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Perspectives on Structure and Mechanism in Organic Chemistry

Detalles Bibliográficos
Autor principal: Carroll, Felix A.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Newark : John Wiley & Sons, Incorporated, 2010.
Colección:New York Academy of Sciences Ser.
Acceso en línea:Texto completo

MARC

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082 0 4 |a 547/.13  |q OCoLC  |2 22/eng/20231120 
049 |a UAMI 
100 1 |a Carroll, Felix A. 
245 1 0 |a Perspectives on Structure and Mechanism in Organic Chemistry  |h [electronic resource]. 
260 |a Newark :  |b John Wiley & Sons, Incorporated,  |c 2010. 
300 |a 1 online resource (966 p.). 
490 1 |a New York Academy of Sciences Ser. 
500 |a Description based upon print version of record. 
505 0 |a Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Acknowledgments -- Introduction -- Chapter 1 Fundamental Concepts of Organic Chemistry -- 1.1 Atoms and Molecules -- Fundamental Concepts -- Molecular Dimensions -- 1.2 Heats of Formation and Reaction -- Experimental Determination of Heats of Formation -- Bond Increment Calculation of Heats of Formation -- Group Increment Calculation of Heats of Formation -- Homolytic and Heterolytic Bond Dissociation Energies -- 1.3 Bonding Models -- Electronegativity and Bond Polarity -- Complementary Theoretical Models of Bonding 
505 8 |a Symmetric, Asymmetric, Dissymmetric, and Nondissymmetric Molecules -- Designation of Molecular Configuration -- Fischer Projections -- Additional Stereochemical Nomenclature -- 2.3 Manifestations of Stereoisomerism -- Optical Activity -- Configuration and Optical Activity -- Other Physical Properties of Stereoisomers -- 2.4 Stereotopicity -- Stereochemical Relationships of Substituents -- Chirotopicity and Stereogenicity -- Problems -- Chapter 3 Conformational Analysis and Molecular Mechanics -- 3.1 Molecular Conformation -- 3.2 Conformational Analysis -- Torsional Strain -- van der Waals Strain 
505 8 |a Angle Strain and Baeyer Strain Theory -- Application of Conformational Analysis to Cycloalkanes -- Conformational Analysis of Substituted Cyclohexanes -- 3.3 Molecular Mechanics -- 3.4 Molecular Strain and limits to Molecular Stability -- Problems -- Chapter 4 Applications of Molecular Orbital Theory and Valence Bond Theory -- 4.1 Introduction to Molecular Orbital Theory -- Huckel Molecular Orbital Theory -- Correlation of Physical Properties with Results of HMO Calculations -- Other Parameters Generated Through HMO Theory -- Properties of Odd Alternant Hydrocarbons -- The Circle Mnemonic 
505 8 |a 4.2 Aromaticity -- Benzene -- Aromaticity in Small Ring Systems -- Larger Annulenes -- Dewar Resonance Energy and Absolute Hardness -- 4.3 Contemporary Computational Methods -- Extended Hückel Theory -- Perturbational Molecular Orbital Theory -- Atoms in Molecules -- Density Functional Theory -- 4.4 Valence Bond Theory -- Resonance Structures and Resonance Energies -- Choosing a Computational Model -- Problems -- Chapter 5 Reactive Intermediates -- 5.1 Reaction Coordinate Diagrams -- 5.2 Radicals -- Early Evidence for the Existence of Radicals -- Detection and Characterization of Radicals 
500 |a Structure and Bonding of Radicals 
590 |a ProQuest Ebook Central  |b Ebook Central Academic Complete 
758 |i has work:  |a Perspectives on structure and mechanism in organic chemistry (Text)  |1 https://id.oclc.org/worldcat/entity/E39PCYxtDfFVmPT7cGPbPVt4mb  |4 https://id.oclc.org/worldcat/ontology/hasWork 
776 0 8 |i Print version:  |a Carroll, Felix A.  |t Perspectives on Structure and Mechanism in Organic Chemistry  |d Newark : John Wiley & Sons, Incorporated,c2010  |z 9780470276105 
830 0 |a New York Academy of Sciences Ser. 
856 4 0 |u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=7103414  |z Texto completo 
880 8 |6 505-00/(S  |a Pictorial Representations of Bonding Concepts -- The Sp3 Hybridization Model for Methane -- Are There Sp3 Hybrid Orbitals in Methane-- Valence Shell Electron Pair Repulsion Theory -- Variable Hybridization and Molecular Geometry -- 1.4 Complementary Descriptions of the Double Bond -- The (α,π Description of Ethene -- The Bent Bond Description of Ethene -- Predictions of Physical Properties with the Two Models -- 1.5 Choosing Models in Organic Chemistry -- Problems -- Chapter 2 Stereochemistry -- 2.1 Introduction -- 2.2 Stereoisomerism -- Isomerism 
938 |a ProQuest Ebook Central  |b EBLB  |n EBL7103414 
994 |a 92  |b IZTAP