup(10)]
- 17 The Zn Group
- 1. Introduction
- 2. Zinc (Zn) 4s[sup(2)]3d[sup(10)]
- 3. Cadmium (Cd) 5s[sup(2)]4d[sup(10)]
- 4. Mercury (Hg) 6s[sup(2)]5d[sup(10)]
- 18 The Actinoid Metals
- 1. Introduction
- 2. Availabilities of the Elements
- 3. Discoveries and Extractions
- 4. Elements and Compounds
- 5. E-pH Diagrams
- 6. Complexes
- 7. Trans-lawrencium Elements
- References
- Index
- A
- B
- C
- D
- E
- F
- G
- H
- I
- L
- M
- N
- O
- P
- R
- S
- T
- U
- V
- W
- Y
- Z.