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Interfacial electrochemistry /
This book provides an advanced level introduction to the electrochemistry. It provides the background required to follow current research in a subject which has again become highly topical through the recent development of surface sensitive techniques. It is divided into three parts covering the fun...
| Clasificación: | Libro Electrónico |
|---|---|
| Autor principal: | |
| Formato: | Electrónico eBook |
| Idioma: | Inglés |
| Publicado: |
New York :
Oxford University Press,
1996.
|
| Temas: | |
| Acceso en línea: | Texto completo |
Tabla de Contenidos:
- Cover
- Contents
- List of Main Symbols
- I58; Fundamentals of Electrochemistry
- 1 Introduction
- 146;1 A typical system
- 2 Preliminaries
- 1 Inner44; outer44; and surface potentials
- 2 The electrochemical potential
- 3 Absolute electrode potential
- 4 Three45;electrode configuration
- 3 The metal45;solution interface
- 346;1 Ideally polarizable electrodes
- 346;2 The Gouy45;Chapman theory
- 346;3 The Helmholtz capacity
- 346;4 The potential of zero charge
- 346;5 Surface tension and the potential of zero charge
- 4 Adsorption on metal electrodes
- 446;1 Adsorption phenomena
- 446;2 Adsorption isotherms
- 446;3 The dipole moment of an adsorbed ion
- 446;4 The structure of single crystal surfaces
- 446;5 The adsorption of iodide on Pt40;11141;
- 446;6 Underpotential deposition
- 446;7 Adsorption of organic molecules
- 5 Phenomenological treatment of electron45;transfer reactions
- 546;1 Outer45;sphere electron45;transfer
- 546;2 The Butler45;Volmer equation
- 546;3 Double45;layer corrections
- 546;4 A note on inner45;sphere reactions
- 6 Theoretical considerations of electron45;transfer reactions
- 646;1 Qualitative aspects
- 646;2 A simple model for electron45;transfer reactions
- 646;3 Electronic structure of the electrode
- 646;4 Gerischer39;s formulation
- 646;5 The energy of reorganization
- 7 The semiconductor45;electrolyte interface
- 746;1 Electronic structure of semiconductors
- 746;2 Potential profile and band bending
- 746;3 Electron45;transfer reactions
- 746;4 Photoinduced electron45;transfer
- 746;5 Dissolution of semiconductors
- 8 Selected experimental results for electron45;transfer reactions
- 846;1 Validity of the Butler45;Volmer equation
- 846;2 Curvature of Tafel plots
- 846;3 Adiabatic electron45;transfer reactions
- 846;4 Electrochemical properties of SnO[sub40;241;]
- 846;5 Photocurrents on WO[sub40;341;] electrodes
- 9 Proton45; and ion45;transfer reactions
- 946;1 Dependence on the electrode potential
- 946;2 Rate45;determining step
- 946;3 The hydrogen evolution reaction
- 946;4 Oxygen reduction
- 946;5 Chlorine evolution
- 946;6 Reaction rate and adsorption energy
- 946;7 Comparison of ion45; and electron45;transfer reactions
- 10 Metal deposition and dissolution
- 1046;1 Morphological aspects
- 1046;2 Surface diffusion
- 1046;3 Nucleation
- 1046;4 Growth of two45;dimensional films
- 1046;5 Deposition on uniformly flat surfaces
- 1046;6 Metal dissolution and passivation
- 11 Complex reactions
- 1146;1 Consecutive charge45;transfer reactions
- 1146;2 Electrochemical reaction order
- 1146;3 Deposition of silver in the presence of cyanide
- 1146;4 Mixed potentials and corrosion
- 12 Liquid45;liquid interfaces
- 11 The interface between two immiscible solutions
- 12 Partitioning of ions
- 13 Energies of transfer of single ions
- 14 Double45;layer properties
- 15 Electron45;transfer reactions.