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221015s2010 xx o ||| 0 eng d |
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|a EBLCP
|b eng
|c EBLCP
|d DXU
|d OCLCO
|d OCLCQ
|d OCLCL
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|c (S
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|a 9781118018170
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|a 1118018176
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|a (OCoLC)1347029310
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|a 547/.13
|q OCoLC
|2 22/eng/20231120
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|a UAMI
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|a Carroll, Felix A.
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|a Perspectives on Structure and Mechanism in Organic Chemistry
|h [electronic resource].
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|a Newark :
|b John Wiley & Sons, Incorporated,
|c 2010.
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|a 1 online resource (966 p.).
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|a New York Academy of Sciences Ser.
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|a Description based upon print version of record.
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|a Cover -- Title Page -- Copyright Page -- Contents -- Preface -- Acknowledgments -- Introduction -- Chapter 1 Fundamental Concepts of Organic Chemistry -- 1.1 Atoms and Molecules -- Fundamental Concepts -- Molecular Dimensions -- 1.2 Heats of Formation and Reaction -- Experimental Determination of Heats of Formation -- Bond Increment Calculation of Heats of Formation -- Group Increment Calculation of Heats of Formation -- Homolytic and Heterolytic Bond Dissociation Energies -- 1.3 Bonding Models -- Electronegativity and Bond Polarity -- Complementary Theoretical Models of Bonding
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|a Symmetric, Asymmetric, Dissymmetric, and Nondissymmetric Molecules -- Designation of Molecular Configuration -- Fischer Projections -- Additional Stereochemical Nomenclature -- 2.3 Manifestations of Stereoisomerism -- Optical Activity -- Configuration and Optical Activity -- Other Physical Properties of Stereoisomers -- 2.4 Stereotopicity -- Stereochemical Relationships of Substituents -- Chirotopicity and Stereogenicity -- Problems -- Chapter 3 Conformational Analysis and Molecular Mechanics -- 3.1 Molecular Conformation -- 3.2 Conformational Analysis -- Torsional Strain -- van der Waals Strain
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|a Angle Strain and Baeyer Strain Theory -- Application of Conformational Analysis to Cycloalkanes -- Conformational Analysis of Substituted Cyclohexanes -- 3.3 Molecular Mechanics -- 3.4 Molecular Strain and limits to Molecular Stability -- Problems -- Chapter 4 Applications of Molecular Orbital Theory and Valence Bond Theory -- 4.1 Introduction to Molecular Orbital Theory -- Huckel Molecular Orbital Theory -- Correlation of Physical Properties with Results of HMO Calculations -- Other Parameters Generated Through HMO Theory -- Properties of Odd Alternant Hydrocarbons -- The Circle Mnemonic
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|a 4.2 Aromaticity -- Benzene -- Aromaticity in Small Ring Systems -- Larger Annulenes -- Dewar Resonance Energy and Absolute Hardness -- 4.3 Contemporary Computational Methods -- Extended Hückel Theory -- Perturbational Molecular Orbital Theory -- Atoms in Molecules -- Density Functional Theory -- 4.4 Valence Bond Theory -- Resonance Structures and Resonance Energies -- Choosing a Computational Model -- Problems -- Chapter 5 Reactive Intermediates -- 5.1 Reaction Coordinate Diagrams -- 5.2 Radicals -- Early Evidence for the Existence of Radicals -- Detection and Characterization of Radicals
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500 |
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|a Structure and Bonding of Radicals
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590 |
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|a ProQuest Ebook Central
|b Ebook Central Academic Complete
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758 |
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|i has work:
|a Perspectives on structure and mechanism in organic chemistry (Text)
|1 https://id.oclc.org/worldcat/entity/E39PCYxtDfFVmPT7cGPbPVt4mb
|4 https://id.oclc.org/worldcat/ontology/hasWork
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776 |
0 |
8 |
|i Print version:
|a Carroll, Felix A.
|t Perspectives on Structure and Mechanism in Organic Chemistry
|d Newark : John Wiley & Sons, Incorporated,c2010
|z 9780470276105
|
830 |
|
0 |
|a New York Academy of Sciences Ser.
|
856 |
4 |
0 |
|u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=7103414
|z Texto completo
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880 |
8 |
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|6 505-00/(S
|a Pictorial Representations of Bonding Concepts -- The Sp3 Hybridization Model for Methane -- Are There Sp3 Hybrid Orbitals in Methane-- Valence Shell Electron Pair Repulsion Theory -- Variable Hybridization and Molecular Geometry -- 1.4 Complementary Descriptions of the Double Bond -- The (α,π Description of Ethene -- The Bent Bond Description of Ethene -- Predictions of Physical Properties with the Two Models -- 1.5 Choosing Models in Organic Chemistry -- Problems -- Chapter 2 Stereochemistry -- 2.1 Introduction -- 2.2 Stereoisomerism -- Isomerism
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938 |
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|a ProQuest Ebook Central
|b EBLB
|n EBL7103414
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994 |
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|a 92
|b IZTAP
|