Thermodynamics of Pharmaceutical Systems An Introduction to Theory and Applications.

Detalles Bibliográficos
Autor principal: Connors, Kenneth A.
Formato: Electrónico eBook
Idioma:Inglés
Publicado: Newark : John Wiley & Sons, Incorporated, 2010.
Colección:New York Academy of Sciences Ser.
Temas:
Electronic books.
Acceso en línea:Texto completo
Tabla de Contenidos:
  • Intro
  • THERMODYNAMICS OF PHARMACEUTICAL SYSTEMS
  • CONTENTS
  • PREFACE
  • PREFACE TO THE FIRST EDITION
  • 0. Review of Mathematics
  • 0.1. Introduction
  • 0.2. Dimensions and Units
  • 0.3. Logarithms and Exponents
  • 0.4. Algebraic and Graphical Analysis
  • 0.5. Dealing with Change
  • 0.6. Statistical Treatment of Data
  • Problems
  • I BASIC THERMODYNAMICS
  • 1. Energy and the First Law of Thermodynamics
  • 1.1. Fundamental Concepts
  • 1.2. The First Law of Thermodynamics
  • 1.3. The Enthalpy
  • Problems
  • 2. The Entropy Concept
  • 2.1. The Entropy Defined
  • 2.2. The Second Law of Thermodynamics
  • 2.3. Applications of the Entropy Concept
  • Problems
  • 3. The Free Energy
  • 3.1. Properties of the Free Energy
  • 3.2. The Chemical Potential
  • Problems
  • 4. Equilibrium
  • 4.1. Conditions for Equilibrium
  • 4.2. Physical Processes
  • 4.3. Chemical Equilibrium
  • Problems
  • II THERMODYNAMICS OF PHYSICAL PROCESSES
  • 5. Introduction to Physical Processes
  • 5.1. Scope
  • 5.2. Concentration Scales
  • 5.3. Standard States
  • Problems
  • 6. Phase Transformations
  • 6.1. Pure Substances
  • 6.2. Multicomponent Systems
  • Problems
  • 7. Solutions of Nonelectrolytes
  • 7.1. Ideal Solutions
  • 7.2. Nonideal Solutions
  • 7.3. Partitioning Between Liquid Phases
  • Problems
  • 8. Solutions of Electrolytes
  • 8.1. Coulombic Interaction and Ionic Dissociation
  • 8.2. Mean Ionic Activity and Activity Coefficient
  • 8.3. The Debye-Hückel Theory
  • Problems
  • 9. Colligative Properties
  • 9.1. Boiling Point Elevation
  • 9.2. Freezing Point Depression
  • 9.3. Osmotic Pressure
  • 9.4. Isotonicity Calculations
  • Problems
  • 10. Solubility
  • 10.1. Solubility as an Equilibrium Constant
  • 10.2. The Ideal Solubility
  • 10.3. Temperature Dependence of the Solubility
  • 10.4. Solubility of Slightly Soluble Salts
  • 10.5. Solubilities of Nonelectrolytes: Further Issues
  • Problems
  • 11. Surfaces and Interfaces
  • 11.1. Thermodynamic Properties
  • 11.2. Adsorption
  • Problems
  • III THERMODYNAMICS OF CHEMICAL PROCESSES
  • 12. Acid-Base Equilibria
  • 12.1. Acid-Base Theory
  • 12.2. pH Dependence of Acid-Base Equilibria
  • 12.3. Calculation of Solution pH
  • 12.4. Acid-Base Titrations
  • 12.5. Aqueous Solubility of Weak Acids and Bases
  • 12.6. Nonaqueous Acid-Base Behavior
  • 12.7. Acid-Base Structure and Strength
  • Problems
  • 13. Electrical Work
  • 13.1. Introduction
  • 13.2. Oxidation-Reduction Reactions
  • 13.3. Electrochemical Cells
  • 13.4. pH Measurement
  • 13.5. Ion-Selective Membrane Electrodes
  • Problems
  • 14. Noncovalent Binding Equilibria
  • 14.1. Introduction
  • 14.2. The Noncovalent Interactions
  • 14.3. Binding Models
  • 14.4. Measurement of Binding Constants
  • 14.5. Applications
  • Problems
  • APPENDIXES
  • Appendix A Physical Constants
  • Appendix B Kinetic Theory of Gases
  • Appendix C Extrathermodynamic Relationships
  • ANSWERS TO PROBLEMS
  • BIBLIOGRAPHY
  • INDEX

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