Fundamental Principles of Polymeric Materials

Detalles Bibliográficos
Autor principal: Brazel, Christopher S.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Newark : John Wiley & Sons, Incorporated, 2012.
Colección:New York Academy of Sciences Ser.
Temas:
Electronic books.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • FUNDAMENTAL PRINCIPLES OF POLYMERIC MATERIALS
  • CONTENTS
  • PREFACE
  • PREFACE TO THE SECOND EDITION
  • ACKNOWLEDGMENTS
  • 1 INTRODUCTION
  • Problems
  • References
  • PART I. POLYMER FUNDAMENTALS
  • 2 TYPES OF POLYMERS
  • 2.1 Reaction to Temperature
  • 2.2 Chemistry of Synthesis
  • 2.3 Structure
  • 2.4 Conclusions
  • Problems
  • Reference
  • 3 MOLECULAR STRUCTURE OF POLYMERS
  • 3.1 Types of Bonds
  • 3.2 Bond Distances and Strengths
  • 3.3 Bonding and Response to Temperature
  • 3.4 Action of Solvents
  • 3.5 Bonding and Molecular Structure
  • 3.6 Stereoisomerism in Vinyl Polymers
  • 3.7 Stereoisomerism in Diene Polymers
  • 3.8 Summary
  • Problems
  • References
  • 4 POLYMER MORPHOLOGY
  • 4.1 Amorphous and Crystalline Polymers
  • 4.2 The Effect of Polymer Structure, Temperature, and Solvent on Crystallinity
  • 4.3 The Effect of Crystallinity on Polymer Density
  • 4.4 The Effect of Crystallinity on Mechanical Properties
  • 4.5 The Effect of Crystallinity on Optical Properties
  • 4.6 Models for the Crystalline Structure of Polymers
  • 4.7 Extended Chain Crystals
  • 4.8 Liquid Crystal Polymers
  • Problems
  • References
  • 5 CHARACTERIZATION OF MOLECULAR WEIGHT
  • 5.1 Introduction
  • 5.2 Average Molecular Weights
  • 5.3 Determination of Average Molecular Weights
  • 5.4 Molecular Weight Distributions
  • 5.5 Gel Permeation (or Size-Exclusion) Chromatography (GPC, SEC)
  • 5.6 Summary
  • Problems
  • References
  • 6 THERMAL TRANSITIONS IN POLYMERS
  • 6.1 Introduction
  • 6.2 The Glass Transition
  • 6.3 Molecular Motions in an Amorphous Polymer
  • 6.4 Determination of Tg
  • 6.5 Factors that Influence Tg
  • 6.6 The Effect of Copolymerization on Tg
  • 6.7 The Thermodynamics of Melting
  • 6.8 The Metastable Amorphous State
  • 6.9 The Influence of Copolymerization on Thermal Properties
  • 6.10 Effect of Additives on Thermal Properties
  • 6.11 General Observations about Tg and Tm
  • 6.12 Effects of Crosslinking
  • 6.13 Thermal Degradation of Polymers
  • 6.14 Other Thermal Transitions
  • Problems
  • References
  • 7 POLYMER SOLUBILITY AND SOLUTIONS
  • 7.1 Introduction
  • 7.2 General Rules for Polymer Solubility
  • 7.3 Typical Phase Behavior in Polymer-Solvent Systems
  • 7.4 The Thermodynamic Basis of Polymer Solubility
  • 7.5 The Solubility Parameter
  • 7.6 Hansen's Three-Dimensional Solubility Parameter
  • 7.7 The Flory-Huggins Theory
  • 7.8 Properties of Dilute Solutions
  • 7.9 Polymer-Polmyer-Common Solvent Systems
  • 7.10 Polymer Solutions, Suspensions, and Emulsions
  • 7.11 Concentrated Solutions: Plasticizers
  • Problems
  • References
  • PART II. POLYMER SYNTHESIS
  • 8 STEP-GROWTH (CONDENSATION) POLYMERIZATION
  • 8.1 Introduction
  • 8.2 Statistics of Linear Step-Growth Polymerization
  • 8.3 Number-Average Chain Lengths
  • 8.4 Chain Lengths on a Weight Basis
  • 8.5 Gel Formation
  • 8.6 Kinetics of Polycondensation
  • Problems
  • References
  • 9 FREE-RADICAL ADDITION (CHAIN-GROWTH) POLYMERIZATION
  • 9.1 Introduction
  • 9.2 Mechanism of Polymerization

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