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EBOOKCENTRAL_on1347027056 |
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OCoLC |
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20240329122006.0 |
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m o d |
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230722s2014 xx o ||| 0 eng d |
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|a EBLCP
|b eng
|c EBLCP
|d OCLCQ
|d EBLCP
|d OCLCO
|d OCLCQ
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| 066 |
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|c (S
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| 020 |
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|a 9783527678280
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|a 352767828X
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| 035 |
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|a (OCoLC)1347027056
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| 082 |
0 |
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|a 547
|q OCoLC
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| 049 |
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|a UAMI
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| 100 |
1 |
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|a Singh, Maya Shankar.
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| 245 |
1 |
0 |
|a Reactive Intermediates in Organic Chemistry
|h [electronic resource] :
|b Structure, Mechanism, and Reactions.
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| 260 |
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|a Newark :
|b John Wiley & Sons, Incorporated,
|c 2014.
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| 300 |
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|a 1 online resource (295 p.).
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| 490 |
1 |
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|a New York Academy of Sciences Ser.
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| 500 |
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|a Description based upon print version of record.
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| 505 |
0 |
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|a Intro -- Reactive Intermediates in Organic Chemistry -- Contents -- Preface -- Chapter 1 Introduction -- 1.1 Reaction Mechanism and Reaction Arrows -- 1.2 Properties and Characteristics of a Reaction -- 1.2.1 Reactants and Reagents -- 1.2.2 Product Selectivity -- 1.2.3 Reaction Characteristics -- 1.2.4 Factors that Influence Reactions -- 1.3 Summary -- Further Reading -- Chapter 2 Carbocations -- 2.1 Introduction -- 2.2 History -- 2.2.1 Carbonium Ions and Carbenium Ions -- 2.3 Structures and Geometry of Carbocations -- 2.4 Generation of Carbocation -- 2.4.1 From a Halide
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|a 2.4.2 From an Alcohol -- 2.4.3 From an Amine -- 2.4.4 From an Alkene -- 2.4.5 From Carbonyl Compounds -- 2.4.6 Solvent Effects -- 2.5 Carbocation Stability -- 2.6 Detection of Carbocations -- 2.7 Fate of Carbocations -- 2.7.1 Reaction with a Nucleophile -- 2.7.2 Elimination of a Proton -- 2.7.3 Rearrangements of Carbocations -- 2.7.4 Cationic Polymerization -- 2.8 Nonclassical Carbocations -- 2.9 Radical Cations -- 2.10 Summary -- Further Reading -- Chapter 3 Carbanions -- 3.1 Structure and Geometry of Carbanions -- 3.2 Generation of Carbanions -- 3.2.1 Reduction of C-X Bond with Metal
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| 505 |
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|a 3.2.2 Deprotonation from a C-H Bond -- 3.2.3 Reaction of a Metal with an Alkene -- 3.2.4 A Negative Ion Adds to a Carbon-Carbon Double or Triple Bond -- 3.3 Stability of Carbanions -- 3.4 Reactions of Carbanions -- 3.5 Enolate Reactions with Carbonyl Groups -- 3.5.1 Aldol Condensation -- 3.5.2 Enamine Additions -- 3.5.3 Robinson Ring-Forming Reaction -- 3.6 Rearrangements of Carbanions -- 3.6.1 Homoallylic Rearrangements -- 3.7 Chiral Carbanions -- 3.8 Carbanions and Tautomerism -- 3.8.1 Mechanism of Keto-Enol Interconversion -- 3.9 Summary -- Further Reading -- Chapter 4 Radicals
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| 505 |
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|a 4.1 Introduction -- 4.2 Detection and Characterization of Radicals -- 4.3 Structure and Bonding of Radicals -- 4.4 Generation of Free Radicals -- 4.5 Stability of Radicals -- 4.6 Reactions of Free Radicals -- 4.7 Stereochemistry of Radical Reactions -- 4.7.1 Cyclization by Intramolecular Addition Reactions -- 4.8 Biradicals -- 4.9 Summary -- Further Reading -- Chapter 5 Carbenes -- 5.1 Structure and Geometry of Carbenes -- 5.2 Generation of Carbenes -- 5.2.1 Thermolysis or Photolysis of Diazo Compounds -- 5.2.2 Reaction of N-Nitrosoureas with Base -- 5.2.3 Reaction of Tosylhydrazone with Base
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| 500 |
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|a Further Reading
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| 590 |
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|a ProQuest Ebook Central
|b Ebook Central Academic Complete
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| 655 |
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0 |
|a Electronic books.
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| 776 |
0 |
8 |
|i Print version:
|a Singh, Maya Shankar
|t Reactive Intermediates in Organic Chemistry
|d Newark : John Wiley & Sons, Incorporated,c2014
|z 9783527335947
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| 830 |
|
0 |
|a New York Academy of Sciences Ser.
|
| 856 |
4 |
0 |
|u https://ebookcentral.uam.elogim.com/lib/uam-ebooks/detail.action?docID=7104680
|z Texto completo
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| 880 |
8 |
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|6 505-00/(S
|a 5.2.4 Carbene Formation by α-Elimination -- 5.2.5 Generation of Carbenoids (Simmons-Smith Reaction) -- 5.2.6 Formation of Carbenes under Neutral Conditions -- 5.2.7 Generation of Carbenes from Small Rings -- 5.3 Reactions of Carbenes -- 5.3.1 Addition Reactions -- 5.3.2 Cycloaddition to 1,2-Dienes (Allenes) -- 5.3.3 Cycloaddition to 1,3-Diene -- 5.3.4 Cycloaddition to Alkynes -- 5.3.5 Insertion Reactions -- 5.3.6 Rearrangement of Carbenes -- 5.3.6.1 Wolff Rearrangement -- 5.3.7 Reactions of Carbenes with Nucleophiles -- 5.4 Carbenes and Carbene Ligands in Organometallic Chemistry -- 5.5 Summary
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| 938 |
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|a ProQuest Ebook Central
|b EBLB
|n EBL7104680
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| 994 |
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|a 92
|b IZTAP
|
