Reactive Intermediates in Organic Chemistry Structure, Mechanism, and Reactions.

Detalles Bibliográficos
Autor principal: Singh, Maya Shankar
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Newark : John Wiley & Sons, Incorporated, 2014.
Colección:New York Academy of Sciences Ser.
Temas:
Electronic books.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Intro
  • Reactive Intermediates in Organic Chemistry
  • Contents
  • Preface
  • Chapter 1 Introduction
  • 1.1 Reaction Mechanism and Reaction Arrows
  • 1.2 Properties and Characteristics of a Reaction
  • 1.2.1 Reactants and Reagents
  • 1.2.2 Product Selectivity
  • 1.2.3 Reaction Characteristics
  • 1.2.4 Factors that Influence Reactions
  • 1.3 Summary
  • Further Reading
  • Chapter 2 Carbocations
  • 2.1 Introduction
  • 2.2 History
  • 2.2.1 Carbonium Ions and Carbenium Ions
  • 2.3 Structures and Geometry of Carbocations
  • 2.4 Generation of Carbocation
  • 2.4.1 From a Halide
  • 2.4.2 From an Alcohol
  • 2.4.3 From an Amine
  • 2.4.4 From an Alkene
  • 2.4.5 From Carbonyl Compounds
  • 2.4.6 Solvent Effects
  • 2.5 Carbocation Stability
  • 2.6 Detection of Carbocations
  • 2.7 Fate of Carbocations
  • 2.7.1 Reaction with a Nucleophile
  • 2.7.2 Elimination of a Proton
  • 2.7.3 Rearrangements of Carbocations
  • 2.7.4 Cationic Polymerization
  • 2.8 Nonclassical Carbocations
  • 2.9 Radical Cations
  • 2.10 Summary
  • Further Reading
  • Chapter 3 Carbanions
  • 3.1 Structure and Geometry of Carbanions
  • 3.2 Generation of Carbanions
  • 3.2.1 Reduction of C-X Bond with Metal
  • 3.2.2 Deprotonation from a C-H Bond
  • 3.2.3 Reaction of a Metal with an Alkene
  • 3.2.4 A Negative Ion Adds to a Carbon-Carbon Double or Triple Bond
  • 3.3 Stability of Carbanions
  • 3.4 Reactions of Carbanions
  • 3.5 Enolate Reactions with Carbonyl Groups
  • 3.5.1 Aldol Condensation
  • 3.5.2 Enamine Additions
  • 3.5.3 Robinson Ring-Forming Reaction
  • 3.6 Rearrangements of Carbanions
  • 3.6.1 Homoallylic Rearrangements
  • 3.7 Chiral Carbanions
  • 3.8 Carbanions and Tautomerism
  • 3.8.1 Mechanism of Keto-Enol Interconversion
  • 3.9 Summary
  • Further Reading
  • Chapter 4 Radicals
  • 4.1 Introduction
  • 4.2 Detection and Characterization of Radicals
  • 4.3 Structure and Bonding of Radicals
  • 4.4 Generation of Free Radicals
  • 4.5 Stability of Radicals
  • 4.6 Reactions of Free Radicals
  • 4.7 Stereochemistry of Radical Reactions
  • 4.7.1 Cyclization by Intramolecular Addition Reactions
  • 4.8 Biradicals
  • 4.9 Summary
  • Further Reading
  • Chapter 5 Carbenes
  • 5.1 Structure and Geometry of Carbenes
  • 5.2 Generation of Carbenes
  • 5.2.1 Thermolysis or Photolysis of Diazo Compounds
  • 5.2.2 Reaction of N-Nitrosoureas with Base
  • 5.2.3 Reaction of Tosylhydrazone with Base

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